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Data for "Estimation of semiconductor-like pigment concentrations in paint mixtures and their differentiation from paint layers using first-derivative reflectance spectra"
This repository contains key raw data to accompany the article "Estimation of semiconductor-like pigment concentrations in paint mixtures and their differentiation from paint layers using first-derivative reflectance spectra".
The repository includes a complete set of reflectance spectra recorded from the paint samples prepared for this work, plus the optimised structures and electronic density-of-states and band-dispersion curves obtained from complementary modelling studies on the three coloured pigments investigated, viz. alpha-HgS (vermillion), tetragonal Pb3O4 (red lead) and SnPb2O4 (lead-tin yellow).
Abstract of the publication:
Identification of the techniques employed by artists, e.g. mixing and layering of paints, if used together with information about their colour palette and style, can help to attribute works of art with more confidence. In this study, we show how the pigment composition in binary paint mixtures can be quantified using optical-reflectance spectroscopy, by analysis of the peak features corresponding to colour-transition edges in the first-derivative spectra. This technique is found to be more robust than a number of other spectral-analysis methods, which can suffer due to shifts in the transition edges in mixed paints compared to those observed in spectra of pure ones. Our method also provides a means of distinguishing paint mixtures from layering in some cases. The spectroscopy also shows the presence of multiple electronic transitions, accessible within a narrow energy range, to be a common feature of many coloured pigments, which electronic-structure calculations attribute to shallow band edges. We also demonstrate the successful application of the reflectance-analysis technique to painted areas on a selection of medieval illuminated manuscripts
Coupon AM1_Lam16_003 (IMPACT)
Stacking sequence: [(+45/0/-45/90)_2]_s
Material: T800/M21
Ply-thickness: 0.2576
Number of plies: 16
Impact energy (J): 12Details about this dataset are available from the main record: https://doi.org/10.15125/BATH-0019
Coupon AM1_Lam16_004 (IMPACT)
Stacking sequence: [(+45/0/-45/90)_2]_s
Material: T800/M21
Ply-thickness: 0.2509
Number of plies: 16
Impact energy (J): 6Details about this dataset are available from the main record: https://doi.org/10.15125/BATH-0019
Coupon AM1_Lam16_006 (IMPACT)
Stacking sequence: [(+45/0/-45/90)_2]_s
Material: T800/M21
Ply-thickness: 0.2563
Number of plies: 16
Impact energy (J): 24Details about this dataset are available from the main record: https://doi.org/10.15125/BATH-0019
Dataset for ORCID EPrints Implementation
A survey canvassing user requirements for integration of EPrints software with the ORCID service was circulated to four mailing lists. Although the target audience was the UK EPrints user community, the survey was open to anyone, so included a number of international responses. This dataset includes an anonymised version of the download of results from Bristol Online Surveys and a copy of the survey form.A survey was circulated to four mailing lists - [email protected], [email protected], [email protected], [email protected]
Although the target audience was the UK EPrints user community, the survey was open to anyone, so included a number of international responses.
A copy of the survey form is included with the dataset.
Analysis was taken from the Bristol Online Surveys tool. No further processing was carried out.Data has been redacted as follows:
Institution names have been replaced with a country.
Job roles have been removed
Other data points in free text comments that would identify a respondent, an individual or an institution have been replaced with a generic term (e.g. [deleted name]).Columns have the full text of the question. Additionally, a copy of the original survey has been provided for information.
Some observations in the report are based on email correspondence which is unsuitable for sharing
Coupon AM1_Lam16_0019 (IMPACT)
Stacking sequence: [(+45/0/-45/90)_2]_s
Material: T800/M21
Ply-thickness: 0.2577
Number of plies: 16
Impact energy (J): 18Details about this dataset are available from the main record: https://doi.org/10.15125/BATH-0019
Coupon BM1_Ply16_049 (IMPACT)
Stacking sequence: [45_2/-45_2/0_2/90_2]_s
Material: T800/M21
Ply-thickness: 0.2527
Number of plies: 16
Impact energy (J): 6Details about this dataset are available from the main record: https://doi.org/10.15125/BATH-0019
Multi-channel Recordings from L2 Dorsal Root of Rat
Five channel recordings made using a set of hook electrodes from the intact dorsal rootlet of an adult female rat
Boronate based fluorescence (ESIPT) probe for peroxynitrite
This repository contains the experimental data discussed in the manuscript. Including, 1H NMR, 13C NMR (FID and PDF) and Mass Spectra for compounds 4, 5 and probe 3. Fluorescence analysis and UV data of probe 3 including the ONOO- and H2O2 titration curve, selectivity data, Fluorescence intensity changes for probe 3 as a function of time with increasing concentrations of ONOO- (time drive), UV before and after addition of ONOO- cell imaging (exogenous and endogenous) and cell viability
Selective Electrochemiluminescent Sensing of Saccharides using Boronic Acid-Modified Coreactant
This repository contains the experimental data discussed in the manuscript. Including, 1H NMR, 13C NMR (FID and PDF) and Mass Spectra for the co-reactants E0, E3 and E6. Electrochemical data (excel) for the figures shown in the manuscript and ESI