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    Community Engagement as Publishable Scholarship

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    The structures that evaluate what counts as novel and fundable knowledge have evolved over a long timeline, primarily driven by traditional forms of explorative, descriptive and critical analysis research. Community Based Participatory Research does not always fit evaluation and funding structures as comfortably as these models of research which are more established in the global academy, and requires careful navigation of, and some further fine-tuning to, review and accreditation processes, to stand beside more traditionally accepted scholarly practices in being readily recognised as producing original scholarly knowledge

    Invasion of rocky shores by a mytilid mussel reveals an abundant‐centre distribution coupled with moderate increases in densities at its absolute range limits

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    Semimytilus patagonicus is an invasive mussel on the coast of southern Africa and has extended its range in recent years. We asked whether its distribution and abundance are consistent with the abundant‐centre hypothesis (ACH). Marginal populations were located by monitoring 33 rocky shore sites in South Africa and southern Namibia in 2021. This revealed no changes to its distributional limits since 2020. At nine of these sites, population demography was measured to allow a comparison of their densities and size structure. Four were central populations on the west coast of South Africa (including the site where the species was first detected in 2009). Four were marginal populations in South Africa: two towards the cold range edge in the north and two towards the warm range edge to the south. The ninth population was in southern Namibia, representing a recent invasion event first detected in 2014. Across the species' South African range, the distribution of its abundance was generally consistent with the ACH, with the greatest abundance at its range centre and a gradual decrease towards the range edges

    Service learning in teacher education programmes: A literature review on the rationale, benefits, and challenges

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    Service-learning is a teaching approach that gives students opportunities to participate in a service that meets community needs as well as being relevant to the curriculum content and to reflect on the service-learning activity/activities and experience. While the discipline specific content is determined by the National Approved Curriculum for the respective Degree, Diploma or Certificate programme, activities which contribute towards concretising concepts and thus, marry theory with real-life challenges are jointly designed and agreed upon by the subject lecturer and the specific community partner. As pre-service teachers engage in servicelearning activities, they experience personal and professional growth through:(i) taking leadership roles in service-learning activities;(ii) exposure to-and awareness of the real-life environment in which the 21st Century teaching profession has to operate;(iii) engaging in and participating in authentic real-life centred teaching practices;(iv) acquisition of new dispositions necessary for a 21st Century teacher; and (v) exposure to-and the relevance of service-learning as a teaching/learning pedagogy. Therefore, this study is a literature review of a range of some of the existing work on service-learning and it collates and brings together key components of service-learning, its benefits, and challenges. The implications of servicelearning in Teacher education programmes are that curriculum content should be questioned regarding its relevance in modern day society, how well it prepares pre-service teachers for teaching skills and needs of a rapidly changing economy and society, and that education should take place in an authentic learning environment where community service activities are integrated with the academic curriculum

    Transnational Activities of Women-Focused Civil Society Actors in Southern Africa

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    Since the 1990s, the opening up of democratic spaces has been characterised by growing transnational activities and regionalisation of non-state actors. In Southern Africa, intergovernmental organisations (IGOs) such as the Southern African Development Community (SADC) began to recognise civil society actors and to integrate and prioritise gender and women issues within their policymaking structures. 1 This was assisted by the formulation of norms at a global level which could be diffused to regional and national policies, leading to greater non-state activity in the SADC area. It was achieved through, firstly, the establishment of an eminent group of commissioners in the early 1990s to review the situation of women across the region. Secondly, following the 1995 Beijing International Women’s Conference, a task force was created to draft a Regional Plan of Action to begin to address gendered insecurities across Southern Africa. Finally, the first meeting of the SADC Ministers Responsible for Women and Gender Affairs was convened in 1997 (Made and Morna, 2009: 34)

    Rationalising the retro-Diels-Alder fragmentation pattern of viscutins using electrospray interface-tandem mass spectrometry coupled to theoretical modelling

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    Although mass spectrometry (MS) is a powerful tool in structural elucidation of unknown flavonoids based on their unique fragmentation patterns, proposing the correct fragmentation mechanism is still a challenge from tandem mass spectrometry data only. In recent years, computational tools such as molecular networking and MS2LDA have played a major role in the identification of structurally related compounds through an in-depth survey of their fragmentation patterns

    Rhodes University Calender 2023

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    Rhodes University Calendar for the academic year 2023

    Agricultural disturbance affects taxonomic and functional diversity of Afrotropical macroinvertebrate composition in a South African river system

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    Developing species-level biomonitoring tools to monitor riverine systems threatened by anthropogenic pollution, including local agricultural activities in the Afrotropical region, remain a critical challenge. Here we explored the utility of taxonomic-based (diversity, richness, and composition) as well as functional-based (functional diversity) indices to examine the effects of agricultural disturbance on macroinvertebrate communities in the Kat River, Eastern Cape Province of South Africa. We collected physicochemical parameters and macroinvertebrates from eight sites delineated into four land-use categories (highly impacted, HIC; impacted category, IC; moderately impacted, MIC and least impacted, LIC) using agricultural land cover. We recorded 70 macroinvertebrate taxa belonging to 49 families and 48 genera in the Kat River. Redundancy analysis (RDA) and Pearson correlation analysis revealed that species of Lymnaeidae, Belostomatidae, Planorbidae and Libellulidae families and class Oligochaeta were tolerant to agricultural disturbance, as they were dominant in the highly impacted sites and were significantly associated with high salinity, temperature, total dissolved solids (TDS), flow velocity and nutrients. Conversely, species of Baetidae, Caenidae and Potamonautidae were negatively associated with the highly impacted sites and high salinity, temperature, and nutrients. On the other hand, taxonomic indices showed more sensitivity to indicators of agricultural pollution than functional indices, with taxon richness, Shannon index, Simpson's index and Margalef's index declining significantly in the highly disturbed sites (p less than 0.05). They were negatively associated with high electrical conductivity, large river width, and high nitrite and nitrate concentrations; hence they were identified as indicator metrics sensitive to agricultural pollution. Overall, our study revealed that agricultural disturbance could differentially affect the structure and function of macroinvertebrates, and indicator taxonomic and functional indices were identified for long-term monitoring of rivers that drain agricultural landscapes

    Introducing VET Africa 4.0

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    This book is about vocational education and training (VET). It is concerned with how the current policy and practice orthodoxy is not working despite the efforts of educators and learners. It is driven by a realization that the futures for which VET is intended to prepare people are ever more precarious at the individual, societal and planetary levels. And it is motivated by a sense that while better futures are possible, VET is poorly positioned to respond to the new skilling needs these will require

    South African women’s experience of the decision, procedure and recovery from “feticide” and late termination of pregnancy due to the presence of severe fetal abnormality: women’s and health service providers’ perspectives

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    Routine antenatal care, including sonography and genetic testing, assist healthcare providers in identifying the presence of severe fetal abnormality. In countries where it is legal, the option to abort such a pregnancy may be presented to the pregnant person. When abortion takes place after the thirteenth week of gestation, it is generally referred to as a late termination of pregnancy and may entail the induction of labour or caesarean section. In cases where termination of the pregnancy is decided upon, and the gestation is further than 21 weeks and six days, the feticide procedure is recommended in order to ensure stillbirth. The feticide procedure entails the injection of potassium chloride directly into the fetal heart in order to ensure fetal demise. Existing literature on “feticide” and late termination of pregnancy (LTOP) owing to fetal abnormalities mostly takes a medical or psychological perspective in researching these procedures. Within the South African context, there are very few studies on feticide and LTOP, with none of these studies (to date – 8 January 2023) taking a feminist approach. This paucity of research that takes into account power relations, structural inequality and factors that affect decision-making and choice is one of the reasons that this study was undertaken. The main research question focused on in this study is: What are South African women’s experiences of feticide and late termination of pregnancy due to the presence of severe fetal abnormality, as related by the women themselves and the health service providers who perform the procedure or provide care? The sub-questions that initially drove the study were: How do the women relate their experience of the process of coming to the decision, undergoing and recovering from the procedure, and how do health service providers relate the experiences of these women? The methodological and theoretical framework employed in this research was a Feminist Social Constructionist approach to Grounded Theory. This reflexive, subjectivist, feminist lens encouraged awareness of the influence of gender, race, class and other structural and systemic factors on women’s experiences within the two healthcare systems. Data collection entailed semi-structured interviews conducted with 12 women, who had undergone feticide and LTOP procedures between one and five years prior to the interviews, in either the public or private healthcare system in South Africa. Semi-structured interviews were also conducted with 13 healthcare providers. The providers included medical specialists and participants from the fields of clinical psychology, genetic counselling and nursing and were employed in public or private healthcare in South Africa. Data relevant to public healthcare users and providers were collected from one tertiary (academic) public healthcare hospital and data regarding private healthcare users and providers were collected from across South Africa. Women’s constructions of their experiences of feticide and LTOP included stark contrasts between public and private healthcare users in South Africa, as well as women experiencing “no choice” and their voices being ignored or silenced. Healthcare providers’ constructions were frequently contradictory, referring to women as having freedom of choice and their needs largely prioritised within the healthcare system, while the providers within the public healthcare system relayed their own frustrations and emotional burden due to systemic failures. Findings from women and providers’ constructions were synthesised into a theoretical understanding of women’s experiences of feticide and LTOP in South Africa, which is grounded in, and emergent from, the data. Women’s experiences of feticide and LTOP in South Africa were conceptualised by framing the three phases of these experiences, namely the decision-making phase (I), undergoing the procedures and in-hospital recovery (phase II) and the recovery phase (III). The most prominent themes emerging in these phases included the schism between the public and private healthcare systems in South Africa, the lack of real choice women experience, as well as the silencing of women and providers with regard to feticide and LTOP. Underlying the three phases, and directly influencing the three prominent themes affecting women’s experiences, were the underlying and insidious structural inequality that undermined reproductive justice with regard to women’s decision-making, experiences of and recovery from feticide and LTOP.Thesis (PhD) -- Faculty of Humanities, Psychology, 202

    The electrocatalytic activity of metallophthalocyanines and their conjugates with carbon nanomaterials and metal tungstate nanoparticles

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    In this dissertation, seventeen phthalocyanine complexes were synthesised. Of these, only four are known and have been published. These complexes were synthesised using the conventional statistical condensation method that involves refluxing the phthalonitrile(s) (4-((1,3-bis(dimethylamino)propan-2-yl)oxy)phthalonitrile, 4-(4-carboxyphenoxy)phthalonitrile, 4-(4-acetylphenoxy)phthalonitrile, dimethyl 5-(3,4-dicyanophenoxy)-isophthalate, 4-(4-(tert-butyl)phenoxy)phthalonitrile, 5-phenoxylpicolinic acid phthalonitrile 4-(4-formylphenoxy) phthalonitrile, and 4-(4-(3-oxo-3-phenylprop-1-enyl) phenoxy) phthalonitrile) with the metal salt and 1,8-diazabicyclo[5.4.0]undecane as a catalyst in a high-temperature solvent. And thereafter (when necessary), isolation and purification of the target compounds were achieved through the use of silica column chromatography. These compounds were characterised using various analytical techniques such as; ultraviolet-visible absorption, mass spectroscopy, and Fourier transform infrared spectra and elemental analysis. These techniques proved that the complexes were successfully synthesised and isolated as pure compounds. Carbon-based (graphene quantum dots and nitrogen-doped graphene quantum dots) and metal oxide (bismuth tungsten oxide and nickel tungsten oxide) nanomaterials were synthesised. Together with the purchased single-walled carbon nanotubes, these nanomaterials were conjugated to some of the MPc complexes via non-covalent (carbon-based nanomaterials) and covalent (metal oxides) linkage forming hybrid materials. These nanomaterials and hybrids were characterised using various analytical methods (ultraviolet-visible absorption, X-ray diffraction, Raman spectroscopy, thermographic analysis, and dynamic light scattering). Nanomaterials were utilised herein to determine their effect on the properties of MPc complexes and provide a synergistic effect in the hope of enhancing these properties. All complexes synthesised in this work (MPcs, nanomaterials and hybrids) were employed as electrocatalysts in electrochemical sensing. These electrocatalysts were embedded onto the glassy carbon electrode via an adsorption method known as drop-casting. The modified electrode surfaces were characterised using cyclic voltammetry, electrochemical impedance spectroscopy and scanning electrochemical microscopy to determine various electrochemical parameters. These electrocatalysts were used in the detection of either nitrite, catechol and/or dopamine. The detection limits, sensitivities, kinetics and catalytic constants were among other parameters determined for each electrocatalyst. These electrocatalysts proved to be stable electrocatalysts that could potentially be used for practical applications. The determined parameters were comparable and sometimes better than those obtained in literature.Thesis (PhD) -- Faculty of Science, Chemistry, 202

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