Diffusion Fundamentals (E-Journal)
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Characterizing Interactions of Ionic Liquid Based Electrolytes with Electrospun Gas Diffusion Electrode Frameworks by 1H PFG NMR
Get PDFPulsed field gradient (PFG) 1H NMR was used to characterize the mobility of ionic liquid cations in porous gas diffusion electrode (GDE) frameworks for metal–air electrochemical systems. The carbon GDE frameworks were produced by electrospinning. It was found that the motion of ionic liquids in the highly porous hosts is more complex than what is commonly exhibited by conventional fluids, which makes a multimodal investigation essential for an adequate description of mobility and wetting of GDEs. Observed NMR diffraction-like patterns cannot be linked to the tortuosity limit but may serve as a proxy for structural features in the fibrous material. While the observed data were interpreted using standard theoretical models, alternative explanations and causes for artifacts are discussed
Grain size influence on the release of radioactive isotopes out of target materials made of powder
Get PDFRadioactive ion beam production by Isotope Separator On Line method (ISOL) has motivated the construction of several nuclear facilities over the world. The method consists in impinging solid target material with beams of stable nucleus. Radioactive nuclei produced during the collision are stopped in the target material and must diffuse out of it as fast as possible to transform them into ions before their radioactive decay. The release time must thus be as short as possible to avoid their losses. The release of the nuclei depends on several parameters, which are related to the chemistry of the atoms in the target matrix, to the geometry and micro-structure of the target, and to its temperature. In the case of targets made of grains, we assumed that an optimum grain size of the grains existed. To make possible its easy determination, we aimed to calculate it analytically. Thus we have built a description of the propagation of the atoms in the target material, while conserving the different physico-chemical parameters and avoiding the use of adjustable parameters. The description of the propagation process will be presented as well as the assumptions. Finally, the optimum grain size will be given for the radioactive Ar atoms out of graphite
