WPSphere Repository (William Paterson University)
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Handwritten notes of interview with Nancy Einreinhoffer about Hobart Art Collection.
No full textHandwritten notes of interview with Nancy Einreinhoffer about Hobart Art Collection
Pioneer 2013
No full textThe annual student yearbook was first published in 1925 as "The Kokoon" when William Paterson University was Paterson State Normal School. The title changed over time but has been "The Pioneer" since 1941
Excerpts from oral history of Hobart Manor and manuscript page of speech by Arnold Speert
No full textExcerpts from oral history of Hobart Manor and manuscript page of speech by Arnold Speert
Arnold Speert and unidentified man viewing William Paterson portrait
No full textArnold Speert and unidentified man with hanging William Paterson portrait
Cage versus Prism: Electronic Energies of the Water Hexamer
Get PDFThis document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Physical Chemistry A, copyright © 2013 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://doi.org/10.1021/jp405739d.Recent experiments show that the cage isomer of the water hexamer is lower in energy than the prism isomer near 0 K, and yet state-of-the-art electronic structure calculations predict the prism to be lower in energy than the cage at 0 K. Here we study the relative energies of the water hexamers from the parametric 2-electron reduced-density-matrix (2-RDM) method in which the 2-RDM rather than the wavefunction is the basic variable of the calculations. In agreement with experiment and in contrast with traditional wavefunction methods, the 2-RDM calculations predict the cage to be more stable than the prism after vibrational zero-point correction. Multiple configurations from the hydrogen bonding are captured by the method. More generally, the results are consistent with our previous 2-RDM applications in that they reveal how multireference correlation in molecular systems is important for resolving small energy differences from hydrogen bonding as well as other types of intermolecular forces, even in systems that are not conventionally considered strongly correlated.D.A.M. gratefully acknowledges the NSF under Grant No. CHE-1152425, the ARO under Grant No. W91 INF-1 1-504 1-0085, the Keck Foundation, and Microsoft Corporation for their support.Accepted Manuscript (AM
Hobart Manor front entrance from angle
No full textB/W photograph Hobart Manor facing front entrance. Handwritten notes on reverse: "44, Arcadia Ch. 2". Date is approximate