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Non-destructive methods for mango ripening prediction: visible and near-infrared spectroscopy (visNIRS) and laser Doppler vibrometry (LDV)
Get PDFWith up to 19% of mango fruit being lost during ripening, the need for non-destructive technologies to predict internal physiochemical traits is paramount. This study compared two non-destructive technologies, visible and near-infrared spectroscopy (visNIRS) and laser Doppler vibrometry (LDV), for predicting the ripeness of mango fruit in two cultivars, ‘Kent’ and ‘Keitt’. An internal quality index (IQI) in ‘Kent’ was predicted using visNIRS (RP2 = 0.729, RMSEP = 0.532) using partial least squares regression, which gave a single measure for ripeness incorporating firmness, sweetness, and pulp colour. This model was improved by using the sum of the individual sugar contents (glucose, sucrose, and fructose) over the conventional total soluble solids (TSS) measure. LDV provided poor predictions of firmness (R2 < 0.5) in both ‘Kent’ and ‘Keitt’ using least squares regression line. The resonant frequency, as measured by LDV, decreased linearly with time, while firmness quantified destructively (quasi-static) showed an exponential decrease, suggesting the vibrational and destructive firmness measure distinct characteristics, which would contribute to poor model performance. These results showed that LDV is not suitable for assessing mango ripening. While visNIRS models have been successful at predicting quality traits, our results suggested that using individual sugar content in place of TSS can improve the prediction of ripening. This understanding of the strengths and limitations of both visNIRS and LDV, and how they relate to destructive quality measurements, can be used to improve postharvest management practices whilst reducing commercial losses in the mango industry.Postharvest Biology and Technolog
Impact of environmental conditions on the concentrations of trichothecenes, their glucosides, and emerging fusarium toxins in naturally contaminated, irradiated, and fusarium iangsethiae inoculated oats
Get PDFTrichothecenes produced by Fusarium species are commonly detected in oats. However, the ratios of the concentrations of free trichothecenes and their conjugates and how they are impacted by different interacting environmental conditions are not well documented. This study aims to examine the effect of water activity (0.95 and 0.98 aw) and temperature (20 and 25 °C) stress on the production of T-2 and HT-2 toxins, deoxynivalenol and their conjugates, as well as diacetoxyscirpenol (DAS). Multiple mycotoxins were detected using liquid chromatography–tandem mass spectrometry from 64 contaminated oat samples. The highest concentrations of HT-2-glucoside (HT-2-Glc) were observed at 0.98 aw and 20 °C, and were higher than other type A trichothecenes in the natural oats’ treatments. However, no statistical differences were found between the mean concentrations of HT-2-Glc and HT-2 toxins in all storage conditions analysed. DAS concentrations were generally low and highest at 0.95 aw and 20 °C, while deoxynivalenol-3-glucoside levels were highest at 0.98 aw and 20 °C in the naturally contaminated oats. Emerging mycotoxins such as beauvericin, moniliformin, and enniatins mostly increased with a rise in water activity and temperature in the naturally contaminated oats treatment. This study reinforces the importance of storage aw and temperature conditions in the high risk of free and modified toxin contamination of small cereal grains.Toxin
Aerodynamic performance of a flyable flapping wing rotor with dragonfly-like flexible wings
Get PDFDrawing inspiration from insect flapping wings, a Flapping Wing Rotor (FWR) has been developed for Micro Aerial Vehicle (MAV) applications. The FWR features unique active flapping and passive rotary kinematics of motion to achieve a high lift coefficient and flight efficiency. This study thoroughly investigates the aerodynamic performance and design of a bio-inspired flexible wing for FWR-MAVs, emphasizing its novel backward-curved wingtip and variable spanwise stiffness resembling a dragonfly's wing. The research departs from previous aerodynamic studies of FWR, which focused predominantly on rectangular and rigid wings, and delves into wing flexibility. Employing Computational Fluid Dynamics (CFD), Computational Structural Dynamics (CSD), and experimental measurements, the study demonstrates the aerodynamic benefits of the dragonfly-inspired FWR wingtip shape and its reinforced structure. Fluid-Structure Interaction (FSI) analysis is used to examine the effects of elastic deformation encompassing twist and bending on aerodynamic forces. The results underscore the importance of bending deformation in enhancing lift and power efficiency and propose a method for analysing variable stiffness along the wingspan using a vortex delay mechanism that is induced by delayed flapping motion. By comparing modelled and measured stiffness, the study validates the flexibility of the FWR wing, revealing optimal aerodynamic efficiency is achieved through moderate flexibility and spanwise stiffness variation. The curving leading-edge beam forming the sweep-back wingtip offers a practical approach to obtaining variable stiffness and aerodynamic benefits for FWR-MAVs. Using the same pair of dragonfly-like flexible wings, FWR-MAVs have effectively exhibited VTOL and hovering flight capabilities, spanning from a 25-g single-motor drive model to a 51-g dual-motor drive model. This research provides valuable insights into flexible wing design for FWR-MAVs, leveraging biomimicry to improve flight efficiency.Aerospace Science and Technolog
Implicit and conventional large eddy simulation of flow around a circular cylinder at Reynolds number of 3900
Get PDFThe implicit Large Eddy Simulation (iLES) incorporating an unstructured 3rd-order Weighted Essential Non-Oscillatory (WENO) reconstruction method and the conventional Large Eddy Simulation with Wall Adapting Local Eddy-Viscosity (WALE) are investigated on the flow around a circular cylinder at a Reynolds number of 3900. Simulations are carried out in the framework of open-source package OpenFOAM with a 2nd-order Euler implicit time integration and Pressure-Implicit Splitting-Operator (PISO) algorithm is used for the pressure-velocity coupling. The results are compared to the high fidelity experiment and DNS data, and demonstrated a favourable performance for iLES with a 3rd-order WENO scheme on the instantaneous flow structure. The conventional LES on the prediction of mean surface pressure coefficient and velocity profiles on the wake can be beneficial by reducing the effect of Rhie-Chow interpolation. The spectral analysis reveals that the current simulations are also capturing Von Karman shedding frequencies and shear layer frequencies. Finally, distinct features of iLES and LES are discussed.AIAA SCITECH 2024 Foru
Reactive media constructed wetland for phosphorus removal: assessing the opportunity and challenges
Get PDFReactive media present an alternative to gravel in constructed wetlands and have the potential to sustainably and efficiently remove phosphorus from wastewater. In this study, a full-scale steel slag wetland has been operated for its whole lifecycle at which 1.39 mg P/g media were retained. During its lifecycle, this wetland met strict consents below 0.5 mg P/L for the first 6 months and was operated for 266 and 353 days before the effluent phosphorus concentration rose above the typical consents of 1 and 2 mg P/L, respectively. A detailed analysis of the system demonstrated that the performance was directly associated with the release of materials from the media into the water which in turn affected other critical parameters such as pH. Further analysis of the media suggested that greater understanding was needed concerning the role of carbonates and in particular calcite if steel slag is to be effectively managed for use on constructed wetlands. Importantly, controlled release of calcium oxide from the media surface is required by managing the concerns of pH and vanadium release.Severn Trent Water. In addition, some of the work reported here was part of the AquaNES project which has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement no. 689450.H2Open Journa
Mobile robot obstacle detection and avoidance with NAV-YOLO
Get PDFIntelligent robotics is gaining significance in Maintenance, Repair, and Overhaul (MRO) hangar operations, where mobile robots navigate complex and dynamic environments for Aircraft visual inspection. Aircraft hangars are usually busy and changing, with objects of varying shapes and sizes presenting harsh obstacles and conditions that can lead to potential collisions and safety hazards. This makes Obstacle detection and avoidance critical for safe and efficient robot navigation tasks. Conventional methods have been applied with computational issues, while learning-based approaches are limited in detection accuracy. This paper proposes a vision-based navigation model that integrates a pre-trained Yolov5 object detection model into a Robot Operating System (ROS) navigation stack to optimise obstacle detection and avoidance in a complex environment. The experiment is validated and evaluated in ROS-Gazebo simulation and turtlebot3 waffle-pi robot platform. The results showed that the robot can increasingly detect and avoid obstacles without colliding while navigating through different checkpoints to the target location.International Journal of Mechanical Engineering and Robotics Researc
Governance in a crisis and the decision to replace the project manager
Get PDFThis article explores the concept of governance behaviors during project crises, which demand rapid responses. Grounded in the Cynefin model for decision-making and inspired by Iftikhar et al., (2021), we sought to explore in greater detail the challenge of a particular and common response to crisis: project manager replacement. We address governance as essentially a two-level function: sensemaking under crisis conditions and offering guidance within the critical early stages of project manager replacement, when the need for governance is crucial. Finally, this article offers some guidance for the employment of governance within different Cynefin complexity domains for maximizing effective replacement steps
Improving wave energy conversion performance of a floating BBDB-OWC system by using dual chambers and a novel enhancement plate
Get PDFIn this study, a novel floating dual-chamber backward bent duct buoy oscillating water column (BBDB-OWC) wave energy converter (WEC) is introduced, featuring a horizontal plate at the bottom of the front chamber to act as an enhancement plate. A three-dimensional computational fluid dynamics (CFD) model is developed and validated by comparing its results with existing experimental measurements. The validated model is employed to investigate the hydrodynamic performance and power generation characteristics of the dual-chamber BBDB-OWC WEC under various conditions, including variations in the length of the horizontal plate (lp/lf) and different regular wave conditions. Key performance metrics, including peak to average ratio of power (PTARP), wave energy capture width ratio (ξtotal), and its wave period respond bandwidth (indicated by Pξtotal > 0.5 and Pξtotal > 0.7), are analyzed and compared with those of a traditional single-chamber BBDB-OWC WEC. The results reveal that, compared to the single-chamber WEC, the dual-chamber WEC with a specific horizontal plate length reduces the average PTARP from 2.88 to a minimum value of 1.82 for lp/lf = 0.5, improves the average ξtotal from 0.55 to a maximum value of 0.64 for lp/lf = 2.5, and increases Pξtotal > 0.5 and Pξtotal > 0.7 from 71 % and 14 % to maximum values of 86 % and 43 % for lp/lf = 2.5, respectively. An explanation for these observations is also provided in the context of structure motion and flow fields.Luofeng Huang acknowledges the Royal Society (Grant No. IEC∖NSFC∖223253, RG\R2\232462).Energy Conversion and Managemen
Moving towards a mechanistic understanding of biostimulant impacts on soil properties and processes: a semisystematic review
Get PDFBiostimulants are gaining prominence in scientific research, with the potential to enhance plant productivity through benefits to crop yield/quality and tolerance to environmental stresses. Through possible improvements to nutrient use efficiency, they may also lessen the adverse environmental impacts of conventional inorganic fertilizer use in agriculture. The application of biostimulants is currently uncommon as a farming practice, with uncertain effectiveness in delivering these potential benefits. Current research focuses on biostimulant effects on plant physiological changes. There is little scientific evidence on the impact of biostimulants on soil properties (biological, physical, or chemical) or soil functions. This knowledge gap should be addressed considering the vital role of soil processes in the bioavailability of nutrients, as reflected in crop productivity. This review evaluates laboratory and field experimental work on the effectiveness of common, non-microbial biostimulants, with a focus on their modes of action within the soil matrix. Of 2,097 initial articles returned through the search strings, 10 were within the scope of this review. A common soil biostimulant mechanism emerges from this literature. This relates to the supply of nutrients provided by the biostimulants, which stimulate native soil microbiology in mineralizing organic material in the soil, thus producing more bioavailable nutrients for plant uptake. Additionally, some articles link biostimulant effects to soil physical and chemical changes, which in turn impact soil biology (and vice versa). However, there is inconsistent evidence to provide full support for these explanatory mechanisms. This review highlights the need for further research into the effect of biostimulants on the native soil microbiology and associated soil properties, to provide greater clarity on biostimulants’ modes of action and greater mechanistic insights into how they can be used to improve crop production.This research was funded by UKRI BBSRC FoodBioSystems Doctoral Training Partnership (DTP) and Sainsbury’s, grant number BB/T008776/1.Frontiers in Agronom
Synthesis, structure characterization, Hirshfeld surface analysis, and computational studies of 3-nitro-1,2,4-triazol-5-one (NTO):acridine
Get PDFTo modify the physical features and extend applications of the 3-nitro-1,2,4-triazol-5-one (NTO), we synthesized NTO with acridine (ACR) at a molar ratio of 1:1, a neutralization reaction. Through altering the chemical composition, it was possible to alter physical properties such as thermal stability, free space (voids), packing coefficient, crystal density, difference in pKa of co-formers, morphology, solubility, and impact sensitivity, and detonation parameters . It appears that physical attributes could be entirely altered. Single-crystal and powder X-ray diffraction methods, infrared spectroscopy, mass spectrometry, nuclear magnetic resonance spectroscopy (1H-NMR and 13C-NMR), and thermal analysis were utilized to comprehensively characterize and confirm the formation of the structure of NTO:ACR. The substantial hydrogen bond interactions and planar layered structures observed between the cations and anions generated a complex 3D network, providing insight into the structure–property interrelationship. One intriguing feature discovered is the layered structure present in NTO:ACR, which may be responsible for the low impact sensitivity. According to the experimental results, NTO:ACR showed good thermal stability (Td = 229 °C) and outstanding impact sensitivity (IS = 100 J). Detonation velocity and pressure were calculated using the EXPLO5 software program and found to be 7006 m·s−1 and 20.02 GPa, respectively.This study was funded by the Scientific and Technological Research Council of Türkiye-TUBITAK-BIDEB 2219-International Postdoctoral Research Fellowship Program (Grant number:1059B192100006).Structural Chemistr