Kansas State University Salina Aerospace and Technology Campus
K-State Research ExchangeNot a member yet
43997 research outputs found
Sort by
Faculty Brass Quintet, Faculty Artist Recital
No full textApril 9, 2019
7:30pm
All Faiths Chapel
J. S. Bach - Coffee Cantata, "Ah, How Sweet Coffee Tastes"
Aaron Copland - Old American Songs: I. Simple Gifts, II. Zion's Walls, III. At the River
Eugene Zador - Brass Quintet: I. Preludium, II. Hungarian Scherzo, III. Peasant Dance, IV. Song, V. Rondo-Finale
Victor Ewald - Brass Quintet No. 2 in E-flat major, Op. 6: I. Allegro risoluto, II. Thema con variation, III. Allegro vivace
Hanley Jackson - Jubilate Deo for chorus, brass quintet, and percussio
Sorghum Carotenoid Variation
Get PDFPurpose The purpose of this research is to understand the heritability and genetic controls of sorghum grain carotenoids in order to develop a biofortification plan. Hypothesis and Predictions • Hypothesis 1: Carotenoids in a genetically diverse sorghum association panel grown in a temperate humid environment are highly heritable. o Prediction 1: There will be a significant correlation in carotenoid content between sorghum grown in 2015 and 2016 measured by high-performance liquid chromatography (HPLC). o Prediction 2: Genome-wide association studies (GWAS) will identify some of the same quantitative trait loci (QTL) in each year, in particular zeaxanthin epoxidase (ZEP)
Dissociation dynamics of molecular ions in ultrafast, intense laser fields: from diatomic to polyatomic molecules
Get PDFDoctor of PhilosophyDepartment of PhysicsItzik Ben-ItzhakOut of the many tools for probing molecular dynamics, intense, ultrafast laser pulses are particularly well suited for this purpose. First, these pulses have temporal durations shorter than the typical rotational and vibrational periods of molecules and therefore allow the observation of molecular dynamics on their native timescales. Further, the broad bandwidth and high peak intensities of these laser pulses can result in the excitation of many transition pathways that may interfere and enable control of dynamics.
The primary focus of this work is the ultrafast laser-induced dissociation of molecular ions. We generate these ions as “fast” beam targets and study their fragmentation using a coincidence three-dimensional (3D) momentum imaging technique, which allows the measurement of all nuclear fragments, including neutrals. This approach is employed to study laser-induced processes in a variety of molecules. The goal of these efforts is not to study specific molecules but rather to use them as testing grounds to deepen our knowledge of laser-induced molecular dynamics in general.
For example, we find that permanent-dipole transitions, which are commonly overlooked in the interpretation of strong-field experiments, play a key role in laser-induced dissociation of metastable NO²⁺ ions. General consideration of these transitions in heteronuclear molecules is important in building our understanding towards more complex molecules. Speaking of more complex systems, we have also begun investigating the laser-induced dynamics of simple hydrocarbons. Our use of molecular ion beam targets gives us the unique ability to exercise control over the initial “configuration,” i.e., geometry of these molecules. Utilizing C₂H₂^q ion beam targets (where q is the molecular ion charge state) prepared in various initial configurations, including acetylene (HCCH), vinylidene (H₂CC), and cis/trans, we have determined that this property has an immense impact on the isomerization dynamics, a finding that we anticipate will lead to future work towards deeper understanding. More broadly, this approach of probing molecules in different initial configurations offers a unique perspective that could be complementary to mainstream methods—not just in the case of C₂H₂ but other chemical systems as well.
We also describe some improvements to the 3D momentum imaging methods that facilitate the study of molecular dynamics. One of these developments is a method to distinguish and evaluate the momenta of neutral-neutral channels resulting from the fragmentation of negative ion beams. The second is a technique for imaging the breakup of long-lived metastable molecules decaying in flight to the detector and retrieving the lifetime(s) of the populated states.
Our collaborative efforts in adaptive closed-loop control are also discussed. Here, an evolutionary learning algorithm supplied with experimental feedback obtains optimally-shaped ultrashort laser pulses for driving targeted molecular dynamics. While the complexity of the shaped pulses can make interpretation challenging, the combination of these efforts with basic experiments like those we perform using ion beams can help.
In closing, the work presented in this thesis extends from diatomic to polyatomic molecules, following the natural progression of building from simpler to more complex systems. We believe that the results of these efforts aid in the advancement of understanding strong-field molecular dynamics and will stimulate future research endeavors along these directions
Self referencing attosecond interferometer with zeptosecond precision
Get PDFIn this work we demonstrate the generation of two intense, ultrafast laser pulses that allow a controlled interferometric measurement of higher harmonic generation pulses with 12.8 attoseconds in resolution (half the atomic unit of time) and a precision as low as 680 zeptoseconds (10−21 seconds). We create two replicas of a driving femtosecond pulse which share the same optical path except at the focus where they converge to two foci. An attosecond pulse train emerges from each focus through the process of high harmonic generation. The two attosecond pulse trains from each focus interfere in the far field producing a clear interference pattern in the extreme ultraviolet region. By controlling the relative optical phase (carrier envelope phase for pulsed fields) between the two driving laser pulses we are able to actively influence the delay between the pulses and are able to perform very stable and precise pump-probe experiments. Because of the phase shaping operation occurs homogeneously across the entire spatial profile, we effectively create two indistinguishable intense laser pulses or a common path interferometer for attosecond pulses. Commonality across the two beams means that they are extremely stable to environmental and mechanical fluctuations up to a Rayleigh range from the focus. In our opinion this represents an ideal source for homodyne and heterodyne spectroscopic measurements with sub-attosecond precision
Spatiotemporal analysis of a final-state shape resonance in interferometric photoemission from Cu(111) surfaces
Get PDFPhotoemission from solid targets includes the excitation and motion of electrons inside the substrate, followed by their propagation in vacuum and detection. It thus depends on the electronic band structure of the solid in the two distinct spectral domains of bound initial and continuum final states. While the imprint of the static (initial-state) valence electronic structure of solids on photoemission spectra is routinely examined in standard photoemission spectroscopy in the energy domain, state-of-the-art time-resolved photoelectron spectroscopy allows, in addition, the scrutiny of photoelectron propagation in the electronic continuum. Within a quantum-mechanical model for attosecond time-resolved interferometric photoelectron emission from solids, we calculated photoemission spectra as a function of the delay between the exciting primary attosecond pulse train and assisting infrared (IR) laser pulse. Accounting for final-state interactions of the photoelectron with the IR laser electric field and the periodic substrate, our numerical results for interferometric photoemission from the 3d-valence band of Cu(111) surfaces show a striking resonantly enhanced sideband yield at photoelectron kinetic energies near 24eV, in conjunction with a pronounced increase of the photoelectron wave-function amplitude inside the solid on a length scale of a few nanometers. This resonant shift of final-state photoelectron-probability density towards the bulk can be interpreted as an increase in the photoelectron propagation time in the solid and is commensurate with the resonantly enhanced spectral sideband-phase shifts observed in recent two-pathway two-photon interference spectra by Kasmi et al. [Optica 4, 1492 (2017)]
Evidence of Extreme Ultraviolet Superfluorescence in Xenon
Get PDFWe present a comprehensive experimental and theoretical study on superfluorescence in the extreme ultraviolet wavelength regime. Focusing a free-electron laser pulse in a cell filled with Xe gas, the medium is quasi-instantaneously population inverted by 4d-shell ionization on the giant resonance followed by Auger decay. On the timescale of ∼10 ps to ∼100 ps (depending on parameters) a macroscopic polarization builds up in the medium, resulting in superfluorescent emission of several Xe lines in the forward direction. As the number of emitters in the system is increased by either raising the pressure or the pump-pulse energy, the emission yield grows exponentially over four orders of magnitude and reaches saturation. With increasing yield, we observe line broadening, a manifestation of superfluorescence in the spectral domain. Our novel theoretical approach, based on a full quantum treatment of the atomic system and the irradiated field, shows quantitative agreement with the experiment and supports our interpretation
Imaging an isolated water molecule using a single electron wave packet
Get PDFObserving changes in molecular structure requires atomic-scale Ångstrom and femtosecond spatio-temporal resolution. We use the Fourier transform (FT) variant of laser-induced electron diffraction (LIED), FT-LIED, to directly retrieve the molecular structure of H2O+ with picometer and femtosecond resolution without a priori knowledge of the molecular structure nor the use of retrieval algorithms or ab initio calculations. We identify a symmetrically stretched H2O+ field-dressed structure that is most likely in the ground electronic state. We subsequently study the nuclear response of an isolated water molecule to an external laser field at four different field strengths. We show that upon increasing the laser field strength from 2.5 to 3.8 V/Å, the O–H bond is further stretched and the molecule slightly bends. The observed ultrafast structural changes lead to an increase in the dipole moment of water and, in turn, a stronger dipole interaction between the nuclear framework of the molecule and the intense laser field. Our results provide important insights into the coupling of the nuclear framework to a laser field as the molecular geometry of H2O+ is altered in the presence of an external field
Tracing intermolecular Coulombic decay of carbon-dioxide dimers and oxygen dimers after valence photoionization
Get PDFWe have conducted an experimental study on the photo double ionization (PDI) of carbon-dioxide dimers at photon energies of 37 and 55 eV and oxygen dimers at photon energies of 38, 41.5, and 46 eV, while focusing on the dissociation dynamics upon single-photon absorption. The investigation was performed by applying the cold-target recoil-ion momentum spectroscopy method in order to collect and record the three-dimensional momenta of the ionic fragments and emitted electrons from the dissociating dimer in coincidence. The kinetic-energy release upon fragmentation and the electron angular distributions in the laboratory and body-fixed frames, as well as the relative electron-electron emission angle, show unambiguous experimental evidence of intermolecular Coulombic decay (ICD) in carbon-dioxide dimers upon photoionization below and above the double-ionization threshold of CO2 monomers. The PDI of oxygen dimers is less conclusive and shows contributions from ICD and knock-off ionization mechanisms. As for atomic dimers, the present results reveal that ICD in CO2 dimers after valence PDI can also serve as a source for low-energy electrons, known to be very relevant in biological systems, cells, and tissues
Destination personality: how to make the metaphor simpler?
Get PDFCitation: Lin, N., & Roberts, K. R. (2019). Destination personality: how to make the metaphor simpler? Anatolia, 0(0), 1–12. https://doi.org/10.1080/13032917.2019.1588758A well-established destination personality facilitates differentiation of destinations and helps to create emotional loyalty and increase repeat visitors. Although destination personality and brand marketing have become increasingly important, there is still a lack of applied research that simplifies the salient dimensions of destination personality. This study applies parsimony analysis to help establish the simplest possible determination of destination personality to identify the top destination personality traits of Kansas. Participants (N = 209) were recruited by an online marketing company, and descriptive statistics, Garrett ranking analysis, and Mann-Whitney U-tests were conducted. The top brand personalities of Kansas identified amongst all visitors included hardworking and reliable. Compared to first-time visitors, repeat visitors perceived Kansas as contemporary, outdoorsy, and less sincere
Accuracy of hay moisture sensing systems for round alfalfa bales
Get PDFMaster of ScienceDepartment of Biological & Agricultural EngineeringAjay ShardaMoisture measurement is critical when baling alfalfa into round bales for feed. If alfalfa is too wet or too dry, it can greatly diminish the alfalfa crop’s feed quality and cause economic loss to producers. Therefore, monitoring of alfalfa moisture content while baling is critical for producers to maintain hay quality and maximize profits. Currently, there are several different types of moisture sensing technologies available for round balers. But, concerns exist regarding their accuracy and repeatability during hay baling. Therefore, objectives of this project are to 1) Establish a protocol for coring methodology to assess the variation of moisture within a round alfalfa hay bale, and 2) Compare and contrast sensing accuracy and repeatability of different hay moisture sensing technologies. A coring methodology was established to determine the average moisture within a round bale based upon the way a sensor in a round baler chamber would determine the bale moisture; by looking at the moisture contents along the round bale diameter. This method was then compared with the more traditional method of using radial cores only to determine the whole bale moisture content. A sensor testing stand was developed to perform comparative testing between the sensors on the same alfalfa hay bale and collect core samples of material immediately after it was formed. Six commercially available moisture sensors were selected to measure moisture at four pre-determined locations on hay bales. After the sensor measurements, core samples were extracted from the exact same locations to determine actual moisture using oven-drying method. The moisture measurements were conducted during three growth stages and bales were formed with three approximate moisture contents of 10%, 15% and 20%. Six different cuts of alfalfa of the same variety were used to capture all the measurements. A seventh cut was also performed for moisture measurements with the alfalfa baled at 15% and the same growth stage, but different baler compression cylinder pressures (250, 400, and 800psi). Actual moisture content was across different sampling locations were compared to understand moisture distribution and establish coring protocol. Sensor and oven-dried measurements were compared to determine accuracy and repeatability of sensing technologies. Results showed that sensors and oven-dried measurement varied for all the sensors for every growth stage and baling moisture levels, with one sensor exhibiting lowest variability in its readings. The comparison identified the most accurate and reliable sensor among the ones currently available. A second year of testing was also conducted to validate the research from the first year of testing. Future research needs to be conducted to identify correlation between the testing stand readings and actual hay baler moisture sensor readings