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    A geochemical study of gallium, germanium and indium, in sulfide mineralisation of the Kombat, Tsumeb and Khusib springs deposits, Otavi Mountain Land, Namibia

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    A dissertation submitted in fulfillment of the requirements for the Degree of Doctor of Philosophy in Science (Geology)Carbonate-hosted base metal deposits are known to contain significant contents of critical metals such as Ga, Ge, and In. These metals occur mainly as inclusions or incorporated within the crystal lattice of the main sulfide minerals while they form rarely discrete minerals. The aim of this Doctor of Philosophy (PhD) study is to determine the geochemical characteristics of the critical raw metals that are associated with the sulfide mineralisation of the base metal deposits of the Otavi Mountain Land, with the emphasis on the Tsumeb, Kombat and Khusib Springs deposits. Tsumeb mine is an over the decades exploited breccia-pipe like polymetallic deposit, hosted by Neoproterozoic dolomite and limestones in the Otavi Group of the Damara Orogenic Belt. Exploitation took place between 1897 and 1996, with a production of about 30 Mt of ore, yielding 1.7 Mt Cu, 2.8 Mt Pb, 0.9 Mt Zn, and 80 t Ge. Mineralisation at this deposit consists of tennantite and sphalerite as the most abundant ore minerals, associated with galena, pyrite, bornite, chalcocite, digenite, and minor enargite, renierite, germanite, chalcopyrite, and traces of various arsenates. Kombat deposit, which is a stratabound, syntectonic Cu-Pb (Ag) sulfide deposit, is hosted in the dolomite of the Hüttenberg Formation, Otavi Group. Mining of the Kombat deposit is currently ongoing, with a total endowment of approximately 13.6 Mt, of which 12 Mt has been exploited until 2008. The ore mineralisation of the Kombat deposit is quite variable comprising massive, disseminated, veinlet-controlled, and brecciated mineralisation styles with abundant bornite, chalcopyrite, galena, covellite, and chalcocite set into quartz-calcite gangue. Khusib Springs deposit is a high-grade Cu-Pb Zn deposit which is classified as a “Tsumeb-type deposit”, hosted by Neoproterozoic dolomite, limestone and phyllites of the Maieberg Formation, Otavi Group. The main aim of this study is to show the siting of the most important minor and trace elements in the diverse sulfide mineral phases and to highlight the relationships between common trace elements and critical metals within the sulfide mineral phases. Various analytical techniques, including laser ablation inductively coupled plasma spectrometry (LA-ICP MS), electron microprobe analysis (EPMA), inductively coupled plasma mass spectrometry (ICP-MS), and X-ray fluorescence (XRF), were employed to study the bulk ii geochemistry and the siting of the trace elements, for the sole purpose of answering the above-mentioned objectives. Additionally, portable X-ray fluorescence (pXRF) technique was utilized with the aim of evaluating the possible usability of a low-cost analytical technique in exploration for base and critical elements in carbonate-hosted sulfide mineralisations. The Kombat mineralization comprises three mineral assemblages (1) bornite-chalcopyrite-covellite, (2) bornite-galena-chalcocite, and (3) bornite-chalcopyrite, set into dolomite-quartz-calcite gangue, with chalcopyrite identified as the main carrier of Ga, Ge, and In in this deposit. The profound micro-analysis of Tsumeb ore revealed the presence of both Ga and Ge, associated with trace elements (Ag, As, Cd, Co, Cu, Fe, Ga, Ge, In, Ni, Pb, Sb, Zn), in the different sulfides. The most significant carriers of Ge are renierite (av. 8.21 wt.%) and enargite (0.78 wt.%), while Ga is mainly incorporated into renierite (av. 0.12 wt.%) and sphalerite (av. 0.11 wt%). Trace element abundance in sphalerite is characterized by elevated Cd, Ge, and Ga, suggestive of low formation temperatures, which corroborates with earlier research on the formation of Tsumeb ore. Reconnaissance Zn isotope data (-0.19 to 0.14‰) delineate Tsumeb ore as typical Zn-rich massive sulfide ore, with Zn isotope values overlapping with those of the Irish MVT deposits (-0.17 to 1.33‰), while Cu isotopes are comparable to isotopic data of hypogene mineralisation. In Khusib Springs ore, tennantite (Fe, Zn, Ag, Sb) and chalcopyrite (Cu, Pb, Ag) are the most important carriers of trace elements while all other sulfides are characterized by a surprisingly low trace element content. In contrast, Khusib Springs massive ore reveals a wealth of Ag-bearing minerals of the pearceite-polybasite mineral group. Modern portable tools are successfully applied for the analyses of selected elements in various fields. Portable XRF can be used as well for the analyses of selected elements (Cu, Fe, Mn, Pb, Zn) in Kombat-type ore, while these instruments fail for the analyses of elements like Ag, Sr, and, in particular, for the analyses of the target elements Ga, Ge, and In. Therefore, this study gives a detailed overview about the relationship between critical elements Ga, Ge, and In and associated elements in sulfide ores in the carbonate-hosted base metal deposits of the Otavi Mountain Land, while showing at the same time the limitations when access to modern analytical technologies is limite

    The effect of different processing methods on the nutritional, anti-nutritional and emulsifying properties of inoculated and no-inoculated Bambara groundnut (Vigna subterranea) cultivars

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    A thesis submitted in fulfilment of the requirements for the Master of Science in Agriculture (Food Science and Technology)Bambara groundnut (Vigna subterranea) is one of the Namibian underutilised legumes that provides protein, carbohydrates, fats, potassium, magnesium, phosphorus, zinc and iron. Several researchers suggest that Bradyrhizobium inoculation has the capacity to improve nutritional composition of Bambara groundnut. This study evaluated the effects of processing on the nutritional composition, anti-nutritional factor (ANF) and emulsifying property of inoculated and non-inoculated cream, brown and red Bambara groundnut cultivars that were grown in Namibia. The cultivars were roasted for 15, 30 and 45 minutes at a temperature of 140°C respectively and boiled for 30 minutes in a solution of 0.5g/100mL of sodium bicarbonate, sodium chloride, and magnesium sulphate respectively. The beans were blended to flours and analysed. Results indicate that each boiling salt has a unique effect on each nutritional component. Certain nutritional composition increased with an increase in roasting time. Bambara groundnut inoculated with Bradyrhizobium had higher protein and emulsifying properties. Fat content of all inoculated Bambara groundnut was lower after processing. Red Bambara groundnut had the highest fat and protein while brown and cream Bambara groundnut had a higher crude fibre and carbohydrate. Non-inoculated Bambara groundnut had lower minerals compared to other Bambara groundnut reported in other studies. Tannins could not be detected in the Bambara groundnut experimented in this stud

    A geochemical baseline study of giant kelp (macrocystis pyrifera) at the kelp blue farm to assess carbon sequestration potential

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    A thesis submitted in fulfilment of the requirements for the Degree of Master of Science (Chemistry)The raised levels of carbon dioxide (CO2) in the earth’s atmosphere have contributed to global climate change, which has adversely affected a wide range of individuals, communities, and organizations. One of the ways to mitigate climate change is to grow a huge amount of kelp forests that can absorb carbon dioxide from the atmosphere and sequester it in the deep ocean. To grow these forests, the right biogeochemical conditions (temperature, nutrients, oxygen, salinity, pH, trace metals and ions) within the ocean is vital to assess the sequestration potential and the impacts on the ocean health. This study aimed at monitoring the biogeochemical changes at the proposed Kelp Blue farm and surrounding areas further away from the farm. This study also aims to create a baseline of the chemical composition of the farm and Lüderitz areas, which has not been done before. Using the results obtained from the study, the potential of the cultivated giant kelp to sequester CO2 will be evaluated. This study measured the geochemical parameters using both in-situ probes and laboratory analyses at 10 different locations in Lüderitz (both offshore and coastal): offshore (within the Kelp Blue Pilot project farm, upstream of the farm in the Dumfudgeon rocks, downstream of the farm at Boot Bay and further south of Lüderitz at the Halifax island) and the coastal areas which are adjacent to the offshore study areas including at coastal site of Guano Bay which is about 17 km and the coastal area of Grossebucht which is about 20 km south the town of Lüderitz as another control site. This study also collected sediment samples at these offshore sites including further north of Walvis Bay at the different latitudinal transects. The sediments were analysed for trace metals by using a portable XRF and for carbon content by LOI (Loss on Ignition) method. Another geochemical analysis done was the titrimetric method to CO2 determination of seawater by using NaOH as a titrant the end points were determined. The concentrations of nutrients (phosphates and nitrites) in seawater samples were determined by adding them to a 10 mL cuvette, which had been zeroed first. A specific nutrient reagent was then introduced, and using ii prescribed sample preparation techniques, a spectrophotometer was employed to measure the concentrations of the nutrients in µg/L and mg/L. The geochemical parameters changed in relation to the seasonality and geographical positioning. In a season when the upwelling system was strong, the concentration of nutrients, acidity and the value of the pH, salinity, other geochemical parameters increased more, compared to other seasons and the further southern sampling sites resembled to that of the Southern Benguela Upwelling System (SBUS). Higher concentrations of phosphates (614 µg/L) were found in areas close to the islands. This is due to the presence of guanos. These remarkable long duration geochemical measuring results shows that the cultivated kelp can co-exist with other natural existing kelp beds in this ecosystem, and they can thrive more predominantly in season of great influx of nutrients during the season of strong winds. With a dynamic Benguela upwelling eastern boundary, these kelp forests have an enormous potential to grow more and will function as carbon absorber and eventually sequester more carbon when cultivated at larger scale. To quantify the carbon sequestration potential of these giant kelps, there are other areas to be investigated such as developing a sediment carbon baseline using isotopic analyses, lipid biomarkers, identifying sediment hotspots where the kelp will be deposited, developing a carbon dioxide removal model and geochemical dispersion models. All these other areas will be developed from the baseline being developed by this study. This study recommends that a continuous and rigorous monitoring of the water and sediment geochemical changes be done as the kelp forest grows and as the scale of operation expand

    Sustainable bioeconomy for next-generation industrial ecology

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    The sustainable bioeconomy is becoming an increasingly important aspect of industrial ecology as we seek to reduce our dependence on finite resources and shift toward more sustainable production and consumption practices. In this chapter, we explore the principles of sustainable bioeconomy and their application in next-generation industrial ecology. We discuss the use of bio-based feedstocks in industrial processes, sustainable manufacturing processes, circular economy and industrial symbiosis, and the importance of social and environmental responsibility in the bioeconomy. Finally, we examine the future directions of sustainable bioeconomy, including technological advancements, policy and regulatory frameworks, and collaboration and partnership

    Exploring time-travel in children’s literature: The case study of when you dance with the crocodile by Erna Muller and crusade in jeans by Thea Beckman

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    A thesis submitted in full fulfilment of the requirements for the degree of master of arts in english studiesThis thesis provides a comparative analysis of the novels When you Dance with the Crocodile (2012) by Erna Muller and Crusade in Jeans (1973) by Thea Beckman. The two novels were purposefully selected because they primarily characterise children or young people as protagonists. Additionally, the novels were selected because of the recurring themes of historical time travel. The major objectives of the study were to analyse the presentation of historical time travel elements in the selected novels and to explore the different methods of time travel used in both novels. This was done through the theory of narratology and mythology. The study then employed a qualitative desktop analysis, and data was analysed using a thematic content analysis, which was systemised into different themes to ease the data analysis and presentation process. The study observed that although the themes in both novels are similar, each novel presents the themes in a unique manner. In Crusade in Jeans (1973), it was found that historical time travel embarked on by the protagonists was a result of a scientific experiment with the hope of providing results and answers to scientific questions pertaining to time travel beyond human comprehension. On the other hand, historical time travel in When you Dance with the Crocodile (2012), accidentally happens with the main characters not knowing they would be going back in time, but just playing a computer game, and this consequently provides an opportunity for a nuanced scientific discovery from video game experiments. Among the themes that emerged in the study are child endangerment, credulity in religion and tradition, and magic and heresy. Further research recommendations are to employ a rhetorical theory analysis to futuristic time travel in children’s literary narrative

    Integrating traditional health care practice into primary health care services: From the perceptions of nurses and medical officers in Windhoek District, Khomas region

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    A Thesis submitted in partial fulfillment of the requirements for the degree of Master of Public HealthThis research explored the perceptions of nurses and medical officers in Windhoek District, Khomas Region, on the relevance of integrating traditional health care practice into primary health care services. The study aimed to understand the role of traditional health care practice on the healthcare system and the potential advantages and disadvantages associated with its integration. Methods: The population of this study consisted of nurses and medical officers stationed in Primary Health Care Facilities in Windhoek District, Khomas Region. A total of thirty eight (38) participants comprised of; twenty-nine (29) nurses and nine (9) Medical Officers took part in this study, who were selected using purposive heterogeneous sampling method. An ethnographic research design was used to collect data through interviews and focus group discussions. Data analysis was guided by the direct content analysis framework from Roger’s Diffusion of Innovation (DOI) theory on adoption processes for a new innovation, namely: compatibility, relative advantage, trial ability, observability, and complexity. These criteria were applied to the adoption of traditional health care services as a new/innovative idea for incorporation into the modern health care system (PHC services). Results: The findings from this study revealed the importance of embracing and respecting traditional healthcare practices and professionalizing them. Integration, collaboration, and regulation were seen as essential elements for enhancing healthcare services and meeting the diverse healthcare needs of the population. Additionally, the findings emphasized the need for regulatory frameworks to ensure the safety and effectiveness of traditional healthcare services and echoed the significance of interdisciplinary dialogue and cooperation. Conclusion: It is recommended that policymakers and healthcare authorities consider developing clear regulatory frameworks, create comprehensive, holistic regulatory guidelines, and standards for the integration of traditional health practices into the primary healthcare system, with a special focus on patient safety, efficacy, cultural sensitivity, and the preservation of Namibia’s diverse ethnic traditional knowledge and healing practice

    The impact of COVID-19 on the livelihood of informal sector workers: A case study of street vendors in Eenhana Town, Ohangwena region, Namibia

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    A thesis submitted in partial fulfilment of the requirements for Degree of Masters of Arts in Development studiesThe global impact of the COVID-19 pandemic has been extensive and has resulted in significant negative consequences, particularly impacting individuals employed in the informal sector. Among the most susceptible groups are street vendors, who face increased vulnerability due to their limited skills and resources for coping with such crises. This research aimed to investigate the effects of COVID-19 on the informal sector in Eenhana Town, Ohangwena Region, Namibia. A quantitative research approach was used, and descriptive statistics on income before, during, and after COVID-19, frequency table, and crosstabulations were used to present the research results. A sample of 133 respondents of street vendors were targeted using a stratified sampling method. Data was gathered using a quantitative survey questionnaire. The data collected through the questionnaires was subjected to statistical data analysis techniques utilising version 23 of the Statistical Package for Social Science (SPSS) software. Many informal sector workers had livelihood losses, with high rates of job and income losses amongst street vendors. The Namibian government has implemented support programmes, but few are aware of them, thus indicating a lack of cohesion between the government and the sector. The research found that it is important to increase the involvement of informal workers in decision-making processes to promote a sustainable recovery and protect against potential crise

    Learner support experiences of learners with learning difficulties at a resource school in Windhoek

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    A thesis submitted in partial fulfilment of the requirements for the Degree of Master of Education in Inclusive EducationThis study aimed to explore the learner support experiences of learners with learning difficulties at a Resource school in Windhoek, Namibia. The study was informed by Vygotsky's Social cultural-historical theory of development, specifically the Zone of proximal development. The researcher employed a phenomenological research design to explore the participants’ experiences of learning support from their point of view. The sample was conveniently drawn, and participants’ views were explored through semi-structured interviews and focus group discussions. Participants’ responses were analysed using thematic analysis. The findings revealed that learners receive different types of learning support delivered through individualised learning instructions and cooperative learning. Furthermore, findings showed that teachers provide a conducive environment for learning, and they employ various learning strategies to accommodate all learners with their various learning styles, such as visual, auditory and kinaesthetic. Although learners receive learning support to ease the learning difficulties they experience, the findings of the study reveal that learners are finding it difficult to develop long-term mechanisms that will help them cope with learning independently. The study recommends that teachers teaching at resource schools should collaborate with professionals and paraprofessionals to share expertise and resources that can be utilised in the classroom to maximise learning for learners with learning difficulties. The study further recommends that the Ministry of Education, Arts and Culture should provide resource schools with the necessary learning devices and financial resources to provide and promote effective teaching and learning environments for learners with learning difficultie

    Percieved perceptions of registered nurses on task-shifting of male circumcision in public health facilities in the Khomas region of Namibia

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    A thesis submitted in fulfilment of the requirements for the degree of Master’s in Nursing ScienceTask-shifting in the context of Voluntary Medical Male Circumcision (VMMC) refers to enabling well-trained clinical personnel who are not Medical doctors to perform all steps of the male circumcision procedure. Since 2009, over 200 000 Voluntary Medical Male Circumcision surgical procedures have been performed throughout Namibia. This performance has been achieved against a backdrop of scarce human resources thus various options have been explored such as task-shifting to increase access to safe VMMC. Since the introduction of male circumcision task-shifting in the Khomas region, little is known about the perceived perceptions of nurses regarding male circumcision task-shifting. Therefore, the purpose of this study was to explore and describe the perceived perceptions of registered nurses on task-shifting of male circumcision in public health facilities in the Khomas Region of Namibia. A qualitative, explorative, descriptive and contextual design was conducted, using individual in-depth interviews to gather data from 14 registered nurses in Katutura Health Centre, of the Khomas region. Data analysis was done using Tesch’s method. The results showed that registered nurses have good and positive perceived perceptions of task-shifting of male circumcision. The study revealed that through task-shifting, nurses are now equipped with special skills, and knowledge that was not part of their scope of practice initially. The study also revealed that because of male circumcision task-shifting, there is limited backlog for patients in need of circumcision services. Recommendations based on this study’s findings include: that the Ministry of Health should provide continuous training and refresher training for the nurses so they gain more skills and knowledge and improve where they can, for continuous provision of exceptional services to the client

    Climate-growth relationships of Argyrosomus spp. found along the Namibian coast

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    A thesis submitted in fulfilment of the requirements for the degree of master of science (Fisheries and Aquatic sciences)Understanding how fish growth responds to changing environments is critical for monitoring and predicting the impacts of climate change on fish populations. The ocean warming hotspot in the northern part of the northern Benguela provides an excellent opportunity to examine the responses of fishes to rapid environmental change. This research focused on the congeneric Argyrosomus inodorus and Argyrosomus coronus as these are commercially and recreationally important fishery species in Namibia. Standard otolith age determination techniques were used to determine if the age and growth of A. inodorus had changed from the 1990s to 2019. The results showed that there was a significant difference (Likelihood-ratio chi square test, χ 2 = 33.36, df = 4, p < 0.001) for the historical (1994-1996) and contemporary (2018-2019) period, thus indicating that A. inodorus stock used to grow older and faster in the historical period when compared to the contemporary. Kruskal Wallis test showed that there was a significant difference between A. inodorus and A. coronus lengths at age 4 (H (1) = 8.264, p = 0.004 < 0.05). The linear mixed-effects models fitted to the A. inodorus otolith biochronology indicated that a best linear unbiased predictor (BLUP) of growth was significantly positively correlated (r = 0.580, n = 25, p < 0.05) with mean SSTs (July, year of formation) and significantly negatively correlated (r = -0.473, n = 25, p < 0.05) with mean spring-summer SSTs (October y-1 to December y-1) in the area 20-24◦S, 12-14◦E. Thus, faster annual growth was observed during cooler periods (above 15℃) and slower growth was noted when exposed to warmer temperatures >17℃. These findings suggest that changes in A. inodorus growth was associated with a change in temperature and that its growth and productivity will be negatively affected with the increasing frequency of extreme climate events and ocean warmin

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