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    Influence of coal ashes on fired clay brick quality: Random forest regression and artifcial neural networks modeling

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    Finding a solution to the problem of the large buildup of coal ashes is a vital necessity. Although the use of coal ashes in fired clay bricks has been thoroughly investigated, there is insuffcient information on their industrial utilization and researchers do not agree on whether or not this addition improves the quality of the fnal products. Therefore, a database has gathered 20 years of research containing key factors related to the quality of the bricks (i.e., chemical composition, fring temperature, soaking time, open porosity, water absorption and compressive strength). Then, random forest regression and artifcial neural networks (ANN) modeling were used to separately predict the parameters concerning the quality of the fnal products. The overall conclusions were that the compressive strengths were the highest when using fly ashes and that class F ashes were highly suitable to be used in the brick industry as a replacement material for brick clay. In addition, the ANN models showed higher coeffcients of determination and an overall better fit to the experimental data. By changing the chemical makeup of the initial materials and their proportions, the particle size of the ashes, the firing temperature and soaking time, as well as the size of a product, the created models can be used to estimate the quality of the brick containing coal ash. That is crucial because the inconsistent chemical composition of ash is generally the main obstacle to its utilization. The local sensitivity analysis revealed the highest influence of the content of the alkali oxides in the initial clay on the fired clay bricks due to their fluxing effect. In the case of ash-clay bricks, the decisive factors were the type of furnace used, the ashes’ class, the Na2O content in raw clay, and the K2O introduced with the ash. The F class ashes containing about 2–3% of K2O and <5% of CaO gave the highest compressive strength in bricks fred at 1000–1100 ◦C. Additional analyzes were made for 50% pond ash and 50% clay bricks to test the best-suited model and fill in the knowledge gap. The results obtained in this study are important for supporting the decision in the selection of materials and process parameter values that will increase the quality of the ash-clay-fired bricks

    Edelweiss Applied Science and Technology

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    https://learning-gate.com/index.php/2576-8484/editorialtea

    Pure Iodide Multication Wide Bandgap Perovskites by Vacuum Deposition

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    The CsPbI3 perovskite has a suitable bandgap (≈1.7 eV) for application in tandem solar cells. One challenge for this compound is that the semiconducting perovskite phase is not stable at room temperature, when it tends to form a yellow nonperovskite phase with a bandgap of approximately 2.8 eV. Therefore, many reports have been focused on the stabilization of the CsPbI3 black perovskite phase through the use of additives during solution processing. Vacuum deposited CsPbI3 has been seldom reported, as in this case, the insertion of stabilizing agents is more challenging. In this work, we demonstrate the vacuum processing of CsPbI3 perovskite films at room temperature, obtained by incorporating dimethylammonium iodide by cosublimation with CsI and PbI2. As-prepared films were applied in planar solar cells, leading to an average power conversion efficiency (PCE) exceeding 12%. In order to improve the device performance, we introduced a third A-site cation (methylammonium) in a four-source deposition process. This pure iodide formulation can be used in wide bandgap solar cells with a PCE up to 14.8%

    Occurrence of cracks due to inadequate turbine shaft construction

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    After several decades of constant exploitation of the horizontal bulb turbine, which is an integral part of the hydroelectric power unit, empirically, the formation of a crack occurs in the turbine shaft due to the influence of corrosion, erosion and cavitation. Through experimental tests and calculations it has been determined that values of bending stresses of the turbine, which occur due to the action of fatigue and corrosion, as well as stress concentration, are bigger than 25 MPa for flanges exposed to water, and in other case bigger than 40 MPa for flanges exposed to `corrosive water` and can cause the occurrence of surface cracks on the transition radius between the cylindrical part of the shaft and the flange. It has been determined that stress values in the zone under the influence of bending stresses were bigger than allowable values, which led to the occurrence of many cracks due to fatigue corrosion. One of those cracks caused the failure of the shaft and of the whole turbine

    Raw kaolinitic-illitic clays for the production of refractory ceramics

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    The study makes a unique effort to characterize all the necessary characteristics of refractory clays and products fired at temperatures between 1100 and 1300 °C on a laboratory level. For 19 composite samples from the recently opened reservoir, thorough instrumental and ceramic-technological data are presented. The potential for using Serbian raw refractory clays from the recently discovered deposit is investigated. The composites had a variety of qualities and varied in composition, but they were majorly composed of kaolinite and illite and had a significant share of fluxes. The samples had high quantities of clay minerals and organic matter, which is seen as the most intense mass loss in the 400–600 °C range. Low-duty and high-duty refractories could be distinguished by their refractoriness over 1581 °C. This parameter was mostly influenced by the content of alumina and kaolinite within the materials. Hydraulically-pressed ceramic tiles, following firing stage showed water absorption was between 9.02–1.42 % and and modulus of rupture of 16.5 – 53.6 MPa. Color is determined by spectrophotometer and correlated to the composition of the initial clay and fired products. For the lining of ceramic and glass furnaces, the majority of these clays can be employed as natural refractory materials. Some of the samples' organic content has a detrimental effect on the fast-firing procedure, since the occurrence of the entrapped air (bloating)

    Pile capacity distribution analysis for SLT with reactive system

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    In the paper, the analysis of the bearing capacity of the pile and the redistribution of the load on the pile toe and shaft was carried out. The tests were carried out by a static load test (SLT) incrementally increasing the compressive force on the test pile, and the tension force on the anchor piles. The test system consisted of one test pile and two anchor piles with a reaction beam. Two tests were conducted according to the same test program, where the test piles were of the same length, while the length of the anchor piles in the second test was increased. In the first test, the anchor pile failed, while in the second test, the test pile failed. Based on the achieved limit values of settlement of the test and anchor pile, the bearing capacity of the test pile at the toe and shaft was determined. Subsequently, a CPT test was carried out and the bearing capacity was calculated according to the LPC-CPT method

    Procedure for correction of bearing capacity of piles examined by the Dynamic Load Test (DLT) according to the Static Load Test (SLT)

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    The paper shows the comparative analysis of behavior and bearing capacity of piles examined using the Dynamic Load Test (DLT) according to Static Load Test (SLT) results. The pile testing methodology is based on the existing ASTM standards and experiences of the authors of the paper. The pile tests were carried out using counterweights, reactive system, dynamic testing equipment, hardware and software for SLT and DLT. The data obtained by testing were statis-tically processed, and also a regression analysis of the linear function was conducted, resulting in the creation of the model for the change of mobilized static bearing capacity from DLT according to SLT. In addition, a procedure for correcting the solution of mobilized static bearing capacity from DLT according to SLT, is made by observing provisions of standard EN 1997-1:2004, so the average deviation of solutions from DLT according to SLT is reduced. Apart from that, through iterations, the value of correlation factor ξ5 is determined, taking into consideration solutions presented by SLT and DLT of piles of the real structures

    Influence of different types of fibers on properties of concrete

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    The paper presents the influence of the use of different types of fibers on the properties of concrete. All concrete samples were made with same component materials and compositions, except for the amount of fibers, which was varied. After hardening, the concrete samples were tested for compressive strength, tensile splitting strength and water penetration depth under pressure. Based on the test results, depending on the type, shape, amount and arrangement of fibers, the tensile and compressive strength values as well as the depth of water penetration under pressure were analyzed. Based on the tests performed, the best mechanical properties were achieved with the use of "Dramix 3D" steel fibers

    An augmented approach for the determination of the particle size effect on energy dispersive X-ray fluorescence analysis outcomes for alumina-based refractory materials

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    The chemical compositions of refractory materials, such as high-alumina concrete, bricks, and putty, were analyzed using an energy-dispersive X-ray spectrometer (EDXRF). An improved methodology for investigating the effect of particle size on the outcomes of EDXRF chemical analysis is presented. Eight independent refractory samples (refractory concrete, brick, and putty) were pulverized utilizing seven milling times (30, 60, 120, 180, 240, 300, and 360 s) and compared to non-pulverized samples. Thus, sixty-four refractory samples were obtained and analyzed using EDXRF. The method for measuring the fundamental EDXRF characteristics was then tested with ten certified reference materials. The acquired data were compared using inductively coupled plasma atomic emission spectrometry (ICP-OES). Univariate and multivariate statistics are used to evaluate EDXRF data. The particle size of the tested samples affected the z-scores of SiO2, Al2O3, Fe2O3, TiO2, CaO, MgO, Na2O, K2O, and P2O5 concentration measurements. Grinding times for refractory concrete, brick, and putty samples were determined in order to validate the robustness of the EDXRF technique and provide reliable chemical analyses. The ideal milling times for the samples studied ranged from 180 to 360 s, depending on the type of refractory material

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