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Coupling photocatalytic CO2 reduction and CH3OH oxidation for selective dimethoxymethane production
No full textCurrently, conventional dimethoxymethane synthesis methods are environmentally unfriendly. Here, we report a photo-redox catalysis system to generate dimethoxymethane using a silver and tungsten co-modified blue titanium dioxide catalyst (Ag.W-BTO) by coupling CO2 reduction and CH3OH oxidation under mild conditions. The Ag.W-BTO structure and its electron and hole transfer are comprehensively investigated by combining advanced characterizations and theoretical studies. Strikingly, Ag.W-BTO achieve a record photocatalytic activity of 5702.49 µmol g−1 with 92.08% dimethoxymethane selectivity in 9 h of ultraviolet-visible irradiation without sacrificial agents. Systematic isotope labeling experiments, in-situ diffuse reflectance infrared Fourier-transform analysis, and theoretical calculations reveal that the Ag and W species respectively catalyze CO2 conversion to *CH2O and CH3OH oxidation to *CH3O. Subsequently, an asymmetric carbon-oxygen coupling process between these two crucial intermediates produces dimethoxymethane. This work presents a CO2 photocatalytic reduction system for multi-carbon production to meet the objectives of sustainable economic development and carbon neutrality.補正完畢DE
Implementation of a Small-Sized Mobile Robot with Road Detection, Sign Recognition, and Obstacle Avoidance
No full textIn this study, under the limited volume of 18 cm × 18 cm × 21 cm, a small-sized mobile robot is designed and implemented. It consists of a CPU, a GPU, a 2D LiDAR (Light Detection And Ranging), and two fisheye cameras to let the robot have good computing processing and graphics processing capabilities. In addition, three functions of road detection, sign recognition, and obstacle avoidance are implemented on this small-sized robot. For road detection, we divide the captured image into four areas and use Intel NUC to perform road detection calculations. The proposed method can significantly reduce the system load and also has a high processing speed of 25 frames per second (fps). For sign recognition, we use the YOLOv4-tiny model and a data augmentation strategy to significantly improve the computing performance of this model. From the experimental results, it can be seen that the mean Average Precision (mAP) of the used model has increased by 52.14%. For obstacle avoidance, a 2D LiDAR-based method with a distance-based filtering mechanism is proposed. The distance-based filtering mechanism is proposed to filter important data points and assign appropriate weights, which can effectively reduce the computational complexity and improve the robot’s response speed to avoid obstacles. Some results and actual experiments illustrate that the proposed methods for these three functions can be effectively completed in the implemented small-sized robot.補正完畢CH
Electrocatalytic ammonia oxidation to nitrite and nitrate with NiOOH-Ni
No full textAmmonia electrooxidation in aqueous solutions can be a highly energy-efficient process in producing nitrate and nitrite while generating hydrogen under ambient conditions. However, the kinetics of this reaction are slow and the role of catalyst in facilitating ammonia electrooxidation is not well understood. In this study, a high-performance NiOOH-Ni catalyst is introduced for converting ammonia into nitrite with Faraday efficiency of up to 90.4% and nitrate production rate of 1 mg h−1 cm−2. By employing Operando techniques, the role of NiOOH catalyst is elucidated in the dynamic electrooxidation of ammonia. Density functional theory (DFT) calculations support experimental observations and reveal the mechanism of the electrochemical oxidation of ammonia to nitrite and nitrate. Overall, this research contributes to the development of a cost-effective and highly efficient catalyst for large-scale ammonia electrolysis, while shedding light on the underlying mechanism of the NiOOH catalyst in ammonia electrooxidation.補正完畢DE
The flow within the head of a gravity current
No full textHigh-resolution simulations of gravity currents in the lock-exchange configuration are conducted to study the flow within the head. The simulations exhibit the geometric features of the head as reported in the laboratory experiments and numerical simulations, and provide more detailed information on the flow within the head of a gravity current. The flow in the lower part of the head, where the lobes and clefts are forming at the leading edge, is qualitatively different from but interconnected to the flow in the upper part of the head, where steepening bulges are protruding from the upright surface above the clefts. Interestingly, regions of positive and negative streamwise vorticity are observed not only in the lower part of the head but also in the upper part of the head at staggered spanwise locations. We have shown that both the streamwise vorticity at the leading edge of the lobes in the lower part of the head and the streamwise vorticity at the steepening bulges in the upper part of the head are contributed from the twisting of spanwise vorticity into the streamwise direction, due to the geometric features of the lobes and the steepening bulges, and contributed from the baroclinic production of vorticity. Our results from visualization using tracers indicate that the ambient fluid ingested in and rising from the clefts is being swept towards the leading edge of a gravity current before being carried upwards from the leading edge to the upright surface above the left and right neighbouring lobes. Furthermore, the heavy fluid inside a lobe may descend towards the bottom boundary, move forward towards the leading edge and outwards towards the neighbouring clefts, and ultimately be carried upwards to the upright surface above the left and right neighbouring lobes. With the knowledge that the erosive power of a gravity current is concentrated in the head region, it is plausible that the bed material, once resuspended by a gravity current, may be lifted up away from the bottom boundary and be dispersed in both the streamwise and spanwise directions. The present study complements existing findings in the literature and provides new insights into the three-dimensional flow field within the head of a gravity current.補正完畢GB
A study on subsoil and pile reactions of embedded piled raft foundations in sandy soils under vertical loads
No full textThis study investigated the load-settlement mechanism of embedded piled raft foundations in sandy soils (ranging from loose to low medium dense sands) under vertically uniform loads through a series of three-dimensional finite element analyses. The foundation model comprises a square concrete raft, varying in width from 16 to 36 m, and embedded at depths of 8 and 12 m from the ground surface. Concrete piles with a diameter of 1 m and lengths of 20 m and 30 m were installed beneath the raft. The foundation was located in homogeneous sands with shear wave velocities ranging from 150 to 210 m/s. Consequently, the modulus of subgrade reaction of the subsoil and the coefficient of pile reaction were both reported. This study examined and presented alternative dimensionless measures of pile displacements, pile reactions, and corresponding coefficients of pile reactions to facilitate hand calculations. Optimized correlations were suggested using box plots and regression analyses for the dimensionless measures with the non-dimensional design parameters of the foundation. Upon verifying the proposed suggestions on a sample example, we conclude that the proposed method offers a preliminary calculation tool for the design of piled raft foundation design in the studied sands.補正完畢KO
