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Recycled Pavement Materials and Urban Microclimate: Albedo and Thermal Capacity Effects on Heat Island Mitigation
No full textIn Mediterranean cities, high solar radiation combined with limited shading and vegetation intensifies the urban heat island (UHI) phenomenon. As the road network often covers a large portion of the cities’ surfaces and is mostly constructed using asphalt pavements, it can significantly affect the urban microclimate, leading to low thermal comfort and increased energy consumption. Recycled and waste materials are increasingly used in the construction of pavements in accordance with the principle of sustainability for minimizing waste and energy to produce new materials based on a circular economy. The scope of this study is to evaluate the effect of recycled or waste materials used in road pavements on the urban microclimate. The surface and ambient temperature of urban pavements constructed with conventional asphalt and recycled/waste-based mixtures are assessed through simulation. Two study areas comprising large street junctions near metro stations in the city of Thessaloniki, in Greece, are examined under three scenarios: a conventional hot mix asphalt, an asphalt mixture containing steel slag, and a high-albedo mixture. The results of the research suggest that the use of steel slag could reduce the air temperature by 0.9 °C at 15:00, east European summer time (EEST), while the high-albedo scenario could reduce the ambient temperature by 1.6 °C at 16:00. The research results are useful for promoting the use of recycled materials, not only as a means of sustainably using resources but also for the improvement of thermal comfort in urban areas, the mitigation of the UHI effect, and the reduction of heat stress for human health
Management of Chronic Health Situations
No full textChronic diseases are one of the greatest current global health challenges, not only because of their direct clinical impacts, but above all because of the functional, emotional, and social repercussions that profoundly affect the lives of patients and their families [...
Effect of Ni on the Natural Passivating Film and Pitting Corrosion Resistance of Stainless Steels in Alkaline Media
No full textThis work addresses the influence of Ni on the natural passivation process of stainless steels (SSs) in alkaline media simulating concrete pore solution by a combination of electrochemical and X-ray photoelectron spectroscopy (XPS) surface analysis. It was found that the involvement of Ni in the passive film on the SS promoted Fe depletion at the passive film/substrate interface and increased the content of Cr oxide during natural passivation, thereby enhancing the corrosion resistance of the passive film. The passive film with Ni has a higher breakdown potential and can be more easily re-passivated compared with a passive film without Ni
Discovery of a Ferroptosis-Related lncRNA–miRNA–mRNA Gene Signature in Endometrial Cancer Through a Comprehensive Co-Expression Network Analysis
No full textBackground: As a newly recognized type of cell death implicated in cancer, ferroptosis plays multiple roles in tumor biology. Here, we sought to construct a prognostic framework for EC on the basis of ferroptosis-related long non-coding RNAs (FerlncRNAs), microRNAs (FermiRNAs), and mRNAs (FRGs) for endometrial cancer (EC). Methods: Transcriptomic profiles of tumors and matched clinical data for 544 EC patients were retrieved from TCGA-UCEC. A prognostic framework was generated through Cox regression, integrating ferroptosis-linked lncRNAs, miRNAs, and mRNAs. EC cases were stratified into groups with high or low predicted risk based on ferroptosis-related gene expression. The model’s prognostic utility was examined through Kaplan–Meier (K–M) analysis and receiver operating characteristic curves. Results: A prognostic model based on 16 RNAs, including 10 FerlncRNAs, 2 FermiRNAs, and 4 FRGs, was developed. Analysis using K–M plots showed that high-risk patients experienced shorter overall survival than their low-risk counterparts (p < 0.001). The model’s area under curve (AUC) values were 0.731, 0.749, and 0.768 at 1-, 3-, and 5-year time points, surpassing those of standard clinical parameters. Furthermore, in an external validation cohort, these signature RNAs were associated with EC prognosis. Conclusions: The novel ferroptosis-related lncRNA–miRNA–mRNA prognostic model provides a basis to assess clinical prognosis in EC patients
Cl-Bearing Mineral Microinclusions in Arc Lavas: An Overview of Recent Findings with Some Metallogenic Implications
No full textQuaternary lavas (ankaramite, basalt, basaltic andesite, andesite, dacite) from the Kamchatka, Kurile, Ecuador and Cascade volcanic arcs contain Cl-bearing mineral microinclusions in rock-forming minerals and groundmass volcanic glass. They are represented by chlorargyrite (with a variable amount of native Ag), Cu, Ag, Sn, and Zn compounds with Cl and S, Sn- and Pb-Sb oxychlorides compositionally similar to abhurite and nadorite, as well as bismoclite and Cl-F-apatite. The Cl-bearing compounds with chalcophile metals are best approximated by mixtures of chlorargyrite with Cu sulfides, malachite, or azurite. Some Cl-bearing solid microinclusions in magmatic rock-forming minerals could have formed from Cl-rich melts exsolved from arc magmas during differentiation. Alternatively, specific magmatic microinclusions may record the decomposition of primary sulfides in the presence of Cl-bearing magmatic volatiles. Post-magmatic Cl microminerals found in fractures, pores, grain contacts, and groundmass glass are most probably precipitated from hydrothermal fluids accompanying their emplacement at the surface and post-eruption transformations in active fumarole fields. Assemblages of Cl-bearing microminerals with native metal, alloy, sulfide, oxide, and sulfate microinclusions in arc lavas potentially record late-magmatic to post-magmatic stages of formation of the epithermal and possibly porphyry mineralization beneath arc volcanoes
Removal and Recovery of Ammonium Nitrogen from Dairy Processing Wastewater Using Air Stripping Technology: A Pilot-Scale Study
No full textAmmonium nitrogen (NH4+-N) removal and recovery from wastewater have been critical issues worldwide and key to achieving a sustainable nitrogen cycle and circular economy. In this study, we designed and constructed a pilot-scale air stripping system integrated with a nutrient-capture unit and evaluated the effective pH, temperature, and airflow conditions for maximising NH4+-N removal and recovery from dairy processing wastewater (DPW). Our results demonstrated that increasing pH and temperature substantially enhances NH4+-N removal via air stripping, with higher airflow rates further improving performance. Under these conditions (pH 11, 32 °C, and 300 L min−1), NH4+-N removal from synthetic wastewater reached ≈40% after 6 h air stripping. In comparison, real DPW exhibited slightly lower removal efficiency under the same conditions, achieving ≈34%, likely due to its more complex matrix. Additionally, incorporating a chemical precipitation step followed by filtration prior to air stripping removed NH4+-N from DPW, achieving ≈43%. However, extending the stripping duration under identical conditions significantly improved removal performance, increasing NH4+-N removal in DPW to ≈70%. The downstream capturing system, consisting of acid bath and granulated activated carbon (GAC), consistently recovered 70–95% of the released ammonia (NH3) when even upstream NH4+-N removal via air stripping was moderate. The GAC effectively adsorbed the volatilised NH3, achieving adsorption capacities of up to ≈18 mg/kg. Overall, this integrated system demonstrates strong potential for simultaneous NH4+-N removal and recovery from industrial wastewater streams, offering notable environmental benefits
Reducing Ship Emissions Through Specialized Maintenance: A Case Study Based on Real Data
No full textMaintenance operations represent one of the most underutilized opportunities to reduce emissions and improve the energy efficiency of ships. This study proposes an innovative approach that analyzes such interventions from a holistic perspective of energy, environment, and economics using real operational data from two liquefied natural gas (LNG) carriers before and after their maintenance operations. The results show that comprehensive actions such as complete hull and propeller cleaning can reduce fuel consumption by more than 30% and CO2 emissions by more than 15%, in addition to improving propulsive efficiency by between 18% and 34%. In contrast, minor interventions, such as underwater propeller cleaning, have a limited effect with very specific improvements in fuel savings at certain speed ranges, but no significant effect on emissions or shaft power. In particular, the study demonstrates that a single comprehensive maintenance operation can change the Carbon Intensity Indicator (CII) rating from category E to D, reinforcing the strategic role of maintenance in the decarbonization and revaluation of maritime transport
Chemiresistive Effect in Ti0.2V1.8C MXene/Metal Oxide Hetero-Structured Composites
No full textTwo-dimensional carbide crystals (MXenes) are emerging as a promising platform for the development of novel gas sensors, offering advantages in energy efficiency and tunable analyte selectivity. One of the most effective strategies to enhance and tailor their functional performance involves forming hetero-structured composites with metal oxides. In this work, we explore a chemiresistive effect in double-metal MXene of Ti0.2V1.8C and its composites with 2 mol. % SnO2 and Co3O4 nanocrystalline oxides toward feasibility tests with alcohol and ammonia vapor probes. The materials were characterized by simultaneous thermal analysis, X-ray diffraction analysis, Raman spectroscopy, and scanning/transmission electron microscopy. Gas-sensing experiments were carried out on composite layers deposited on multi-electrode substrates to be exposed to the test gases, 200–2000 ppm concentrations, at an operating temperature of 370 °C. The developed sensor array demonstrated clear analyte discrimination. The distinct sensor responses enabled a selective identification of vapors through linear discriminant analysis, demonstrating the further potential of MXene-based materials for integrated electronic nose applications
Complementary Techniques of Thermal Analysis as a Tool for Studying the Properties and Effectiveness of Intumescent Coatings Deposited on Wood
No full textFire-retardant intumescent coatings offer an effective means of enhancing the fire resistance of combustible substrates such as wood. These coatings have a complex chemical composition and, when exposed to temperatures above 200 °C, undergo an intumescent reaction accompanied by the release of non-flammable gases, forming an expanded, charred layer with low thermal conductivity. This provides thermal insulation and acts as a physical barrier against heat, oxygen, and flammable volatiles. In this study, the applicability of several thermoanalytical techniques for evaluating the performance of three different intumescent coatings applied to spruce wood was investigated. Simultaneous thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) showed that coating No. 3 was the most efficient, initiating substrate protection at the lowest temperature and reducing the combustion enthalpy by approximately 50% compared to uncoated wood. DSC-microscopy visualization enabled direct observation of the intumescent expansion, degradation of the carbonized protective layer, and delayed thermal decomposition of coated wood. Furthermore, a comparison between TGA-MS and TGA-IST16-GC-MS demonstrated the superiority of chromatographic separation for identifying evolved gaseous products. While TGA-MS is effective for detecting small gaseous species (e.g., H2O, CO2, formaldehyde), TGA-IST16-GC-MS enables the deconvolution of many degradation products evolving simultaneously, allowing for distinction between flame-retardant-related species, polymer backbone fragments, nitrogen-rich heterocycles, and small oxygenated molecules in the most effective coating
Straightforward Synthetic Approach to Aminoalcohols with 9-oxabicyclo[3.3.1]nonane or Cyclooctane Core via Nucleophilic Ring-Opening of Spirocyclic Bis(oxiranes)
No full textNucleophilic ring-opening of bis(oxiranes), containing several reactive centers, can be used to elaborate straightforward atom-economy and stereoselective approaches to polyfunctionalized compounds. In the present work, ring-opening of cis- and trans-diastereomers of a spirocyclic bis(oxirane), containing a cyclooctane core (namely, 1,8-dioxadispiro[2.3.2.3]dodecane), upon treatment with various amines, was studied. Trans-isomer afforded aminoalcohols with 9-oxabicyclo[3.3.1]nonane moiety, formed via domino-process, including opening of an oxirane ring followed by intramolecular cyclization. Ring-opening of cis-isomer gave aminosubstituted cis-cyclooctane-1,5-diols, derived from independent reaction of two oxirane moieties. Activation of oxirane rings by the addition of LiClO4, acting as a Lewis acid, allowed the involvement of a number of primary and secondary aliphatic amines as well as aniline derivatives in the reaction. Scope and limitations of the reaction were studied and a series of aminoalcohols with a 9-oxabicyclo[3.3.1]nonane core and symmetric diaminodiols with a cyclooctane core were obtained