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No full textMolecular design of cost-effective donor polymers with high visible transmission for eco-friendly and efficient semitransparent organic solar cells
No full textPhotoactive layer materials that overcome the trade-off between power conversion efficiency (PCE) and average visible transmittance (AVT) are required to prepare successful high-performance semitransparent organic solar cells (ST-OSCs). Among 12 novel cost-effective D-p=A polymers with high visible light transmission, P(3IN = 0.3)(3IN2F = 0.5)(BDD = 0.2) achieved a PCE of 14.0% and high stability in an eco-friendly solvent-processed OSC with BTP-eC9. This blend film exhibited an AVT of 62.1% and a color rendering index of 95.0, demonstrating the high potential for ST-OSCs. The ternary OSC with PM6 greatly enhances the PCE to 17.3%. Binary and ternary ST-OSCs achieve light utilization efficiencies (LUEs) of 4.38% and 4.04%, respectively, demonstrating the potential of the D-p=A structure. Under a 3000 K light-emitting diode light at 958 lx low illuminance, PCEs of 12.4% and 15.7% are obtained for binary and ternary ST-OSCs, respectively, and the indoor LUEs (LUIEs) of ST-OSCs are greatly enhanced to 5.52% and 5.48%, respectively. Air-processed eco-friendly ternary ST-OSC module (4.7 cm(2)) achieves not only a PCE of 12.1% and LUIE of 3.90% under 958 lx, but also color coordinates of (0.290, 0.323) and an infrared radiation rejection rate of 87.5%, meeting the civil engineering specifications for windows. This ST-OSC module can be a substitute power source of the thermo-hygrometer in real time, even operate at 195 lx, which paved the way towards zero-energy indoor and outdoor electrical devices as well as windows for buildings and vehicles
Impact of cross-section uncertainties on supernova neutrino spectral parameter fitting in the Deep Underground Neutrino Experiment
No full textA primary goal of the upcoming Deep Underground Neutrino Experiment (DUNE) is to measure the Oo10 thorn MeV neutrinos produced by a Galactic core-collapse supernova if one should occur during the lifetime of the experiment. The liquid-argon-based detectors planned for DUNE are expected to be uniquely sensitive to the & nu;e component of the supernova flux, enabling a wide variety of physics and astrophysics measurements. A key requirement for a correct interpretation of these measurements is a good understanding of the energy-dependent total cross section & sigma;oE & nu; thorn for charged-current & nu;e absorption on argon. In the context of a simulated extraction of supernova & nu;e spectral parameters from a toy analysis, we investigate the impact of & sigma;oE & nu; thorn modeling uncertainties on DUNE's supernova neutrino physics sensitivity for the first time. We find that the currently large theoretical uncertainties on & sigma;oE & nu; thorn must be substantially reduced before the & nu;e flux parameters can be extracted reliably; in the absence of external constraints, a measurement of the integrated neutrino luminosity with less than 10% bias with DUNE requires & sigma;oE & nu; thorn to be known to about 5%. The neutrino spectral shape parameters can be known to better than 10% for a 20% uncertainty on the cross-section scale, although they will be sensitive to uncertainties on the shape of & sigma;oE & nu; thorn . A direct measurement of low-energy & nu;e-argon scattering would be invaluable for improving the theoretical precision to the needed level
Temporal variation of surface reflectance and cloud fraction used to identify background aerosol retrieval information over East Asia
No full textTemporal variation in cloud cover and surface conditions greatly affects estimation errors associated with reference surface reflectance and atmospheric composition retrievals. In this study, to determine an optimal temporal window for clear-sky composition methods that are used to identify surface reflectance for the retrieval of atmospheric properties, we analyzed temporal variation in surface reflectance and cloud fractions using longterm daily observations from the Moderate Resolution Imaing Spectroradiometer (MODIS) satellite. For the temporal variation in surface reflectance, gridded pixels with a standard deviation less than 0.025 represented 87.0%, 84.5%, 80.5%, and 77.3% of the total pixels for periods of 15, 20, 30, and 40 days, respectively. The temporal variability of surface reflectance was lowest in summer and highest in winter due to vegetation and snow cover changes over land surface in East Asia. For the temporal variation in cloud fractions, pixels with a cloud fraction <10% ranged from 91.2% (15-day) to 98.1% (40-day). Only temporal windows of 30 and 40 days satisfied the criterion of 95% cumulative distribution in the 10% cloud fraction range. Thus, and appropriate temporal window for clear-sky composition methods must be selected in consideration of the seasonal dependency of surface types and cloud cover variation. The temporal window for the clear-sky composition must be longer than 30 days considering the temporal variability of cloud cover, and shorter than 30 days considering that of surface reflectance. However, seasonal dependencies of surface reflectance and cloud fraction are also additionally considered to select the appropriated temporal window for the clear-sky composition
On the distribution of analytic ranks of elliptic curves
No full textIn this paper, under GRH for elliptic curve L-functions, we give an upper bound for the probability for an elliptic curve with analytic rank ???a
for a???11, and also provide an upper bound of n-th moments of analytic ranks of elliptic curves. These are applications of counting elliptic curves with local conditions
Hexaazatriphenylene-Based Two-Dimensional Conductive Covalent Organic Framework with Anisotropic Charge Transfer
No full textThe development of covalent organic frameworks (COFs) with efficient charge transport is of immense interest for applications in optoelectronic devices. To enhance COF charge transport properties, electroactive building blocks and dopants can be used to induce extended conduction channels. However, understanding their intricate interplay remains challenging. We designed and synthesized a tailor-made COF structure with electroactive hexaazatriphenylene (HAT) core units and planar dioxin (D) linkages, denoted as HD-COF. With the support of theoretical calculations, we found that the HAT units in the HD-COF induce strong, eclipsed & pi;-& pi; stacking. The unique stacking of HAT units and the weak in-plane conjugation of dioxin linkages leads to efficient anisotropic charge transport. We fabricated HD-COF films to minimize the grain boundary effect of bulk COFs, which resulted in enhanced conductivity. As a result, the HD-COF films showed an electrical conductivity as high as 1.25 S cm-1 after doping with tris(4-bromophenyl)ammoniumyl hexachloroantimonate. Electroactive hexaazatriphenylene (HAT)-dioxin linked covalent organic framework, denoted as HD-COF, was designed, and synthesized. The unique & pi;-& pi; stacking of HAT units and the weak in-plane conjugation of dioxin linkages in the HD-COF structure led to efficient anisotropic charge transport. In situ formed HD-COF film demonstrated enhanced electric conductivity as high as 1.25 S cm-1 after doping with magic blue.+imag
Synoptic meteorological conditions and contributing factors to air quality during the SIJAQ campaign
No full textThe Satellite Integrated Joint Monitoring of Air Quality (SIJAQ) field campaign was conducted from October 10 to November 25, 2021, to assess air quality across the Korean Peninsula and validate the results of the Geostationary Environment Monitoring Spectrometer (GEMS) employing remote sensing, modeling, and satellite, aircraft, and ground measurements. To integrate all measurements collected during the campaign, synoptic features across the Korean Peninsula were analyzed. We identified cyclones and anticyclones by tracing weather charts and divided the campaign into five periods (P1 to P5): P1 - Sustained marine stagnation (October 10???28, 2021), P2 - Transitional stagnant high (October 29???November 7, 2021), P3 - Continental migratory low (November 8???14, 2021), P4 - Continental migratory high (November 15???21, 2021), and P5 - Continental migratory low (November 22???25, 2021). The synoptic features, such as the locations of stagnant or migratory cyclones and anticyclones were analyzed during the periods, in association with levels of particulate matter with a diameter of less than 2.5 ??m (PM2.5 levels) over the Seoul metropolitan area (SMA). The synoptic characteristics showed that the presence of a high pressure system was well associated with the occurrence of high PM2.5 level over the SMA, and a pattern of near-surface divergence and descending motions originating from the mid-troposphere. In addition, we identified and compared two PM2.5 level peaks caused by local accumulation and transboundary transport process. We also investigated the underlying synoptic meteorological mechanisms of these peaks in terms of large-scale dynamic variables, such as geostrophic wind speed, transient synoptic scale features, vorticity, and vorticity advection at 850 hPa geopotential height, which are responsible for transboundary transport and local accumulation-driven process of PM2.5 in the SMA