Ulsan National Institute of Science and Technology

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    A Brief Review of Some Challenging Issues in Textured Piezoceramics via Templated Grain Growth Method

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    It is well known that polycrystalline ceramics fabricated via the templated grain growth method along a desired crystallographic direction, generally along [001], exhibits enhanced piezoelectric response. Generally, the piezoelectric properties of textured ceramics depend on the degree of texture, as piezoelectric properties peak in single crystals. Therefore, understanding the relationship between the degree of texture and piezoelectric properties is fundamental. Here, we present state-of-the-art textured piezoceramics by focusing on critical issues such as the quality of templates used for texturing and proper evaluation of the degree of texture analysis. The relationship between the degree of texture and its impact on the properties of textured materials is exclusively defined by the Lotgering factor (L.F.) calculated from the X-ray diffraction profiles. Additionally, we show that L.F. is not a suitable indicator of the degree of texture, contrary to previous interpretations. This statement was further supported by the fact that the true degree of texture can be better quantified by the multiples of random distribution. This argument was justified by comparing the quantitative values of the degree of texture obtained from both methods to those of the piezoelectric charge coefficient of textured and random ceramics

    Magnetocaloric properties and critical behavior of magnetic phase transition in La(Fe(0.94-x)NixCo(0.06))(11.4)Si1.6B0.25 alloys

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    For the widespread application of solid magnetic refrigeration technology, this is one of the key technologies to realize the wide temperature range of magnetic entropy change near room temperature. In this paper, the effect of Ni-doping on the magnetocaloric properties and the temperature range of magnetic entropy change was studied for La(Fe(0.94-x)NixCo(0.06))(11.4)Si1.6B0.25 alloy subjected to the industrial high-frequency suspension furnace. The results show that the Curie temperature of the alloy system can be adjusted to room temperature by changing the Ni content, and the temperature range of magnetic entropy change can be expanded effectively. In addition, the critical behavior of the industrial grade purity alloy system was evaluated by modified Arrott-plot and critical isotherm analysis methods, and the optimal values of critical parameters were obtained, providing a novel thermodynamic method to determine the critical behavior of magnetic phase transition in La(FeSi)13 alloy system

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