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The PAU Survey and Euclid: Improving broadband photometric redshifts with multi-task learning
No full textCurrent and future imaging surveys require photometric redshifts (photo-zs) to be estimated for millions of galaxies. Improving the photo-z quality is a major challenge but is needed to advance our understanding of cosmology. In this paper we explore how the synergies between narrow-band photometric data and large imaging surveys can be exploited to improve broadband photometric redshifts. We used a multi-task learning (MTL) network to improve broadband photo-z estimates by simultaneously predicting the broadband photo-z and the narrow-band photometry from the broadband photometry. The narrow-band photometry is only required in the training field, which also enables better photo-z predictions for the galaxies without narrow-band photometry in the wide field. This technique was tested with data from the Physics of the Accelerating Universe Survey (PAUS) in the COSMOS field. We find that the method predicts photo-zs that are 13% more precise down to magnitude iAB 1. Applying this technique to deeper samples is crucial for future surveys such as Euclid or LSST. For simulated data, training on a sample with iAB z scatter by 16% for all galaxies with iAB zs, which reduces the photo-z scatter by 20% in the COSMOS field
Ground solar absorption observations of total column CO, CO₂, CH₄, and aerosol optical depth from California's Sequoia Lightning Complex Fire: emission factors and modified combustion efficiency at regional scales
No full textWith global wildfires becoming more widespread and severe, tracking their emissions of greenhouse gases and air pollutants is becoming increasingly important. Wildfire emissions have primarily been characterized by in situ laboratory and field observations at fine scales. While this approach captures the mechanisms relating emissions to combustion phase and fuel properties, their evaluation on regional-scale plumes has been limited. In this study, we report remote observations of total column trace gases and aerosols during the 2020 wildfire season from smoke plumes in the Sierra Nevada of California with an EM27/SUN solar Fourier transform infrared (FTIR) spectrometer. We derive total column aerosol optical depth (AOD), emission factors (EFs) and modified combustion efficiency (MCE) for these fires and evaluate relationships between them, based on combustion phase at regional scales. We demonstrate that the EM27/SUN effectively detects changes in CO, CO₂, and CH₄ in the atmospheric column at ∼10 km horizontal scales that are attributed to wildfire emissions. These observations are used to derive total column EF_(CO) of 120.5 ± 12.2 and EF_(CH₄) of 4.3 ± 0.8 for a regional smoke plume event in mixed combustion phases. These values are consistent with in situ relationships measured in similar temperate coniferous forest wildfires. FTIR-derived AOD was compared to a nearby AERONET (AErosol RObotic NETwork) station and observed ratios of X_(CO) to AOD were consistent with those previously observed from satellites. We also show that co-located X_(CO) observations from the TROPOspheric Monitoring Instrument (TROPOMI) satellite-based instrument are 9.7 ± 1.3 % higher than our EM27/SUN observations during the wildfire period. Finally, we put wildfire CH4 emissions in context of the California state CH₄ budget and estimate that 213.7 ± 49.8 Gg CH₄ were emitted by large wildfires in California during 2020, about 13.7 % of the total state CH₄ emissions in 2020. Our work demonstrates a novel application of the ground-based EM27/SUN solar spectrometers in wildfire monitoring by integrating regional-scale measurements of trace gases and aerosols from smoke plumes
Empirical analysis of the corporate social responsibility and financial performance causal nexus: Evidence from the banking sector of Bangladesh
No full textIn a culture like Bangladesh where social trust is low and corporate philanthropy is rare, corporate social responsibility (CSR) engagements of the banking sector have been in a conspicuously upward trend. It begs the question of whether the galvanization of CSR expenditure is validated by financial motivations or a genuine thirst for corporate philanthropy. The literature on the relationship between CSR and corporate financial performance (CFP) is without any overarching consensus. From an emotional viewpoint, we revere corporate philanthropy without necessarily analyzing its financial merits. This study extends the contemporary CSR literature horizon by examining 30 listed banks in Bangladesh from the years 2006 through 2018, with particular emphasis on methodology that attempts to validate the CSR-CFP relationship. In addition to examining the bidirectional causality between CSR and financial returns using Panel Vector Autoregression, the study examines the factor determinants of CSR. The study finds that better CFP leads to more CSR expenditure, but CSR expenditure does not necessarily influence CFP. Moreover, net income, total deposits, return on asset, and previous year's CSR have a significant positive relationship with CSR whereas firm age has a significant negative relationship
Two Volcanic Tsunami Events Caused by Trapdoor Faulting at a Submerged Caldera Near Curtis and Cheeseman Islands in the Kermadec Arc
No full textTwo submarine earthquakes (M_w 5.8) occurred near volcanic islands, Curtis and Cheeseman, in the Kermadec Arc in 2009 and 2017. Following both earthquakes, similar tsunamis with wave heights of about a meter, larger than expected from their moderate seismic magnitudes, were observed by coastal tide gauges. We investigate the source mechanism for both earthquakes by analyzing tsunami and seismic data of the 2017 event. Tsunami waveform analysis indicates that the earthquake uplifted a submerged caldera around the islands. Combined analysis of tsunami and seismic data suggests that trapdoor faulting, or sudden intra-caldera fault slip interacted with magma reservoir deformation, occurred due to magma overpressure, possibly in association with caldera resurgence. The earthquake scaling relationship for trapdoor faulting events at three calderas deviates from that for regular earthquakes, possibly due to the fault-reservoir interaction in calderas
Measurement of Doppler effects in a cryogenic buffer-gas cell
No full textBuffer-gas cooling is a universal cooling technique for molecules and used for various purposes. One of its applications is using molecules inside a buffer-gas cell for low-temperature spectroscopy. Although a high-intensity signal is expected in the cell, complex molecular dynamics is a drawback for precise spectroscopy. In this study, we performed high-resolution absorption spectroscopy of low-J transitions in the ò(0, 0, 0)-X̃²Σ⁺(0, 0, 0) band of calcium monohydroxide (CaOH). CaOH molecules were produced by laser ablation in a copper cell and cooled to ∼5 K using helium buffer gas. We probed the Doppler effects in a buffer-gas cell by injecting counterpropagating lasers inside the cell. The time evolutions of the Doppler width and shift were simulated using a dedicated Monte Carlo simulation and compared with data
Leaping liquid crystal elastomers
No full textSnap-through mechanisms are pervasive in everyday life in biological systems, engineered devices, and consumer products. Snap-through transitions can be realized in responsive materials via stimuli-induced mechanical instability. Here, we demonstrate a rapid and powerful snap-through response in liquid crystalline elastomers (LCEs). While LCEs have been extensively examined as material actuators, their deformation rate is limited by the second-order character of their phase transition. In this work, we locally pattern the director orientation of LCEs and fabricate mechanical elements with through-thickness (functionally graded) modulus gradients to realize stimuli-induced responses as fast as 6 ms. The rapid acceleration and associated force output of the LCE elements cause the elements to leap to heights over 200 times the material thickness. The experimental examination in functionally graded LCE elements is complemented with computational evaluation of the underlying mechanics. The experimentally validated model is then exercised as a design tool to guide functional implementation, visualized as directional leaping
A Bacterial Form I’ Rubisco Has a Smaller Carbon Isotope Fractionation than Its Form I Counterpart
No full textForm I rubiscos evolved in Cyanobacteria ≥ 2.5 billion years ago and are enzymatically unique due to the presence of small subunits (RbcS) capping both ends of an octameric large subunit (RbcL) rubisco assembly to form a hexadecameric (L8S8) holoenzyme. Although RbcS was previously thought to be integral to Form I rubisco stability, the recent discovery of a closely related sister clade of octameric rubiscos (Form I’; L8) demonstrates that the L8 complex can assemble without small subunits (Banda et al. 2020). Rubisco also displays a kinetic isotope effect (KIE) where the 3PG product is depleted in 13C relative to 12C. In Cyanobacteria, only two Form I KIE measurements exist, making interpretation of bacterial carbon isotope data difficult. To aid comparison, we measured in vitro the KIEs of Form I’ (Candidatus Promineofilum breve) and Form I (Synechococcus elongatus PCC 6301) rubiscos and found the KIE to be smaller in the L8 rubisco (16.25 ± 1.36‰ vs. 22.42 ± 2.37‰, respectively). Therefore, while small subunits may not be necessary for protein stability, they may affect the KIE. Our findings may provide insight into the function of RbcS and allow more refined interpretation of environmental carbon isotope data
Carbon Deposit Analysis in Catalyst Deactivation, Regeneration, and Rejuvenation
No full textHydrocarbon conversion catalysts suffer from deactivation by deposition or formation of carbon deposits. Carbon deposit formation is thermodynamically favored above 350 °C, even in some hydrogen-rich environments. We discuss four basic mechanisms: a carbenium-ion based mechanism taking place on acid sites of zeolites or bifunctional catalysts, a metal-induced formation of soft coke (i.e., oligomers of small olefins) on bifunctional catalysts, a radical-mediated mechanism in higher-temperature processes, and fast-growing carbon filament formation. Catalysts deactivate because carbon deposits block pores at different length scales, or directly block active sites. Some deactivated catalysts can be re-used, others can be regenerated or have to be discarded. Catalyst and process design can mitigate the effects of deactivation. New analytical tools allow for the direct observation (in some cases even under in situ or operando conditions) of the 3D-distribution of coke-type species as a function of catalyst structure and lifetime
Using rational filters to uncover the first ringdown overtone in GW150914
No full textThere have been debates in the literature about the existence of the first overtone in the ringdown of GW150914. We develop a novel Bayesian framework to reanalyze the data of this event, by incorporating a new technique, the “rational filter” that can clean particular modes from the ringdown signal. We examine the existence of the first overtone in GW150914 from multiple novel perspectives. First, we confirm that the estimates of the remnant black hole mass and spin are more consistent with those obtained from the full inspiral-merger-ringdown signal when including the first overtone at an early stage of the ringdown (right after the inferred signal peak); such improvement fades away at later times. Second, we formulate a new way to compare the ringdown models with and without the first overtone by calculating the Bayes factor at different times during the ringdown. We obtain a Bayes factor of 600 at the time when the signal amplitude reaches its peak. The Bayes factor decreases sharply when moving away from the peak time and eventually oscillates around a small value when the overtone signal is expected to have decayed. Third, we clean the fundamental mode from the ringdown of GW150914 and estimate the amplitudes of the modes using the filtered data with Markov chain Monte Carlo (MCMC). The inferred amplitude of the fundamental mode is ∼0 whereas the amplitude of the first overtone remains almost unchanged, implying that the filtered data is consistent with a first-overtone-only template. Similarly, if we remove the first overtone from the GW150914 data, the filtered data are consistent with a fundamental-mode-only template. Finally, after removing the fundamental mode, we use MCMC to infer the remnant black hole mass and spin from the first overtone alone. We find the posteriors are still informative and consistent with those inferred from the fundamental mode. The conclusions are also verified through simulations in Gaussian noise using a GW150914-like numerical relativity waveform
Spatially resolved imaging of the inner Fomalhaut disk using JWST/MIRI
No full textPlanetary debris disks around other stars are analogous to the asteroid and Kuiper belts in the Solar System. Their structure reveals the configuration of small bodies and provides hints for the presence of planets. The nearby star Fomalhaut hosts one of the most prominent debris disks, resolved by the Hubble Space Telescope, Spitzer, Herschel and the Atacama Large Millimeter Array. Images of this system at mid-infrared wavelengths using JWST/MIRI not only show the narrow Kuiper belt-analogue outer ring, but also that (1) what was thought from indirect evidence to be an asteroid-analogue structure is instead broad, extending outward into the outer system, and (2) there is an intermediate belt, probably shepherded by an unseen planet. The newly discovered belt is demarcated by an inner gap, located at ~78 au, and it is misaligned relative to the outer belt. The previously known collisionally generated dust cloud, Fomalhaut b, could have originated from this belt, suggesting increased dynamical stirring and collision rates there. We also discovered a large dust cloud within the outer ring, possible evidence of another dust-creating collision. Taken together with previous observations, Fomalhaut appears to be the site of a complex and possibly dynamically active planetary system