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Measuring Terzaghi’s effective stress by decoding force transmission in fluid-saturated granular media
No full textForce transmission between solid and fluid phases in fluid-saturated granular systems is yet to be fully resolved. This is rooted in our inability to measure inter-particle forces in opaque systems in the presence of fluids. At the same time, the concept of effective stress was introduced by Karl Terzaghi a century ago, but this empirical approach is yet to be linked to grain-scale phenomena experimentally. To this end, we derive an expression for the effective stress based on inter-particle forces and use a hybrid optical–mechanical method to directly measure the evolution of inter-particle forces and effective stress, offering a new perspective on how forces are distributed between solid and fluid phases. While our derivation and measurement of effective stress focuses on the limiting case of the Terzaghi stress, the methodology presented herein could be extended to more general situations, such as unsaturated conditions, where the micro-mechanical origin of effective stress remains elusive
Resolving the H i in damped Lyman α systems that power star formation
No full textReservoirs of dense atomic gas (primarily hydrogen) contain approximately 90 per cent of the neutral gas at a redshift of 3, and contribute to between 2 and 3 per cent of the total baryons in the Universe. These ‘damped Lyman α systems’—so called because they absorb Lyman α photons within and from background sources—have been studied for decades, but only through absorption lines present in the spectra of background quasars and γ-ray bursts. Such pencil beams do not constrain the physical extent of the systems. Here we report integral-field spectroscopy of a bright, gravitationally lensed galaxy at a redshift of 2.7 with two foreground damped Lyman α systems. These systems are greater than 238 kiloparsecs squared in extent, with column densities of neutral hydrogen varying by more than an order of magnitude on scales of less than 3 kiloparsecs. The mean column densities are between 10^(20.46) and 10^(20.84) centimetres squared and the total masses are greater than 5.5 × 10⁸–1.4 × 10⁹ times the mass of the Sun, showing that they contain the necessary fuel for the next generation of star formation, consistent with relatively massive, low-luminosity primeval galaxies at redshifts greater than 2
Examining the Impact of Relative Mechanophore Activity on the Selectivity of Ultrasound-Induced Mechanochemical Chain Scission
No full textDespite recent advances in polymer mechanochemistry, a more complete understanding of the factors that dictate the ultrasound-induced mechanochemical activation efficiency of mechanophores is necessary. Here, we examine how the identity of a mechanophore, and hence its unique force-coupled reactivity, affects the competition between mechanophore activation and nonspecific polymer backbone scission. Polymers incorporating distinct mechanophores but with putatively similar “chain-centeredness” exhibit widely different mechanochemical activation efficiencies. Furthermore, we employ mechanophores that can be orthogonally cleaved following ultrasonication using heat or light to report on the degree of nonspecific backbone scission that occurs for different mechanophore-containing polymers subjected to ultrasound-induced mechanical force. Our results illustrate that the identity of the mechanophore as well as its position in the polymer chain are inextricably important parameters that together control the selectivity of mechanophore activation during ultrasonication
Asymptotic burnout and homeostatic awakening: a possible solution to the Fermi paradox?
No full textPrevious studies show that city metrics having to do with growth, productivity and overall energy consumption scale superlinearly, attributing this to the social nature of cities. Superlinear scaling results in crises called ‘singularities’, where population and energy demand tend to infinity in a finite amount of time, which must be avoided by ever more frequent ‘resets’ or innovations that postpone the system's collapse. Here, we place the emergence of cities and planetary civilizations in the context of major evolutionary transitions. With this perspective, we hypothesize that once a planetary civilization transitions into a state that can be described as one virtually connected global city, it will face an ‘asymptotic burnout’, an ultimate crisis where the singularity-interval time scale becomes smaller than the time scale of innovation. If a civilization develops the capability to understand its own trajectory, it will have a window of time to affect a fundamental change to prioritize long-term homeostasis and well-being over unyielding growth—a consciously induced trajectory change or ‘homeostatic awakening’. We propose a new resolution to the Fermi paradox: civilizations either collapse from burnout or redirect themselves to prioritizing homeostasis, a state where cosmic expansion is no longer a goal, making them difficult to detect remotely
Analytical expressions for the clipping of Laguerre– and Hermite–Gauss modes by circular apertures
No full textWe present a closed-form analytical expression that describes the effect of clipping by circular apertures on laser beams, described in terms of an expansion in eigenmodes of the paraxial wave equation, in either the Laguerre–Gauss or Hermite–Gauss bases. This result provides a faster and more accurate way to compute the coupling between higher-order modes, compared to commonly used grid-based numerical integration
F₁-ATPase Rotary Mechanism: Interpreting Results of Diverse Experimental Modes With an Elastic Coupling Theory
No full textIn this chapter, we review single-molecule observations of rotary motors, focusing on the general theme that their mechanical motion proceeds in substeps with each substep described by an angle-dependent rate constant. In the molecular machine F₁-ATPase, the stepping rotation is described for individual steps by forward and back reaction rate constants, some of which depend strongly on the rotation angle. The rotation of a central shaft is typically monitored by an optical probe. We review our recent work on the theory for the angle-dependent rate constants built to treat a variety of single-molecule and ensemble experiments on the F₁-ATPase, and relating the free energy of activation of a step to the standard free energy of reaction for that step. This theory, an elastic molecular transfer theory, provides a framework for a multistate model and includes the probe used in single-molecule imaging and magnetic manipulation experiments. Several examples of its application are the following: (a) treatment of the angle-dependent rate constants in stalling experiments, (b) use of the model to enhance the time resolution of the single-molecule imaging apparatus and to detect short-lived states with a microsecond lifetime, states hidden by the fluctuations of the imaging probe, (c) treatment of out-of-equilibrium “controlled rotation” experiments, (d) use of the model to predict, without adjustable parameters, the angle-dependent rate constants of nucleotide binding and release, using data from other experiments, and (e) insights obtained from correlation of kinetic and cryo-EM structural data. It is also noted that in the case where the release of ADP would be a bottleneck process, the binding of ATP to another site acts to accelerate the release by 5–6 orders of magnitude. The relation of the present set of studies to previous and current theoretical work in the field is described. An overall goal is to gain mechanistic insight into the biological function in relation to structure
Keldysh Space Control of Charge Dynamics in a Strongly Driven Mott Insulator
No full textThe fate of a Mott insulator under strong low frequency optical driving conditions is a fundamental problem in quantum many-body dynamics. Using ultrafast broadband optical spectroscopy, we measured the transient electronic structure and charge dynamics of an off-resonantly pumped Mott insulator Ca₂RuO₄. We observe coherent bandwidth renormalization and nonlinear doublon-holon pair production occurring in rapid succession within a sub-100-fs pump pulse duration. By sweeping the electric field amplitude, we demonstrate continuous bandwidth tuning and a Keldysh crossover from a multiphoton absorption to quantum tunneling dominated pair production regime. Our results provide a procedure to control coherent and nonlinear heating processes in Mott insulators, facilitating the discovery of novel out-of-equilibrium phenomena in strongly correlated systems
Hydrodynamic simulations of electron-capture supernovae: progenitor and dimension dependence
No full textWe present neutrino-transport hydrodynamic simulations of electron-capture supernovae (ECSNe) in flash with new two-dimensional (2D) collapsing progenitor models. These progenitor models feature the 2D modelling of oxygen-flame propagation until the onset of core collapse. We perform axisymmetric simulations with six progenitor models that, at the time of collapse, span a range of propagating flame front radii. For comparison, we also perform a simulation with the same set-up using the canonical, spherically symmetrical progenitor model n8.8. We found that the variations in the progenitor models inherited from simulations of stellar evolution and flame propagation do not significantly alter the global properties of the neutrino-driven ECSN explosion, such as the explosion energy (∼1.36–1.48 × 10⁵⁰ erg) and the mass (∼0.017–0.018 M_⊙) and composition of the ejecta. Due to aspherical perturbations induced by the 2D flame, the ejecta contains a small amount (≲ 1.8 × 10⁻³ M_⊙) of low-Ye (0.35 < Yₑ < 0.4) component. The baryonic mass of the protoneutron star is ∼1.34 M_⊙ (∼1.357 M_⊙) with the new (n8.8) progenitor models when simulations end at ∼400 ms and the discrepancy is due to updated weak-interaction rates in the progenitor evolutionary simulations. Our results reflect the nature of ECSN progenitors containing a strongly degenerate oxygen–neon–magnesium (ONeMg) core and suggest a standardized ECSN explosion initialized by ONeMg core collapse. Moreover, we carry out a rudimentary three-dimensional simulation and find that the explosion properties are fairly compatible with the 2D counterpart. Our paper facilitates a more thorough understanding of ECSN explosions following the ONeMg core collapse, though more three-dimensional simulations are still needed
Neutrino follow-up with the Zwicky Transient Facility: Results from the first 24 campaigns
No full textThe Zwicky Transient Transient Facility (ZTF) performs a systematic neutrino follow-up program, searching for optical counterparts to high-energy neutrinos with dedicated Target-of-Opportunity (ToO) observations. Since first light in March 2018, ZTF has taken prompt observations for 24 high-quality neutrino alerts from the IceCube Neutrino Observatory, with a median latency of 12.2 hours from initial neutrino detection. From two of these campaigns, we have already reported tidal disruption event (TDE) AT2019dsg and likely TDE AT2019fdr as probable counterparts, suggesting that TDEs contribute >7.8% of the astrophysical neutrino flux. We here present the full results of our program through to December 2021. No additional candidate neutrino sources were identified by our program, allowing us to place the first constraints on the underlying optical luminosity function of astrophysical neutrino sources. Transients with optical absolutes magnitudes brighter that -21 can contribute no more than 87% of the total, while transients brighter than -22 can contribute no more than 58% of the total, neglecting the effect of extinction. These are the the first observational constraints on the neutrino emission of bright populations such as superluminous supernovae. None of the neutrinos were coincident with bright optical AGN flares comparable to that observed for TXS 0506+056/IC170922A, suggesting that most astrophysical neutrinos are not produced during such optical flares. We highlight the outlook for electromagnetic neutrino follow-up programs, including the expected potential for the Rubin Observatory
Amazonian terrestrial water balance inferred from satellite-observed water vapor isotopes
No full textAtmospheric humidity and soil moisture in the Amazon forest are tightly coupled to the region’s water balance, or the difference between two moisture fluxes, evapotranspiration minus precipitation (ET-P). However, large and poorly characterized uncertainties in both fluxes, and in their difference, make it challenging to evaluate spatiotemporal variations of water balance and its dependence on ET or P. Here, we show that satellite observations of the HDO/H₂O ratio of water vapor are sensitive to spatiotemporal variations of ET-P over the Amazon. When calibrated by basin-scale and mass-balance estimates of ET-P derived from terrestrial water storage and river discharge measurements, the isotopic data demonstrate that rainfall controls wet Amazon water balance variability, but ET becomes important in regulating water balance and its variability in the dry Amazon. Changes in the drivers of ET, such as above ground biomass, could therefore have a larger impact on soil moisture and humidity in the dry (southern and eastern) Amazon relative to the wet Amazon