Institutional Repository of Yantai Institute of Coastal Zone Research, CAS
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Polymeric membrane potentiometric antibiotic sensors using computer-aided screening of supramolecular macrocyclic carriers
No full textCarrier-based polymeric membrane potentiometric sensors are an ideal tool for detecting ionic species. However, in the fabrication of these sensors, the screening of carriers still relies on empirical trial- and error-based optimization, which requires tedious and time-consuming experimental verification. In this work, computer-aided screening of carriers is applied in the preparation of polymeric membrane potentiometric sensors. Molecular docking is used to study the host-guest interactions between receptors and targets. Binding energies are employed as the standard to screen the appropriate carrier. As a proof-of-concept experiment, the antibiotic ciprofloxacin is selected as the target model. A series of supramolecular macrocyclic receptors including cyclodextrins, cucurbiturils and calixarenes are chosen as potential receptors. The proposed sensor based on the receptor calix[4]arene screened by molecular docking shows a lower detection limit of 0.5 mu mol L-1 for ciprofloxacin. It can be expected that the proposed computer-aided screening technique of carriers can provide a simple but highly efficient method for the fabrication of carrier-based electrochemical and optical sensors.
A polymeric membrane potentiometric antibiotic sensor using computationally screened supramolecular macrocyclic carriers by the molecular docking technique is described
Reproductive biology of <i>Hemitripterus villosus</i> in the Bohai Strait, China
No full textTo understand the reproductive biology of Hemitripterus villosus in the Bohai Strait, and fill the key knowledge gap in verifying reproductive seasonality and documenting gonadotropin dependent reproductive cycle of this species, a year-round detail study was conducted for the first time. In total, 263 individuals were randomly sampled off the coasts of the Bohai Strait. Results show that and the overall female-to-male ratio (1.35:1) did not differ significantly from the 1:1 sex ratio. The length and weight relationship for females and males were regressed, depicting an isometric growth for both sexes. Four reproductive phases of the complete gonadotropin dependent reproductive cycle in both sexes were identified. The monthly variations in the gonadosomatic and hepatosomatic indexes for both sexes further indicated that this species spawns a single batch of eggs per year and the peak spawning period is from October to December. The average diameter of eggs ranged from 2.10 to 3.57 mm. The length at first sexual maturity was 224.87 mm for females and 241.26 mm for males. Significant positive relationships between absolute fecundity and fish size, and also gonadal weight were observed. H. villosus from the Bohai Strait exhibited smaller body size, smaller egg diameter, lower gonadosomatic index, lower absolute fecundity, and higher population extinction risk than the other populations' studied previously. Our findings contribute to understanding the status of this isolated westernmost population, and we emphasize that more efficient protection measures for the species and control measures are urgently required to improve the coastal environment in the Bohai Strait
Seasonal distribution of caffeine in the Bohai Sea, Yellow Sea, and estuaries of Yantai City, China
No full textWe employed a validated method to assess the seasonal variation and distribution of caffeine in the Bohai and Yellow Seas, as well as in Yantai urban estuaries and offshore region in northern China. Caffeine concentrations were highest during the summer in the Yellow Sea (1436.4 ng/L) and lowest in the Yantai urban offshore region during the spring and autumn and in the Yantai urban estuarine area and Bohai Sea during the winter (0.1 ng/L). There was significant variation in maximum caffeine levels among seasons across all regions examined, reaching a difference of 5980.5 times at the same sampling site between summer and winter. The caffeine concentration in the Yantai offshore region was significantly higher than in the Bohai and Yellow Seas. This study is the first investigation of seasonal fluctuations in the pollution levels of neurotoxic substances in the northern seas of China
Preliminary Performance Assessment of the Wave Parameter Retrieval Algorithm from the Average Reflected Pulse
No full textTo obtain new information about surface waves, it is proposed to use an underwater acoustic wave gauge, and an assessment of its effectiveness can be performed using a numerical simulation and field experiment. A new device, an underwater acoustic wave gauge named "Kalmar", was developed by the Institute of Applied Physics of the Russian Academy of Sciences for long-term, all-weather monitoring of wind waves. The instrument uses ultrasound to probe the water surface from underwater and can be used to verify remote sensing data. In this work, the capabilities of the device are tested and compared with ADCP data. Two independent methods for processing underwater acoustic wave gauge data are discussed and compared. One of them is completely new for acoustic measurements and is based on the analysis of the shape of the reflected acoustic pulse averaged over space and time. The other allows processing individual reflected pulses and calculating the time implementation of the distance to the water surface. It is shown that two independent methods of significant wave height retrieval from the acoustic wave gauge measurements are highly correlated. The "Kalmar" acoustic wave gauge and the RDI WH-600 acoustic Doppler current profiler operated simultaneously at the test site in Gelendzhik from 1 February to 10 February 2020. The significant wave heights measured by the two instruments are in good agreement
From dynamics to sustainability: Modeling the shrimp<i> (Penaeus</i><i> chinensis)</i> fishery in Shandong, China
No full textSince 1984, the stocking of shrimp juveniles has been implemented in the Bohai Sea, China as a strategy to manage the depleted marine fishery. Subsequently, major harvest restriction policies including "Dual Control" (1987), "Summer Fishing Moratorium" (1995), and "Fishermen Transfer and Fishing Fleet Scraping" (2003) were gradually implemented to reduce fishing intensity. However, the relative effectiveness of these three policy changes and management improvements, such as varying stocking quantity, adjusting the duration of the summer fishing ban, and reducing fishing intensity rate have rarely been assessed before their implementation. To address this gap, we developed a System Dynamic model that incorporated multiple scenarios related to these strategies in the shrimp fishery. Using Penaeus chinensis shrimp in the coastal province of Shandong, China, as a test case, we simulated the harvest metrics and stock size for each scenario. Our model predictions revealed that among the three strategies, extending the duration of the summer fishing ban is the most likely to improve the harvest metrics, while reducing fishing intensity significantly increases shrimp abundance. Based on the research findings, we recommend an optimal combination of the three strategies: releasing approximately 700 million individual juveniles per year, decreasing the fishing intensity rate to 0.65, and increasing the duration of the summer fishing ban to 123 days, from 1 May to 31 August. The research outcomes contribute to evidence-based decision-making and sustainable management practices in the Bohai Sea shrimp fishery and beyond
Molecular signatures and formation mechanisms of water-soluble chromophores in particulate matter from Karachi in Pakistan
No full textExcitation -emission matrix (EEM) fluorescence spectroscopy is a widely -used method for characterizing the chemical components of brown carbon (BrC). However, the molecular basics and formation mechanisms of chromophores, which are decomposed by parallel factor (PARAFAC) analysis, are not yet fully understood. In this study, we characterized the water-soluble organic carbon (WSOC) in aerosols collected from Karachi, Pakistan, using EEM spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). We identified three PARAFAC components, including two humic-like components (C1 and C2) and one phenolic -like species (C3). We determined the molecular families associated with each component by performing Spearman correlation analysis between FT-ICR MS peaks and PARAFAC component intensities. We found that the C1 and C2 components were associated with nitrogen -enriched compounds, where C2 with the longest emission wavelength exhibited a higher level of aromaticity, N content, and oxygenation than C1. The C3 associated formulas have fewer nitrogen -containing species, a lower unsaturation degree, and a lower oxidation state. An oxidation pathway was identified as an important process in the formation of C1 and C2 components at the molecular level, particularly for the assigned CHON compounds associated with the gas -phase oxidation process, despite their diverse precursor types. Numerous C2 formulas were found in the "potential BrC" region and overlapped with the BrC-associated formulas. It can be inferred that the compounds that fluoresce C2 contributed considerably to the light absorption of BrC. These findings are essential for future studies utilizing the EEM-PARAFAC method to explore the sources, processes, and compositions of atmospheric BrC
Evolutionary dynamics of island shoreline in the context of climate change: insights from extensive empirical evidence
No full textThe evolution and future trajectory of island shorelines, amidst global climate change, are of increasing concern to governments, communities and researchers worldwide. However, the field of island studies is often hampered by a lack of data and inconsistent methodologies, leading to an inadequate understanding of the processes driving shoreline changes on islands within the context of climate change. This research aims to bridge this gap by analyzing islands in Southeast Asia, the Indian Ocean and the Mediterranean Sea from 1990 to 2020 using remote sensing. Of over 13,000 islands examined, approximately 12% experienced significant shifts in shoreline positions. The total shoreline length of these islands approaches 200,000 km, with 7.57% showing signs of landward erosion and 6.05% expanding seaward. Human activities, particularly reclamation and land filling, were identified as primary drivers of local shoreline transformations, while natural factors have a comparatively minor impact. Moreover, the ongoing rise in sea levels is identified as an exacerbating factor for coastal erosion rather than the primary cause. Drawing from these findings, we propose several adaptive measures for islands in response to climate change. Taken together, this research provides comprehensive data and a basis for decision-making for sustainable development of island territories
Molecular Imprinting-Based SERS Detection Strategy for the Large-Size Protein Quantitation and Curbing Non-Specific Recognition
No full textMolecular imprinting-based surface-enhanced Raman scattering (MI-SERS) sensors have shown remarkable potential from an academic standpoint. However, their practical applications, especially in the detection of large-size protein (>= 10 nm), face challenges due to the lack of versatile sensing strategies and nonspecific fouling of matrix species. Herein, we propose a Raman reporter inspector mechanism (RRIM) implemented on a protein-imprinted polydopamine (PDA) layer coated on the SERS active substrate. In the RRIM, after large-size protein recognition, the permeability of the PDA imprinted cavities undergoes changes that are scrutinized by Raman reporter molecules. Target proteins can specifically bind and fully occupy the imprinted cavities, whereas matrix species cannot. Then, Raman reporter molecules with suitable size are introduced to serve as both inspectors of the recognition status and inducers of the SERS signal, which can only penetrate through the vacant and nonspecifically filled cavities. Consequently, changes in the SERS signal exclusively originate from the specific binding of target proteins, while the nonspecific recognition of matrix species is curbed. The RRIM enables reproducible quantitation of the large-size cyanobacteria-specific protein model (>= 10 nm), phycocyanin, at the level down to 2.6 x 10-3 mu g L-1. Finally, the practical applicability of the RRIM is confirmed by accurately analyzing crude urban waterway samples over 21 min without any pretreatment
Carbon fluxes of China's coastal wetlands and impacts of reclamation and restoration
No full textCoastal wetlands play an important role in regulating atmospheric carbon dioxide (CO2) concentrations and contribute significantly to climate change mitigation. However, climate change, reclamation, and restoration have been causing substantial changes in coastal wetland areas and carbon exchange in China during recent decades. Here we compiled a carbon flux database consisting of 15 coastal wetland sites to assess the magnitude, patterns, and drivers of carbon fluxes and to compare fluxes among contrasting natural, disturbed, and restored wetlands. The natural coastal wetlands have the average net ecosystem exchange of CO2 (NEE) of -577 g C m(-2) year(-1), with -821 g C m(-2) year(-1) for mangrove forests and -430 g C m(-2) year(-1) for salt marshes. There are pronounced latitudinal patterns for carbon dioxide exchange of natural coastal wetlands: NEE increased whereas gross primary production (GPP) and respiration of ecosystem decreased with increasing latitude. Distinct environmental factors drive annual variations of GPP between mangroves and salt marshes; temperature was the dominant controlling factor in salt marshes, while temperature, precipitation, and solar radiation were co-dominant in mangroves. Meanwhile, both anthropogenic reclamation and restoration had substantial effects on coastal wetland carbon fluxes, and the effect of the anthropogenic perturbation in mangroves was more extensive than that in salt marshes. Furthermore, from 1980 to 2020, anthropogenic reclamation of China's coastal wetlands caused a carbon loss of similar to 3720 Gg C, while the mangrove restoration project during the period of 2021-2025 may switch restored coastal wetlands from a carbon source to carbon sink with a net carbon gain of 73 Gg C. The comparison of carbon fluxes among these coastal wetlands can improve our understanding of how anthropogenic perturbation can affect the potentials of coastal blue carbon in China, which has implications for informing conservation and restoration strategies and efforts of coastal wetlands
Beyond the promise: Exploring the complex interactions of nanoparticles within biological systems
No full textThe exploration of nanoparticle applications is filled with promise, but their impact on the environment and human health raises growing concerns. These tiny environmental particles can enter the human body through various routes, such as the respiratory system, digestive tract, skin absorption, intravenous injection, and implantation. Once inside, they can travel to distant organs via the bloodstream and lymphatic system. This journey often results in nanoparticles adhering to cell surfaces and being internalized. Upon entering cells, nanoparticles can provoke significant structural and functional changes. They can potentially disrupt critical cellular processes, including damaging cell membranes and cytoskeletons, impairing mitochondrial function, altering nuclear structures, and inhibiting ion channels. These disruptions can lead to widespread alterations by interfering with complex cellular signaling pathways, potentially causing cellular, organ, and systemic impairments. This article delves into the factors influencing how nanoparticles behave in biological systems. These factors include the nanoparticles' size, shape, charge, and chemical composition, as well as the characteristics of the cells and their surrounding environment. It also provides an overview of the impact of nanoparticles on cells, organs, and physiological systems and discusses possible mechanisms behind these adverse effects. Understanding the toxic effects of nanoparticles on physiological systems is crucial for developing safer, more effective nanoparticlebased technologies