Institutional Repository of GuangZhou Institute of Energy Conversion, CAS
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Co-pyrolysis and activation of microalgae and waste polypropylene in the synthesis of nitrogen doped and porous carbon for pollutant adsorption
Algae and waste plastics are two promising raw materials for the preparation of carbon -based adsorbents, which are regarded as the promising adsorbent to remove pollutants in wastewater. To obtain an activated carbon with well -developed porous structure and abundant functional groups, the mixture of H -rich disposable waste polypropylene (WP) and N -rich Chlorella vulgaris (CV) were selected as precursors through co -pyrolysis and KOH activation. The optimum mass ratio of WP and CV for preparing co -pyrolysis carbon (CPC) was 1:3, while the optimum mass ratio of CPC and KOH for preparing co -pyrolysis activated carbon (CAC) was 1:5 at the activation temperature of 800 degrees C. The morphologies, mean pore diameter, material surface element and degree of graphitization of CAC were analyzed by SEM, BET, XRD, XPS and Raman spectroscopy, respectively. The adsorption kinetics and thermodynamics of tetracycline (TC) onto CPC were investigated. And the sustainability of algal -based activated carbon in adsorption of pollutants has been tested. This study provides a synthesis method of CAC by using algal -based biomass and waste plastics for the absorption of organic pollutants in wastewaters
Numerical simulation of single-well enhanced geothermal power generation system based on discrete fracture model
This study proposes a single-well enhanced geothermal system (SEGS) to mitigate the high-risk of traditional Enhanced Geothermal Systems (ESGs) with two or more wells and enhance the general applicability. A detailed thermodynamic model that couples the wellbore, reservoir, and organic Rankine cycle is built. For the reservoir, a three-dimensional flow and heat transfer model featuring a discrete fracture network is employed. The effects of injection flow rate, injection temperature, branch well length, and branch well spacing on net output work, pump power consumption, thermal efficiency, and exergy efficiency have been investigated. The results indicate that an increase in the injection flow rate improves the shaft power of the expander and the power consumption of the injection pump. An optimal flow rate of 30 kg/s is identified, which maximizes the annual net power output to 1221.2 kW. Additionally, an increase in the injection temperature is found to enhance the buoyancy effect, thereby improving both thermal and exergy efficiency, and reducing the power consumption of the injection pump. The maximum net output power is achieved at an injection temperature of 60 degrees C. The study also notes that the branch well length has a negligible effect on thermal and exergy efficiency and expander shaft work. However, a longer branch well length contributes to a decrease in the power consumption of the injection pump and an increase in the net power output. Finally, it is observed that increasing the lateral well spacing slows the rate decay of the production temperature. A spacing of 360 m is found to yield a maximum annual net output power of 1259.4 kW. In conclusion, this study offers significant insights and practical guidance for the development and utilization of SEGS, demonstrating its potential as an effective alternative to conventional EGS methodologies
Numerical simulation of single-well enhanced geothermal power generation system based on discrete fracture model
This study proposes a single-well enhanced geothermal system (SEGS) to mitigate the high-risk of traditional Enhanced Geothermal Systems (ESGs) with two or more wells and enhance the general applicability. A detailed thermodynamic model that couples the wellbore, reservoir, and organic Rankine cycle is built. For the reservoir, a three-dimensional flow and heat transfer model featuring a discrete fracture network is employed. The effects of injection flow rate, injection temperature, branch well length, and branch well spacing on net output work, pump power consumption, thermal efficiency, and exergy efficiency have been investigated. The results indicate that an increase in the injection flow rate improves the shaft power of the expander and the power consumption of the injection pump. An optimal flow rate of 30 kg/s is identified, which maximizes the annual net power output to 1221.2 kW. Additionally, an increase in the injection temperature is found to enhance the buoyancy effect, thereby improving both thermal and exergy efficiency, and reducing the power consumption of the injection pump. The maximum net output power is achieved at an injection temperature of 60 degrees C. The study also notes that the branch well length has a negligible effect on thermal and exergy efficiency and expander shaft work. However, a longer branch well length contributes to a decrease in the power consumption of the injection pump and an increase in the net power output. Finally, it is observed that increasing the lateral well spacing slows the rate decay of the production temperature. A spacing of 360 m is found to yield a maximum annual net output power of 1259.4 kW. In conclusion, this study offers significant insights and practical guidance for the development and utilization of SEGS, demonstrating its potential as an effective alternative to conventional EGS methodologies