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A silicon isotopic perspective on the contribution of diagenesis to the sedimentary silicon budget in the Southern Ocean
Get PDFDiatoms are known to fractionate silicon isotopes during the formation of their frustules causing the silicon isotopic composition of biogenic silica to track the degree of silicic acid consumption in surface waters. Despite a growing body of work that uses this proxy to reconstruct past changes in silicic acid utilization, the understanding of the benthic silicon cycle, particularly the identification and quantification of the processes that potentially alter the silicon isotopic composition of biogenic silica during early diagenesis is still lacking. We investigated these processes by comparing the silicon isotopic composition of pore water silicic acid, biogenic silica and, for the first time, lithogenic silica from five sediment cores collected in the deep basin of the Southern Ocean representing a diversity of sedimentation regimes. Silicic acid concentrations and the isotopic composition of Southern Ocean pore waters were the result of a dynamic balance between the dissolution of biogenic silica, reactive lithogenic silica phases and Si re-precipitation with the relative importance of each processes differing significantly between regions. The results are consistent with the formation of authigenic alumino-silicates derived from dissolved biogenic silica in the Sub-Antarctic Zone and in the Antarctic Zone (on average 12 ± 5% and 17 ± 13%, respectively). Since this latter process can fractionate silicon isotopes, this implies that, even if the silicon isotopic composition of diatoms preserved in the sediments is a reliable proxy for silicic acid utilization in the past ocean, care must be taken to extract a clean biogenic silica phase free of authigenic clays and lithogenic phases from sediments to eliminate this potential bias when interpreting isotopic records
The upper ocean silicon cycle of the subarctic Pacific during the EXPORTS field campaign
Get PDFDiatoms are major contributors to marine primary productivity and carbon export due to their rapid growth in high-nutrient environments and their heavy silica ballast. Their contributions are highly modified in high-nutrient low-chlorophyll regions due to the decoupling of upper-ocean silicon and carbon cycling caused by low iron (Fe). The Si cycle and the role of diatoms in the biological carbon pump was examined at Ocean Station Papa (OSP) in the HNLC region of the northeastern subarctic Pacific during the NASA EXport Processes in the Ocean from RemoTe Sensing (EXPORTS) field study. Sampling occurred during the annual minimum in surface silicic acid (Si(OH)4) concentration. Biogenic silica (bSi) concentrations were low, being in the tens of nanomolar range, despite high Si(OH)4 concentrations of about 15 mM. On average, the \u3e5.0-mm particle size fraction dominated Si dynamics, accounting for 65% of bSi stocks and 81% of Si uptake compared to the small fraction (0.6-5.0 mm). Limitation of Si uptake was detected in the small, but not the large, size fraction. Growth rate in small diatoms was limited by Fe, while their Si uptake was restricted by Si(OH)4 concentration, whereas larger diatoms were only growth-limited by Fe. About a third of bSi production was exported out of the upper 100 m.The contribution of diatoms to carbon export (9-13%) was about twice their contribution to primary productivity (3-7%). The combination of low bSi production, low diatom primary productivity and high bSi export efficiency at OSP was more similar to the dynamics in the subtropical gyres than to other high-nutrient low-chlorophyll regions
Overview of the MOSAiC expedition: Snow and sea ice
Get PDFYear-round observations of the physical snow and ice properties and processes that govern the ice pack evolution and its interaction with the atmosphere and the ocean were conducted during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition of the research vessel Polarstern in the Arctic Ocean from October 2019 to September 2020. This work was embedded into the interdisciplinary design of the 5 MOSAiC teams, studying the atmosphere, the sea ice, the ocean, the ecosystem, and biogeochemical processes. The overall aim of the snow and sea ice observations during MOSAiC was to characterize the physical properties of the snow and ice cover comprehensively in the central Arctic over an entire annual cycle. This objective was achieved by detailed observations of physical properties and of energy and mass balance of snow and ice. By studying snow and sea ice dynamics over nested spatial scales from centimeters to tens of kilometers, the variability across scales can be considered. On-ice observations of in situ and remote sensing properties of the different surface types over all seasons will help to improve numerical process and climate models and to establish and validate novel satellite remote sensing methods; the linkages to accompanying airborne measurements, satellite observations, and results of numerical models are discussed. We found large spatial variabilities of snow metamorphism and thermal regimes impacting sea ice growth. We conclude that the highly variable snow cover needs to be considered in more detail (in observations, remote sensing, and models) to better understand snow-related feedback processes. The ice pack revealed rapid transformations and motions along the drift in all seasons. The number of coupled ice–ocean interface processes observed in detail are expected to guide upcoming research with respect to the changing Arctic sea ice
Rapid metabolism fosters microbial survival in the deep, hot subseafloor biosphere
Get PDFA fourth of the global seabed sediment volume is buried at depths where temperatures exceed 80 °C, a previously proposed thermal barrier for life in the subsurface. Here, we demonstrate, utilizing an extensive suite of radiotracer experiments, the prevalence of active methanogenic and sulfate-reducing populations in deeply buried marine sediment from the Nankai Trough subduction zone, heated to extreme temperature (up to ~120 °C). The small microbial community subsisted with high potential cell-specific rates of energy metabolism, which approach the rates of active surface sediments and laboratory cultures. Our discovery is in stark contrast to the extremely low metabolic rates otherwise observed in the deep subseafloor. As cells appear to invest most of their energy to repair thermal cell damage in the hot sediment, they are forced to balance delicately between subsistence near the upper temperature limit for life and a rich supply of substrates and energy from thermally driven reactions of the sedimentary organic matter
“Arriba las metodistas”: educación protestante, deportes y sufragio transnacional
No full textEl sufragio femenino, la templanza, la educación, la labor femenil, los deportes y la salud prenatal fueron aspectos en los cualeslas organizaciones de mujeres metodistas se enfocaron. Las escuelas metodistas para niñas y señoritas en México, muchas de ellas fundadas en la década de 1870, lograron ser herramientas útiles en la lucha de los derechos femeniles. A través de la mirada de mujeres metodistas y su educación, este artículo analiza la interacción entre el sufragio femenino transnacional, la participación en eventos deportivos, el nacionalismo revolucionario y los debates acerca del papel del protestantismo entre 1917 y1953. Este artículo se enfoca particularmente en la misionera y maestra norteamericana Clara M. Hill y la fundadora de Frente Único pro-Derechos de la Mujer (FUPDM) y periodista mexicana Margarita Robles de Mendoza
SITE-BASED ASSESSMENT OF OYSTER SHELLFISHERIES AND ASSOCIATED BIO-PHYSICAL CONDITIONS IN GHANA AND THE GAMBIA
Get PDFNew insights into the failure mechanisms of horizontal plate anchors in clay during pull-out
No full textOffshore wind developments are moving towards deep-water regions where energy is abundant, visual impact is minimised and the larger turbine sizes can make the energy production more cost-effective. One of the key challenges facing the industry is the development of reliable substructures. While fixed foundation systems are widely used for shallow-water (\u3c60 m) developments, permanent anchors are seen as one of the most viable mooring solutions for floating structures in deep water. In the current study, the pull-out behaviour of square plate anchors in clay was investigated using large-displacement finite-element analysis. The anchor capacity and failure mechanism were considered for a range of embedment ratios and undrained shear strengths. Three distinct modes of anchor failure identified in previous studies were examined through the analysis of four descriptors including: The pull-out capacity of the anchor, the pull-out displacement required to mobilise this capacity, the energy absorbed by the anchor during pull-out and the variation of the pull-out capacity with respect to a normalised overburden pressure. The findings of the study are presented in the form of a series of charts that can aid design through understanding of the factors controlling the development of anchor failure modes, in addition to identifying the transition point between different failure mechanisms
Field study of group effects on the pullout capacity of “deep” helical piles in sand
No full textThis paper presents the results of a field load test program used to investigate group effects on the pullout capacity of single-helix “deep” helical piles/anchors in sand. The high tensile capacity and silent installation of helical piles has given them serious consideration as an alternative to conventional deep foundations and anchors for offshore renewable energy structures. New offshore applications may consider the use of groups of helical piles to resist structural loads. Group interaction effects are known to occur in helical piles, but there is a scarcity of field data on groups in sands under tensile loading. This study involved the installation and load testing of single-helix 152 mm diameter round shaft piles and pile groups embedded in sand to depths of 12 and 18 helix diameters below the ground surface. The study was designed to explore the effects of close pile spacing, group configuration (i.e., number of piles), and soil strength (i.e., friction angle) as interpreted from cone penetration test (CPT) resistance. The results showed group efficiencies ranging from about 0.6 to 1.0 at a horizontal spacing of 2 to 3 times the helix diameter in sands with friction angles of about 39° to 44°. The data from this study may also be useful for validation of numerical models for analysis of helical pile group interactions
The Influence of US Drug Price Dynamics on Cost-Effectiveness Analyses of Biologics
Get PDFObjectives: This study aimed to evaluate the influence of drug price dynamics in cost-effectiveness analyses.
Methods: We evaluated scenarios involving typical US drug price increases during the exclusivity period and price decreases after the loss of exclusivity (LOE). Worked examples are presented using the Institute for Clinical and Economic Review’s assessments of tezepelumab for the treatment of severe asthma and targeted immune modulators for rheumatoid arthritis.
Results: Tezepelumab case: yearly 2% price increases during the period of exclusivity and a post-LOE price decrease of 25% yielded an incremental cost per quality-adjusted life-year (QALY) gained that increased over the base case from 444 600 (+3.2%). Yearly 2% price increases followed by a steeper post-LOE price reduction of 40% resulted in a cost per QALY gained of 121 000 and 119 200/QALY). Including a 2% yearly price increase during the projected exclusivity periods of both intervention and comparator increased the cost per QALY gained by \u3e 60%.
Conclusion: Two biologic treatment cases incorporating price dynamics in cost-effectiveness analyses had varied impacts on the cost-effectiveness ratio depending on the magnitude of pre-LOE price increase and post-LOE price decrease and whether the LOE also affected the comparator. Yearly price increase magnitude during the period of exclusivity, among other factors, may counterbalance the effects of lower post-LOE intervention prices
