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Effects of microfractures on permeability in carbonate rocks based on digital core technology
Carbonate reservoirs develop many different types of microfractures that play an important role in increasing the effective reservoir space and permeability. Thus, the qualitative and quantitative characterisation of the effect of microfractures on permeability in rocks is essential. In this study, a quantitative method for evaluating the impact of different microfracture parameters on carbonate rock permeability was proposed. Lattice Boltzmann simulations were carried on two carbonate digital cores with different types of artificially added microfractures. Based on the simulation results, a partial least squares regression analysis was used to investigate the impact of microfractures on the permeability of the cores. Increases in the fracture length, aperture, and density were found to linearly increase the permeability of the carbonate rocks, and as the fracture length increased to penetrate the whole core, an exponential increase in permeability was observed. Additionally, the effect of microfractures on the digital core permeability was more significant in cores with high permeability compared to that in low-permeability cores. Although both fractures and matrix permeability contribute to the permeability of the digital cores, the former were found to have a greater effect on the permeability.Cited as: Liu, C., Zhang, L., Li, Y., Liu, F., Martyushev, D. A., Yang, Y. Effects of microfractures on permeability in carbonate rocks based on digital core technology. Advances in Geo-Energy Research, 2022, 6(1): 86-90. https://doi.org/10.46690/ager.2022.01.0
Molecular dynamics simulations of oil recovery from dolomite slit nanopores enhanced by CO2 and N2 injection
Shale oil reservoirs are dominated by micro-and nanopores, which greatly impede the oil recovery rates. CO2 and N2 injection have proven to be highly effective approaches to enhance oil recovery from low-permeability shale reservoirs, and also represent great potential for CO2 sequestration. Therefore, a better understanding of the mechanism of shale oil recovery enhanced by CO2 and N2 is of great importance to achieve maximum shale oil productivity. In this paper, the adsorption behavior of shale oil and the mechanism of enhancing shale oil recovery by CO2 and N2 flooding in dolomite slit pores are investigated by performing nonequilibrium molecular dynamics simulations. Considering the shale oil adsorption behavior, mass density distribution is analyzed and the results indicate that a symmetric density distribution of the oil regarding the center in the slit pore along the x-axis can be obtained. The maximum density of the adsorbed layer nearest to the slit wall is 1.310 g/cm3 for C8H18 , which is about 2.0 times of that for bulk oil density in the middle area of slit pore. The interaction energy and radial distribution functions (between oil and CO2 , and between oil and N2 ) are calculated to display the displacement behavior of CO2 and N2 flooding. It is found that CO2 and N2 play different roles: CO2 has strong solubility, diffusivity and a higher interaction energy with dolomite wall, and the oil displacement efficiency of CO2 reaches 100% after 1 ns of flooding; however, during N2 flooding, the oil displacement efficiency is 87.3% after 4 ns of flooding due to the lower interaction energy between N2 and dolomite and that between N2 and oil.Cited as: Guo, H., Wang, Z., Wang, B., Zhang, Y., Meng, H., Sui, H. Molecular dynamics simulations of oil recovery from dolomite slit nanopores enhanced by CO2 and N2 injection. Advances in Geo-Energy Research, 2022, 6(4): 306-313. https://doi.org/10.46690/ager.2022.04.0
Investigation of shale gas flows under confinement using a self-consistent multiscale approach
This report summarises our recent findings on non-ideal gas flow characteristics in shale nanopores facilitated by our strongly-inhomogeneous kinetic model. As there are a significant portion of nano-scale pores in shale, gas molecule size is comparable to both the gas mean free path and the characteristic length of the flow domain, and various factors including fluid-solid and fluid-fluid interactions, pore confinement, surface roughness, and non-equilibrium effect need to be considered in a self-consistent manner. These factors are either considered in the governing equation according to the dense gas and mean-field theories, or through the boundary condition based on molecular dynamics simulations. Our kinetic model results are consistent with the molecular dynamics data at the molecular scale and converge to the continuum predictions when pores become large. This model serves as an accurate tool to investigate multiscale transport of shale gas and is helpful for upscaling from the microscopic to continuum levels with a firm theoretical basis.Cited as: Shan, B., Ju, L., Guo, Z., Zhang, Y. Investigation of shale gas flows under confinement using a self-consistent multiscale approach. Advances in Geo-Energy Research, 2022, 6(6): 537-538. https://doi.org/10.46690/ager.2022.06.1
Stability analysis of the water bridge in organic shale nanopores: A molecular dynamic study
In the last decades, shale gas development has relieved the global energy crisis and slowed global warming problems. The water bridge plays an important role in the process of shale gas diffusion, but the stability of the water bridge in the shale nanochannel has not been revealed. In this work, the molecular dynamics method is applied to study the interaction between shale gas and water bridge, and the stability can be tested accordingly. CO2 can diffuse into the liquid H2O phase, but CH4 only diffuses at the boundary of the H2O phase. Due to the polarity of H2O molecules, the water bridge presents the wetting condition according to model snapshots and one-dimensional analyses, but the main body of the water bridge in the two-dimensional contour shows the non-wetting condition, which is reasonable. Due to the effect of the molecular polarity, CO2 prefers to diffuse into kerogen matrixes and the bulk phase of water bridge. In the bulk of the water bridge, where the interaction is weaker, CO2 has a lower energy state, implies that it has a good solubility in the liquid H2O phase. Higher temperature does not facilitate the diffusion of CO2 molecules, and higher pressure brings more CO2 molecules and enhances the solubility of CO2 in the H2O phase, in addition, a larger ratio of CO2 increases its content, which does the same effects with higher pressures. The stability of the water bridge is disturbed by diffused CO2 , and its waist is the weakest position by the potential energy distribution.Cited as: Liu, J., Zhang, T., Sun, S. Stability analysis of the water bridge in organic shale nanopores: A molecular dynamic study. Capillarity, 2022, 5(4): 75-82. https://doi.org/10.46690/capi.2022.04.0
Review of underground hydrogen storage: Concepts and challenges
The energy transition is the pathway to transform the global economy away from its current dependence on fossil fuels towards net zero carbon emissions. This requires the rapid and large-scale deployment of renewable energy. However, most renewables, such as wind and solar, are intermittent and hence generation and demand do not necessarily match. One way to overcome this problem is to use excess renewable power to generate hydrogen by electrolysis, which is used as an energy store, and then consumed in fuel cells, or burnt in generators and boilers on demand, much as is presently done with natural gas, but with zero emissions. Using hydrogen in this way necessitates large-scale storage: the most practical manner to do this is deep underground in salt caverns, or porous rock, as currently implemented for natural gas and carbon dioxide. This paper reviews the concepts, and challenges of underground hydrogen storage. As well as summarizing the state-of-the-art, with reference to current and proposed storage projects, suggestions are made for future work and gaps in our current understanding are highlighted. The role of hydrogen in the energy transition and storage methods are described in detail. Hydrogen flow and its fate in the subsurface are reviewed, emphasizing the unique challenges compared to other types of gas storage. In addition, site selection criteria are considered in the light of current field experience.Document Type: Invited reviewCited as: Hematpur, H., Abdollahi, R., Rostami, S., Haghighi, M., Blunt, M. J. Review of underground hydrogen storage: Concepts and challenges. Advances in Geo-Energy Research, 2023, 7(2): 111-131. https://doi.org/10.46690/ager.2023.02.0
Investigation of fractured carbonate reservoirs by applying shear-wave splitting concept
In this study, fracture orientations in carbonate reservoirs were determined using a multicomponent velocity analysis based on shear wave splitting. The analysis is based on the estimated velocities of large seismic events with different polarizations. In a fractured zone with a dominant orientation, weak amplitude split shear events, including shear noise, result in shear waves that are polarized toward the symmetry and anisotropy axes and propagate with a common fast and slow velocity, respectively. Thus, a velocity stack should show high coherency anomalies in directions parallel and orthogonal to the fracture strike. Furthermore, because the analysis is applied locally at a specific depth range, it is less susceptible to the effects of overburden anisotropy and noise. The dominant fracture orientations from carbonate reservoirs of four oilfields were compared to those interpreted from fullbore microimager and core data. Fractures in two offshore reservoirs strike NNE-SSW and NW-SE, which are related to Zagros stress. Fractures in two onshore reservoir strikes NE-SW, while in deeper onshore reservoir fractures are aligned with N-S direction. The findings of this study are promising, particularly for the fractured reservoirs especially those located in Abu Dhabi, which are characterized by high heterogeneity and complex fracture network related to complex tectonic history. In order to obtain geometrical parameters of fractures at seismic scale, it is recommended to implement the analysis adapted in this study after acquiring three component zero-offset vertical seismic profiling.Document Type: Original articleCited as: Diaz-Acosta, A., Bouchaala, F., Kishida, T., Jouini, M. S., Ali, M. Y. Investigation of fractured carbonate reservoirs by applying shear-wave splitting concept. Advances in Geo-Energy Research, 2023, 7(2): 99-110. https://doi.org/10.46690/ager.2023.02.0
Strengthening and weakening of methane hydrate by water vacancies
Gas clathrate hydrates show promising applications in sustainable technologies such as future energy resources, gas capture and storage. The stability of clathrate hydrates under external load is of great crucial to those important applications, but remains unknown. Water vacancy is a common structural defect in clathrate hydrates. Herein, the mechanical characteristics of sI methane hydrates containing three types of water vacancy are investigated by molecular dynamics simulations with four different water forcefields. Mechanical properties of methane hydrates such as tensile strength are dictated not only by the density but also the type of water vacancy. Surprisingly, the tensile strength of methane hydrates can be weakened or strengthened, depending on the adopted water model and water vacancy density. Strength enhancement mainly results from the formation of new water cages. This work provides critical insights into the mechanics and microstructural properties of methane clathrate hydrates under external load, which is of primary importance in the recovery of natural gas from methane hydrate reservoirs.Cited as: Lin, Y., Liu, Y., Xu, K., Li, T., Zhang, Z., Wu, J. Strengthening and weakening of methane hydrate by water vacancies. Advances in Geo-Energy Research, 2022, 6(1): 23-37. https://doi.org/10.46690/ager.2022.01.0
Characterization of mineral and pore evolution under CO2-brine-rock interaction at in-situ conditions
Herein, a method of physical modeling of CO2-brine-rock interaction and in-situ characterization of mineral and pore evolution is established. The nested preparation and installation of the same sample with different sizes could protect and keep the integrality of the millimeter-size sample in conventional high-temperature and high-pressure reactors. This paper establishes a procedure to obtain the three-dimensional in-situ comparison of minerals and pores before and after the reaction. The resolution is updated from 5-10 µ m to 10 nm, which could be helpful for modeling CO2-brine-rock interaction in unconventional tight reservoirs. This method could be applied to CO2-enhanced oil recovery as well as CO2 capture, utilization, and storage scientific research. Furthermore, it may shed light on the carbon sequestration schemes in the Chinese petroleum industry.Cited as: Wu, S., Yu, C., Hu, X., Yu, Z., Jiang, X. Characterization of mineral and pore evolution under CO2-brine-rock interaction at in-situ conditions. Advances in Geo-Energy Research, 2022, 6(2): 177-178. https://doi.org/10.46690/ager.2022.02.0
Hydraulic fracturing-induced seismicity characterization through coupled modeling of stress and fracture-fault systems
This work summarizes our recent findings on hydraulic fracturing-induced seismicity nucleated in the Duvernay shale reservoirs within the Western Canada Sedimentary Basin. A coupled model of in-situ stress and fracture-fault systems was built to quantify four-dimensional stress and pressure changes and spatiotemporal seismicity nucleation during hydraulic fracturing. Five triggering mechanisms were successfully recognized in seismicity-frequent areas, including a direct hydraulic connection between impermeable faults and hydraulic fractures, fault slip owing to downward pressure diffusion, fault reactivation due to upward poroelastic stress perturbation, aftershocks of mainshock events, and reactivation of natural fractures surrounding the faults. This work shed light on how fracturing operations triggered the induced seismicity, providing a solid foundation for the investigation of controlling factors and mitigation strategies for hydraulic fracturing-induced seismicity.Cited as: Hui, G., Chen, Z., Chen, S., Gu, F. Hydraulic fracturing-induced seismicity characterization through coupled modeling of stress and fracture-fault systems. Advances in Geo-Energy Research, 2022, 6(3): 269-270. https://doi.org/10.46690/ager.2022.03.1
Super-resolution reconstruction of digital rock CT images based on residual attention mechanism
Computer tomography technology is widely used in geological exploration because it is a nondestructive and three-dimensional imaging method that can be integrated with computer simulation. However, the large-scale application of the computer tomography technique is limited by economic costs and time consumption. Therefore, it is challenging and intractable to indicate the pore structure characteristics of rock. To address this issue, a super-resolution reconstruction algorithm based on convolutional neural networks, residual learning, and attention mechanism was proposed to generate super-resolution images in this study. This algorithm was applied to the reconstruction of carbonate rock and sandstone. The performance of two-dimensional image reconstruction was evaluated by quantitative extraction and qualitative visualization. The results from experiments indicate that the built model performs well on different upscaling factors and is superior to the existing super-resolution approaches based on convolutional neural network.Cited as: Shan, L., Bai, X., Liu, C., Feng, Y., Liu, Y., Qi, Y. Super-resolution reconstruction of digital rock CT images based on residual attention mechanism. Advances in Geo-Energy Research, 2022, 6(2): 157-168. https://doi.org/10.46690/ager.2022.02.0