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Measurement of production in association with additional b-jets in the eμ final state in proton–proton collisions at = 13 TeV with the ATLAS detector
No full textThis paper presents measurements of top-antitop quark pair () production in association with additional b-jets. The analysis utilises 140 fb of proton–proton collision data collected with the ATLAS detector at the Large Hadron Collider at a centre-of-mass energy of 13 TeV. Fiducial cross-sections are extracted in a final state featuring one electron and one muon, with at least three or four b-jets. Results are presented at the particle level for both integrated cross-sections and normalised differential cross-sections, as functions of global event properties, jet kinematics, and b-jet pair properties. Observable quantities characterising b-jets originating from the top quark decay and additional b-jets are also measured at the particle level, after correcting for detector effects. The measured integrated fiducial cross-sections are consistent with predictions from various next-to-leading-order matrix element calculations matched to a parton shower within the uncertainties of the predictions. State-of-the-art theoretical predictions are compared with the differential measurements; none of them simultaneously describes all observables. Differences between any two predictions are smaller than the measurement uncertainties for most observables.[graphic not available: see fulltext
Measurement of the Lund jet plane in hadronic decays of top quarks and W bosons with the ATLAS detector
No full textThe Lund jet plane (LJP) is measured for the first time in events, using 140 of TeV pp collision data collected with the ATLAS detector at the LHC. The LJP is a two-dimensional observable of the sub-structure of hadronic jets that acts as a proxy for the kinematics of parton showers and hadron formation. The observable is constructed from charged particles and is measured for anti- jets with transverse momentum above 350 GeV containing the full decay products of either a top quark or a daughter W boson. The other top quark in the event is identified from its decay into a b-quark, an electron or a muon and a neutrino. The measurement is corrected for detector effects and compared with a range of Monte Carlo predictions sensitive to different aspects of the hadronic decays of the heavy particles. In the W-boson-initiated jets, all the predictions are incompatible with the measurement. In the top quark initiated jets, disagreement with all predictions is observed in smaller subregions of the plane, and with a subset of the predictions across the fiducial plane. The measurement could be used to improve the tuning of Monte Carlo generators, for better modelling of hadronic decays of heavy quarks and bosons, or to improve the performance of jet taggers
Local-in-Time Conservative Binary Dynamics at Fifth Post-Minkowskian and First Self-Force Orders
No full textWe report the local-in-time conservative dynamics of nonspinning binary systems at fifth Post-Minkowskian (5PM) and first self-force (1SF) orders. This follows from an explicit calculation of the 5PM/1SF nonlocal-in-time tail-type contribution to the deflection angle via worldline effective field theory techniques. Proceeding as in [2403.04853], we subtract the nonlocal tail terms from the result in [2403.07781] and reconstruct a local-in-time Hamiltonian in isotropic gauge -- valid for generic orbits. For completeness, we reinstate the nonlocal terms relevant for elliptic-like motion up to 6PN/1SF in a small-eccentricity expansion. Via the connection between the (source) energy flux in [2210.05541] and tail effects, we also derive the SF-exact logarithmic-dependent part of the full 5PM bound Hamiltonian. Our results provide the most accurate description to date of the dynamics of bound compact objects within the framework of relativistic scattering computations
Self‐Catalyzed Hydrogenated Carbon Nano‐Onions Facilitates Mild Synthesis of Transparent Nano‐Polycrystalline Diamond
No full textTransparent nano-polycrystalline diamond (t-NPD) possesses superior mechanical properties compared to single and traditional polycrystalline diamonds. However, the harsh synthetic conditions significantly limit its synthesis and applications. In this study, a synthesis routine is presented for t-NPD under low pressure and low temperature conditions, 10 GPa, 1600 °C and 15 GPa, 1350 °C similar with the synthesis condition of organic precursor. Self-catalyzed hydrogenated carbon nano-onions (HCNOs) from the combustion of naphthalene enable synthesis under nearly industrial conditions, which are like organic precursor and much lower than that of graphite and other carbon allotropes. This is made possible thanks to the significant impact of hydrogen on the thermodynamics, as it chemically facilitates phase transition. Ubiquitous nanotwinned structures are observed throughout t-NPD due to the high concentration of puckered layers and stacking faults of HCNOs, which impart a Vickers hardness about 140 GPa. This high hardness and optical transparency can be attributed to the nanocrystalline grain size, thin intergranular films, absence of secondary phase and pore-free features. The facile and industrial-scale synthesis of the HCNOs precursor, and mild synthesis conditions make t-NPD suitable for a wide range of potential applications
Surface States Governing the Activity and Selectivity of Pt-Based Ammonia Slip Catalysts for Selective Ammonia Oxidation
No full textSelective oxidation of ammonia to nitrogen over Pt/AlO was studied in order to determine active Pt species for the activity and selectivity of Pt under conditions close to those of realistic emission control applications. For this purpose, reaction rates and apparent activation energies were measured at different compositions of the reaction feed. Additionally, in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and operando X-ray absorption spectroscopy (XAS) including its interpretation based on theoretical XAS calculations were applied. Three main chemically different states of Pt were detected. The predominance of each of them correlated with the different performance of the catalyst at distinct temperature ranges. At low temperatures (<150 °C), the Pt surface was covered by oxygen species, which poisoned the catalyst. They needed to be removed by heating in the reaction mixture to start with a light off. At 150–300 °C, Pt was covered with NH species, which provided the maximal selectivity to N. At higher temperatures, when full ammonia conversion was reached, the Pt surface again became available for oxidation by the O species, resulting in both surface chemisorbed and subsurface O. This high-temperature state possessed high oxidation activity and high selectivity to undesired NO and NO
Exploring the Potential of Nitride and Carbonitride MAX Phases: Synthesis, Magnetic and Electrical Transport Properties of VGeC, VGeCN, and VGeN
No full textThe chemical composition variety of MAX phases is rapidly evolving in many different directions, especially with the synthesis of carbides that contain two or more metals on the M-site of these layered solids. However, nitride and carbonitride MAX phases are still underrepresented, and only a few members have been reported that are for the most part barely characterized, particularly in terms of magnetic and electronic properties. Here, we demonstrate a simple and effective synthesis route, as well as a comprehensive characterization of three MAX phases, (i) VGeC, (ii) the hitherto unknown carbonitride VGeCN, and (iii) the almost unexplored nitride VGeN. By combining a microwave-assisted precursor synthesis with conventional heat treatment and densification by spark plasma sintering, almost phase-pure (carbo)nitride products are obtained. Magnetic measurements reveal an antiferromagnetic-paramagnetic-like phase transition for all samples in the temperature range of 160–200 K. In addition, increasing the amount of nitrogen on the X-site of the MAX phase structure leads to a constant increase in the magnetic susceptibilities while the electrical resistivity is constantly decreasing. Overall, these findings provide crucial insights into how to tune the electronic and magnetic properties of MAX phases by only varying the chemical composition of the X-site. This further substantiates the demand for (carbo)nitride research with the potential to be extended to the remaining elemental sites within the MAX phase structure to push toward controlled material design and to achieve desired functional properties, such as ferromagnetism
Nitride Synthesis under High-Pressure, High-Temperature Conditions: Unprecedented In Situ Insight into the Reaction
No full textHigh-pressure, high-temperature (HP/HT) syntheses are essential for modern high-performance materials. Phosphorus nitride, nitridophosphate, and more generally nitride syntheses benefit greatly from HP/HT conditions. In this contribution, we present the first systematic in situ investigation of a nitridophosphate HP/HT synthesis using the reaction of zinc nitride ZnN and phosphorus(V) nitride PN to the nitride semiconductor ZnPN as a case study. At a pressure of 8 GPa and temperatures up to 1300 °C, the reaction was monitored by energy-dispersive powder X-ray diffraction (ED-PXRD) in a large-volume press at beamline P61B at DESY. The experiments investigate the general behavior of the starting materials under extreme conditions and give insight into the reaction. During cold compression and subsequent heating, the starting materials remain crystalline above their ambient-pressure decomposition points, until a sufficient minimum temperature is reached and the reaction starts. The reaction proceeds via ion diffusion at grain boundaries with an exponential decay in the reaction rate. Raising the temperature above the minimum required value quickly completes the reaction and initiates single-crystal growth. After cooling and decompression, which did not influence the resulting product, the recovered sample was analyzed by energy-dispersive X-ray (EDX) spectroscopy
CETASim: A numerical tool for beam collective effect study in storage rings
No full textWe developed a 6D multi-particle tracking program CETASim in C++ to simulate intensity-dependent effects in electron storage rings. The program can simulate the beam collective effects due to short-range/long-range wakefields for single/coupled-bunch instability studies. It also features the simulation of interactions among charged ions and the trains of electron bunches, including both fast ion and ion trapping effects. The bunch-by-bunch feedback is also included so that the user can simulate the damping of the unstable motion when its growth rate is faster than the radiation damping rate. The particle dynamics is based on the transfer maps from sector to sector, including the nonlinear effects of amplitude-dependent tune shift, high-order chromaticity, and second-order momentum compaction factor. Users can also introduce a skew quadrupole useful for emittance sharing and exchange studies. This paper describes the code structure, the physics models, and the algorithms used in CETASim. We also present the results of its application to the PETRA-IV storage ring
Ternary Stacking Complexes by Allosteric Regulation in Multilayer Nanographenes
No full textConstruction of π–π stacking supramolecular complexes with more than two different components is challenging due to the weak and directionless nature of dispersion interactions. Here, we report ternary complexes of a ditopic nanographene tetraimide (1), α-substituted phthalocyanine (Pc), and polyaromatic hydrocarbons (PAHs) in solution and the crystalline state via allosteric regulation. Binding of one Pc gives rise to significant distortion and conformational changes in 1 that in turn lead to the inhibition of the second binding of Pc. The conformational changes associated with first binding allowed an allosteric binding of a third component (PAHs) to form ternary complexes in solution. 1H NMR titration revealed moderately high thermodynamic stability for the ternary complexes in CDCl3. Competition between allosterically regulated ternary complexes ([Pc·1·PAH]) and 1:2 stoichiometric binary complexes of 1 with PAHs ([PAH·1·PAH]) was elucidated. Further, the selective formation of ternary complexes in solution led to the generation of ternary cocrystals from a 1:1:1 mixture of three components in solution. Our work shows that large π-conjugated nanographenes designed with allosteric recognition sites allow the construction of multilayer ternary complexes in solution and the solid state even with dispersive π–π interactions