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A novel synthetic nano-catalyst (Ag2O3/Zeolite) for high quality of light naphtha by batch oxidative desulfurization reactor
Get PDFYesOxidative desulfurization process (ODS), enhanced with a novel metal oxide (Ag ions) as an active component over nano-zeolite that has not been reported in the literature, is used here to improve the fuel quality by removing mercaptan (as a model sulfur compound in the light naphtha). Nano-crystalline (nano-support (Nano-zeolite)) composite is prepared by Incipient Wetness Impregnation method loaded with a metal salt to obtain 0.5, 1 and 1.5% of Ag2O3 over Nano-zeolite. The new homemade nano-catalysts (Ag2O3/Nano-zeolite) prepared are characterized by Brunauer-Emmett-Teller (BET) (surface area, pore volume and pore size), X-ray Diffraction (XRD), Fourier Transform Infra Red (FTIR), and Scanning Electron Microscopy (SEM) analysis. The ODS process is then used to evaluate the performance of the catalysts for the removal of sulfur at different reaction temperatures (80-140 °C) and reaction times (30-50 min) in a batch reactor using the air as oxidant. 87.4% of sulfur removal has been achieved using 1% silver oxide loaded on Nano zeolite (1% of Ag2O3/Nano-zeolite) giving a clear indication that our newly designed catalyst is highly efficient catalyst in the removal of sulfur compound (mercaptan) from naphtha. A new mechanism of chemical reaction for sulfur removal by oxygen using the new homemade catalyst (Ag2O3/Nano-zeolite) prepared has been suggested in this study. The best kinetic model parameters of the relevant reactions are also estimated in this study using pseudo first order technique based on the experimental results
Following historical 'tracks' of hair follicle miniaturisation in patterned hair loss: Are elastin bodies the forgotten aetiology?
Get PDFYesPattern Hair Loss (PHL) is a chronic regressive condition of the scalp, where follicular miniaturisation and decreased scalp hair coverage occurs in affected areas. In all PHL cases there is a measurable progressive shortening of the terminal hair growth duration, along with reduced linear growth rates. In both genders, PHL initially shows an increase in short telogen hairs ≤30mm in length, reflecting a cycle completion of under six months in affected terminal hair follicles. To understand the miniaturisation process, we re-examine the dynamics of miniaturisation and ask the question, 'why do miniaturised hair follicles resist treatment?' In the light of recent developments in relation to hair regeneration, we looked back in the older literature for helpful clues 'lost to time' and reprise a 1978 Hermann Pinkus observation of an array of elastin deposits beneath the dermal papilla following subsequent anagen/telogen transitions in male balding, originally described by Arao and Perkins who concluded that these changes provide a "morphologic marker of the entire biologic process in the balding scalp". Thus, we have reviewed the role of the elastin-like bodies in hair pathology and we propose that alterations in elastin architecture may contribute to the failure of vellus-like hair reverting back to their terminal status and may indicate a new area for therapeutic intervention
Energy-harvesting concrete for smart and sustainable infrastructures
Get PDFYesConcrete with smart and functional properties (e.g., self-sensing, self-healing, and energy-harvesting) represents a transformative direction in the field of construction materials. Energy-harvesting concrete has the capability to store or convert the ambient energy (e.g., light, thermal, and mechanical energy) for feasible uses, alleviating global energy and pollution problems as well as reducing carbon footprint. The employment of energy-harvesting concrete can endow infrastructures (e.g., buildings, railways, and highways) with energy self-sufficiency, effectively promoting sustainable infrastructure development. This paper provides a systematic overview on the principles, fabrication, properties, and applications of energy-harvesting concrete (including light-emitting, thermal-storing, thermoelectric, pyroelectric, and piezoelectric concretes). The paper concludes with an outline of some future challenges and opportunities in the application of energy-harvesting concrete in sustainable infrastructures
On the Intellectual Structure and Influence of Tourism Social Science Research
No full textYesThe full-text of this article will be released for public view at the end of the publisher embargo, 24 months after first publication
Corruption and SME growth: the roles of institutional networking and financial slack
Get PDFYesIn this study, we investigate the mediating effect of institutional networking on the relationship between perceived corruption and the growth of small and medium-sized enterprises (SMEs). We also examine the moderating impact of financial slack on the relationship between perceived corruption and institutional networking. We test our moderated mediation model using data from 212 SMEs operating in Ghana. The findings from the study show that perceived corruption is positively related to institutional networking and this relationship is amplified when levels of financial slack are greater. The findings also show that institutional networking positively mediates the relationship between perceived corruption and SME growth. Theoretical and practical implications are discussed
Organic residue analysis of Early Neolithic 'bog pots' from Denmark demonstrates the processing of wild and domestic foodstuffs
Get PDFYesCeramic containers, intentionally deposited into wetlands, offer detailed insights into Early Neolithic culinary practices. Additionally, they are key for ascertaining the Neolithisation process in Denmark since they appear to form a typo-chronological sequence. Here, we use a combination of organic residue analysis (ORA) of pottery alongside Bayesian chronological modelling of the radiocarbon dates obtained on these vessels to explore the initial stages of votive deposition in wetlands, a practice that stretches from the Mesolithic to the onset of Christianity in Northern Europe. We consider 34 Early-Middle Neolithic (c. 3900–2350 cal BC) ‘bog pots’ from Denmark, of which 20 have ORA data, and 26 have been dated directly. Carbonised surface residues and absorbed lipids from powdered sherds were analysed using a combination of bulk carbon and nitrogen stable isotope analysis, gas chromatography-mass spectrometry (GC–MS) and GC-combustion-isotope ratio MS (GC-C-IRMS). The molecular and isotopic compositions of the analysed samples revealed the presence of aquatic, ruminant carcass and dairy fats as well as plant waxes with the majority containing mixtures thereof. Dairy fats were present from the onset of the Funnel Beaker culture, whilst aquatic foods, prevalent at the close of the preceding Mesolithic period, continued to be processed in pottery for the following thousand years.UK Arts and Humanities Research Board Grant B/RG/AN1717/APN14658 (to O.E.C.) and the UK Arts and Humanities Research Council Grant AH/E008232/1 (to C.P.H and O.E.C.) for funding this research. H.K.R. acknowledges the British Academy for funding during the preparation of the manuscript
Flood Suspended Sediment Transport: Combined Modelling from Dilute to Hyper-concentrated Flow
Get PDFYesDuring flooding, the suspended sediment transport usually experiences a wide-range of dilute to hyper-concentrated suspended sediment transport depending on the local flow and ground con-ditions. This paper assesses the distribution of sediment for a variety of hyper-concentrated and dilute flows. Due to the differences between hyper-concentrated and dilute flows, a linear-power coupled model is proposed to integrate these considerations. A parameterised method combining the sediment size, Rouse number, mean concentration, and flow depth parameters has been used for modelling the sediment profile. The accuracy of the proposed model has been verified against the reported laboratory measurements and comparison with other published analytical methods. The proposed method has been shown to effectively compute the concentration profile for a wide range of suspended sediment conditions from hyper-concentrated to dilute flows. Detailed com-parisons reveal that the proposed model calculates the dilute profile with good correspondence to the measured data and other modelling results from literature. For the hyper-concentrated profile, a clear division of lower (bed-load) to upper layer (suspended-load) transport can be observed in the measured data. Using the proposed model, the transitional point from this lower to upper layer transport can be calculated precisely
Energy Savings in CO2 Capture System through Intercooling Mechanism
Get PDFYesIt has been globally recognized as necessary to reduce greenhouse gas (GHG) emissions for mitigating the adverse effects of global warming on earth. Carbon dioxide (CO2) capture and storage (CCS) technologies can play a critical role to achieve these reductions. Current CCS technologies use several different approaches including adsorption, membrane separation, physical and chemical absorption to separate CO2from flue gases. This study aims to evaluate the performance and energy savings of CO2capture system based on chemical absorption by installing an intercooler in the system. Monoethanolamine (MEA) was used as the absorption solvent and Aspen HYSYS (ver. 9) was used to simulate the CO2capturing model. The positioning of the intercooler was studied in 10 different cases and compared with the base case 0 without intercooling. It was found that the installation of the intercooler improved the overall efficiency of CO2recovery in the designed system for all 1-10 cases. Intercooler case 9 was found to be the best case in providing the highest recovery of CO2(92.68%), together with MEA solvent savings of 2.51%. Furthermore, energy savings of 16 GJ/h was estimated from the absorber column alone, that would increase many folds for the entire CO2capture plant. The intercooling system, thus showed improved CO2recovery performance and potential of significant savings in MEA solvent loading and energy requirements, essential for the development of economical and optimized CO2capturing technology
Element failure probability of soil slope under consideration of random groundwater level
Get PDFYesThe instability of soil slopes is directly related to both the shear parameters of the soil material and the groundwater, which usually causes some uncertainty. In this study, a novel method, the element failure probability method (EFP), is proposed to analyse the failure of soil slopes. Based on the upper bound theory, finite element discretization, and the stochastic programming theory, an upper bound stochastic programming model is established by simultaneously considering the randomness of shear parameters and groundwater level to analyse the reliability of slopes. The model is then solved by using the Monte-Carlo method based on the random shear parameters and groundwater levels. Finally, a formula is derived for the element failure probability (EFP) based on the safety factors and velocity fields of the upper bound method. The probability of a slope failure can be calculated by using the safety factor, and the distribution of failure regions in space can be determined by using the location information of the element. The proposed method is validated by using a classic example. This study has theoretical value for further research attempting to advance the application of plastic limit analysis to analyse slope reliability.National Natural Science Foundation of China (grant no. 51564026), the Research Foundation of Kunming University of Science and Technology (grant no. KKSY201904006) and the Key Laboratory of Rock Mechanics and Geohazards of Zhejiang Province (grant no. ZJRM-2018-Z-02)
Regional financial disparity in India: can it be measured?
Get PDFYesIn this study we examine disparities in financial development at the regional level in India. The major research questions of the study are: How do we measure the level of financial development at the sub-national level? How unequal is financial development across the states? Does it vary by ownership of financial institutions? To explore these research questions, our study develops composite banking development index at the sub-national level for three different bank groups - public, private and foreign for 25 Indian states covering 1996 - 2015. Our findings suggest that despite reforms, banking development is significantly higher in the leading high income and more developed regions compared to lagging ones. Further, we find that all bank groups including public banks are concentrated more in the developed regions. Overall, over the years the position of top three and bottom three states in the aggregate banking index has remained unchanged reflecting lop-sidedness of regional development. We also note improvement in the ranking of some north-eastern states during the period 2009-15