10 research outputs found

    Widespread CO2-rich cordierite in the UHT Bakhuis granulite belt, Surinam

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    The Bakhuis Granulite Belt, approx. 30 x 100 km, transects the large Paleoproterozoic greenstone belt along the north-eastern coast of South America. Part of the Granulite belt witnessed typical Ultrahigh-Temperature Metamorphism (UHTM). A metapelite area in the NE of the belt shows assemblages characteristic of UHTM: aluminous (up to 10 wt.%) orthopyroxene + sillimanite +/- sapphirine. Leucosomes commonly show mesoperthite or K-rich antiperthite. Ternary feldspar thermometry indicates a peak temperature of 1000-1050°C and pressure is estimated to have been around 9 kbar. Metapelites elsewhere in the belt lack mineral assemblages characteristic of UHTM. However, feldspar thermometry for these metapelites as well as for mesoperthite granulites indicates that peak temperatures were 900°C or higher throughout the belt and locally reached 1000-1050°C. It is, therefore, concluded that the other parts of the belt also witnessed UHTM, despite their lack of typical UHTM assemblages. Study of peak assemblages in metapelites in these parts is hampered by varying, but usually considerable retrograde metamorphism. The main mafic mineral in metapelites is coarse Mg-rich cordierite, accompanied by coarse sillimanite. Widespread occurrence of cordierite + sillimanite in metapelites is unusual for UHTM, the more so as UHTM assemblages are commonly formed at the expense of cordierite-bearing assemblages. In a small part of the metapelites cordierite is accompanied by coarse aluminous (up to 9 wt.%) orthopyroxene. Associated cordierite and orthopyroxene appear to have formed in equilibrium with each other. Only the presence of aluminous orthopyroxene (as well as the presence of mesoperthite) is typical for UHTM, but is limited to a small part of the metapelites. Peak P-T conditions for the cordierite-bearing part of the belt are estimated to have been similar to those in the NE area with its characteristic UHTM assemblages. Primary and secondary fluid inclusions in UHT quartz blebs in orthopyroxene consist of pure CO2 and have a high density. Raman spectroscopy indicated a considerable CO2 content in cordierite. Estimated from their birefringence, the CO2 content of most cordierites is in the range of 1-2 wt.% CO2. This corresponds to a substantial filling of the cordierite channels with CO2 and for the higher levels possibly near-saturation with CO2 according to the model of Harley and Thompson for the maximum level of CO2 in cordierite. Thermodynamic data for CO2-rich cordierite are poorly known. However, a high level of CO2 in cordierite has been considered to lead to a substantial expansion of its stability field, also into the field of UHTM, at T > 900°C. This is, therefore, assumed to be the explanation for the unusual, widespread occurrence of cordierite in the UHTM belt. A small part of the metapelite samples shows cordierite of a high birefringence, twice that of quartz. SIMS analysis of such cordierite showed 3.0 wt.% CO2, the highest level known from nature. The level is far too high to have formed at UHTM conditions according to the model of Harley and Thompson and would be possible only at conditions such as 700°C and 10 kbar. It is assumed that locally the CO2 level of cordierite changed after UHTM, by taking up additional CO2. Secondary fluid CO2 inclusions in UHT quartz have a higher density than the primary inclusions, indicating a near-isobaric cooling path down to 700-750°C. In these conditions cordierite probably could steadily re-equilibrate at decreasing temperature while taking up more and more CO2, up to 3 wt.% around 700°C. The heat source for the UHTM in the Bakhuis Granulite belt is considered to be asthenospheric upwelling or mafic underplating, but mafic magmatism of identical age to the UHTM has not yet been found. One mafic intrusion was found to be around 20 Ma older than the UHTM, whereas in the SW of the belt numerous mafic intrusions formed around 70 Ma after UHTM

    Charnockites and UHT metamorphism in the Bakhuis Granulite Belt, western Suriname: Evidence for two separate UHT events

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    The Bakhuis Granulite Belt in western Suriname is an ultrahigh-temperature (UHT) metamorphic terrain in the centre of the Paleoproterozoic (Transamazonian) Guiana Shield. Next to the UHT granulites, the belt contains a 30 by 30km body of orthopyroxene-bearing granitoids: the Kabalebo charnockites. This setting offers an excellent opportunity to investigate the source and origin of charnockite magmatism and the common association of charnockites with (ultra)high-temperature metamorphic terrains. We present a detailed geochemical dataset and LA-ICPMS zircon U/Pb ages with the aim to investigate the geochemical and geochronological relationship between charnockite magmatism and UHT metamorphism in the Bakhuis Granulite Belt. The Kabalebo charnockites have a characteristic trace element signature with elevated K2O, P2O5, Zr, REE and Ba coupled with mobile element depletion, which is a consequence of high-temperature melting of anhydrous but fertile granulitic crust. Field and geochemical evidence suggests that the intermediate granulites in the Bakhuis Granulite Belt are the source of the Kabalebo charnockites. The new U/Pb zircon ages indicate that charnockite magmatism (1993-1984Ma) postdates UHT metamorphism (2.07-2.05Ga) by at least 60Myr. We argue that it is not possible to maintain a thermal anomaly >200°C in excess of a normal geothermal gradient for such a prolonged period and hence conclude that the Bakhuis Granulite Belt has experienced two distinct periods in which temperatures >950°C were reached in the lower crust.The presence of comagmatic metadolerite enclaves in the charnockites establishes that mafic magmatism occurred contemporaneously with, and was the likely heat source for, charnockite magmatism at 1.99-1.98. Ga. In contrast, the 2.07-2.05. Ga UHT metamorphic event is not associated with felsic or mafic magmatism in the Bakhuis Granulite Belt or nearby Guiana Shield and postdates the suturing of the juvenile North Guiana TTG-greenstone belt with the West African Shield by at least 10. Myr. We postulate that the UHT metamorphism at 2.07-2.05. Ga is the result of mantle upwelling in a slab tear in the subducted West African slab that formed as the result of crustal scale shearing and boudinage. Prior to the final stabilisation of the Amazonian-West African Shield at 1.90. Ga, northward subduction at 1.99-1.98. Ga caused the emplacement of voluminous hot, mafic magma, resulting in partial melting of the Bakhuis granulite suite to form the Kabalebo charnockites. Charnockite magmatism was roughly contemporaneous with the emplacement of a large belt of shallow granites and felsic volcanic rocks in the SW Guiana Shield. Despite their similar age, the inherited zircon populations suggest that the charnockites are derived from a distinct, juvenile source while the felsic volcanic rocks include an Archaean protolith

    Mafic magmatism in the Bakhuis Granulite Belt (western Suriname) : relationship with charnockite magmatism and UHT metamorphism

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    The Bakhuis Granulite Belt (BGB) is a metamorphic terrain within the Guiana Shield that experienced ultrahigh-temperature (UHT) metamorphism at 2.07–2.05Ga. In the southwest of the BGB, the Kabalebo charnockites were emplaced at ca. 1.99Ga and thus postdate UHT metamorphism by at least 60Myr. Two generations of gabbroic intrusions have been recognized within the BGB, which could act as a heat source for the two UHT events. A younger generation of tholeiitic “Charlie” gabbros yields a baddeleyite U/Pb age of 1971±15Ma. The presence of a metamorphic overprint indicates that the hornblende-bearing “Moi–Moi” metagabbros predate the Charlie gabbros. Large zircons with complex zoning patterns are found in a Moi–Moi metagabbro sample. The main growth domains of these zircons give an age of 1984±4Ma, which is indistinguishable from the surrounding charnockites. Matching trace element and Hf isotope characteristics indicate that the complex zircons are derived from the charnockites. We argue that the emplacement of the metagabbros and charnockite magmatism were contemporaneous and that zircon grains from the charnockitic melt were mechanically transferred to the gabbroic bodies during magma mingling. The new ages for the gabbroic bodies in the BGB confirm that they are contemporaneous with, and the likely heat source for, charnockite magmatism, but that they are not associated with the 2.07–2.05Ga UHT event. Furthermore, the new ages and recognition of the Moi–Moi metagabbros as an Alaskan-type complex provide the first direct evidence for late Transamazonian subduction zone magmatism in the Guiana Shield
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