12,130 research outputs found

    « Des Je perdants au Je réussi. Les intermittences de l’esprit dans l’œuvre de Philippe Vilain »

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    L’évolution du parcours scriptural de Philippe Vilain ainsi que sa constante réflexion critique sur l’écriture de soi et le rapport que celle-ci entretient avec l’autofiction, fait émerger une exigence toujours plus importante de trouver une modalité narrative qui permette au premier « je » sténographié de ses manuscrits de s’ouvrir à un dialogue complexe entre ces différentes instances de la subjectivité qui sont le « je », « le moi » et le « soi ». Elle devient particulièrement féconde et riche en stimuli d’analyse dans le roman Pas son genre où il expérimente une nouvelle frontière possible de l’autofiction, étape importante d’un projet narratif complexe qui ouvre la voie à des nouvelles dimensions narratives explorées dans La femme infidèle. Par des voies toujours interrogeantes, l’œuvre de Vilain se déploie visant la recherche constante d’une unité substantielle, originaire, par ses récurrences et sa dimension obsessionnelle. Chaque roman fonctionne comme un épisode, une « intermittence », une variation d’un seul roman in fieri, qui raconte le parcours d’une intériorité culturalisée exemplaire de l’époque contemporaine. En choisissant comme thème central et obsessionnel la relation amoureuse, Vilain met son « je » à l’épreuve d’un sacrifice d’ égoïté qui comporterait un retour à une innocence et à une confiance originaires. Désirée, recherchée, souhaitée par le « je », la pulsion fusionnelle de l’amour est constamment interrogée par Vilain ainsi que l’illusion qu’elle comporte et le sentiment d’échec qui l’accompagne et qui se révèle, en dépit des apparences et des préjugés, une grande ressource narrative et humaine, la seule qui permette à l’aventure du « je » - de l’homme - de continuer à se réinventer dans son existence

    Ryhiner-Kartensammlung / 20 Accurata Moreæ olim Peloponesvs dictæ tabula

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    studio [Christo]ph: Weigelii ; M. K[auffer] sc."[Cum pr]ivilegio c. maj."Titelkartusche unten links, Massstabsleisten unten Mitt

    An intracellular pH gradient in the anammox bacterium Kuenenia stuttgartiensis as evaluated by (31)P NMR

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    The cytoplasm of anaerobic ammonium oxidizing (anammox) bacteria consists of three compartments separated by membranes. It has been suggested that a proton motive force may be generated over the membrane of the innermost compartment, the “anammoxosome”. 31P nuclear magnetic resonance (NMR) spectroscopy was employed to investigate intracellular pH differences in the anammox bacterium Kuenenia stuttgartiensis. With in vivo NMR, spectra were recorded of active, highly concentrated suspensions of K. stuttgartiensis in a wide-bore NMR tube. At different external pH values, two stable and distinct phosphate peaks were apparent in the recorded spectra. These peaks were equivalent with pH values of 7.3 and 6.3 and suggested the presence of a proton motive force over an intracytoplasmic membrane in K.stuttgartiensis. This study provides for the second time—after discovery of acidocalcisome-like compartments in Agrobacterium tumefaciens—evidence for an intracytoplasmic pH gradient in a chemotrophic prokaryotic cell.BiotechnologyApplied Science

    Concept and development of an autonomous wearable micro-fluidic platform for real time pH sweat analysis

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    In this work the development of an autonomous, robust and wearable micro-fluidic platform capable of performing on-line analysis of pH in sweat is discussed. Through the means of an optical detection system based on a surface mount light emitting diode (SMD LED) and a light photo sensor as a detector, a wearable system was achieved in which real-time monitoring of sweat pH was performed during 55 minutes of cycling activity. We have shown how through systems engineering, integrating miniaturised electrical components, and by improving the micro-fluidic chip characteristics, the wearability, reliability and performance of the micro-fluidic platform was significantly improved

    Exploring the effect of the pH on the corrosion of multilayer nickel-chromium coatings

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    The impact of the pH on the corrosion of microporous nickel-chromium coatings has been explored at localised scale by Scanning Electrochemical Microscopy and validated by potentiodynamic polarisation measurements. Results not only reveal the correlation between both techniques but also enables to identify the different corrosion rate after increasing the electrolyte aggressiveness varying the pH. However, independently of the pH, a similar corrosion mechanism was determined: the cross-section micrographs (by Field Emission-Scanning Electron Microscope) have revealed an isotropic growth of the actives sites at early-stage corrosion as well as the attack of different nickel layers during the corrosion propagation.Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.Team Yaiza Gonzalez Garci

    Il dibattito italiano su principi e clausole generale e l'ideale della certezza del diritto

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    This essay provides a critical assessment of the current Italian debate on general clauses and principles as set forth in a recent book edited by Giovanni D’Amico. The Author focuses on the role that legal certainty has played so far in this discussion and suggests that its impact on real life decisions and the functioning of the legal system has been greatly undervalued. The essay’s central argument attempts to demonstrate that, in the interpretation of general clauses and their translation into specific rules, the objective of legal certainty should be pursued and can ultimately be achieved

    Dynamics of Network Formation Processes in the Co-Author Model

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    This article studies the dynamics in the formation processes of a mutual consent network in game theory setting: the Co-Author Model. In this article, a limited observation is applied and analytical results are derived. Then, 2 parameters are varied: the number of individuals in the network and the initial probability of the links in the network in its initial state. A simulation result shows a finding that is consistent with an analytical result for a state of equilibrium while it also shows different possible equilibria.Dynamics, Network, Game Theory, Model,Simulation, Equilibrium, Complexity

    Quinolinium-Based Fluorescent Probes for Dynamic pH Monitoring in Aqueous Media at High pH Using Fluorescence Lifetime Imaging

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    Spatiotemporal pH imaging using fluorescence lifetime imaging microscopy (FLIM) is an excellent technique for investigating dynamic (electro)chemical processes. However, probes that are responsive at high pH values are not available. Here, we describe the development and application of dedicated pH probes based on the 1-methyl-7-amino-quinolinium fluorophore. The high fluorescence lifetime and quantum yield, the high (photo)stability, and the inherent water solubility make the quinolinium fluorophore well suited for the development of FLIM probes. Due to the flexible fluorophore-spacer-receptor architecture, probe lifetimes are tunable in the pH range between 5.5 and 11. An additional fluorescence lifetime response, at tunable pH values between 11 and 13, is achieved by deprotonation of the aromatic amine at the quinolinium core. Probe lifetimes are hardly affected by temperature and the presence of most inorganic ions, thus making FLIM imaging highly reliable and convenient. At 0.1 mM probe concentrations, imaging at rates of 3 images per second, at a resolution of 4 μm, while measuring pH values up to 12 is achieved. This enables the pH imaging of dynamic electrochemical processes involving chemical reactions and mass transport.ChemE/Transport PhenomenaChemE/Opto-electronic MaterialsChemE/Advanced Soft Matte

    Soil carbon and nutrient stocks under Scots pine plantations in comparison to European beech forests: a paired-plot study across forests with different management history and precipitation regimes

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    Abstract Background Organic carbon stored in forest soils (SOC) represents an important element of the global C cycle. It is thought that the C storage capacity of the stable pool can be enhanced by increasing forest productivity, but empirical evidence in support of this assumption from forests differing in tree species and productivity, while stocking on similar substrate, is scarce. Methods We determined the stocks of SOC and macro-nutrients (nitrogen, phosphorus, calcium, potassium and magnesium) in nine paired European beech/Scots pine stands on similar Pleistocene sandy substrates across a precipitation gradient (560–820 mm∙yr− 1) in northern Germany and explored the influence of tree species, forest history, climate, and soil pH on SOC and nutrient pools. Results While the organic layer stored on average about 80% more C under pine than beech, the pools of SOC and total N in the total profile (organic layer plus mineral soil measured to 60 cm and extrapolated to 100 cm) were greater under pine by about 40% and 20%, respectively. This contrasts with a higher annual production of foliar litter and a much higher fine root biomass in beech stands, indicating that soil C sequestration is unrelated to the production of leaf litter and fine roots in these stands on Pleistocene sandy soils. The pools of available P and basic cations tended to be higher under beech. Neither precipitation nor temperature influenced the SOC pool, whereas tree species was a key driver. An extended data set (which included additional pine stands established more recently on former agricultural soil) revealed that, besides tree species identity, forest continuity is an important factor determining the SOC and nutrient pools of these stands. Conclusion We conclude that tree species identity can exert a considerable influence on the stocks of SOC and macronutrients, which may be unrelated to productivity but closely linked to species-specific forest management histories, thus masking weaker climate and soil chemistry effects on pool sizes
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