239,964 research outputs found

    ljt-uiuc/H-k-c: H-k-c

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    H-k-c package: Generalized H-k after harmonic correction on receiver functions a modification of H-k method by Zhu and Kanamori (2000) by Jiangtao Li, Xiaodong Song, Pan Wang, and Lupei Zhu Reference: Li, J., Song, X., Wang, P., & Zhu, L. (2019). A generalized H-k method with harmonic corrections on Ps and its crustal multiples in receiver functions. J. Geophys. Res. Solid Earth, 124(4), 3782-3801 Contact: [email protected]; [email protected]

    Air-Stable Manganese(I)-Catalyzed C−H Activation for Decarboxylative C−H/C−O Cleavages in Water

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    The decarboxylative C-H/C-O functionalization was accomplished by air-and water-tolerant manganese(I) catalysis. The versatile C-H allylation occurred by facile organometallic C-H metalation on indoles, arenes, amino acids and synthetically meaningful aryl ketimines with ample substrate scope and high levels of chemo-, site- and regioselectivity

    Domino C–H/N–H Allylations of Imidates by Cobalt Catalysis

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    The domino C-H/N-H allylation of aryl imidates was accomplished by a versatile cobalt(III) catalyst. In contrast to a tandem rhodium/palladium catalysis approach, an operationally simple cationic cobalt complex proved effective in the step-economical C-H/N-H functionalization of imidates to directly provide expedient access to decorated vinyl isoquinolines by kinetically relevant C-H activation

    Wang Shuo and the commercialisation of contemporary Chinese culture

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    This thesis examines the commercialisation of Chinese culture that has taken place over the past twenty years in mainland China. It explores the contribution of Wang Shuo, a cultural figure who straddles different fields of culture, moving from literature to the ultimate mass culture medium of television, this study plots Wang Shuo' s development from educational failure, to business failure, to fiction writer, film & TV editor, film director and cultural critic and analyst. His stories, films, TV series and articles have caused shock-waves throughout national cultural circles as he has transformed the terms of the debate from academic discourse to a validation of the role of the market in the culture field. Although Wang Shuo has not been labelled as a dissident, his approach to the culture market has had a more subversive effect on official ideology that those overt dissidents who have had to live in exile or have been imprisoned. He has utilised the language of official ideology to satirise the authorities, turning the ideology and its supporters into figures of fun. Yet his own goals have been strictly personal and economic ones. The authorities recognize the value of Wang Shuo's work in the cultural market but at the same time distrust his works and place him under strict censorship. Examining the way Wang Shuo and people surround him have succeeded in different fields of cultural achievement is a mirror to understanding the process of the transformation of contemporary Chinese culture from a socialist state-controlled culture to a market-oriented mass culture industry

    Wang Meng and contemporary Chinese literature: the vicissitudes of a committed writer

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    This thesis examines the way Wang Meng has developed as a writer from the 1950s to the 1990s in the context of New China's political and literary background. It looks at the compromises he was forced to make between his political beliefs in the Communist Party and his chosen role as a professional writer. After his disastrous early foray into what was deemed to be unacceptable political criticism with The Young Newcomer in the Organisation Department in the 1950s, when the opportunity came to start publishing again in the late 1970s he was boldly innovative in style, helping to transform New Period literature, but conservative in content, sticking to politically acceptable topics. It was only with Hard Porridge in 1989 that he ventured again, and very successfully, into political comment. There is no outstanding leading writer in contemporary China, but Wang Meng is a leading contender for the title

    Overcoming the Limitations of C−H Activation with Strongly Coordinating N‐Heterocycles by Cobalt Catalysis

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    Strongly coordinating nitrogen heterocycles, including pyrimidines, oxazolines, pyrazoles, and pyridines, were fully tolerated in cobalt-catalyzed C-H amidations by imidate assistance. Structurally complex quinazolines are thus accessible in a step-economic manner. Our findings also establish the relative powers of directing groups in cobalt(III)-catalyzed C-H functionalization for the first time

    Improved measurement of the branching fraction of h c → γη′/η and search for h c → γπ 0

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    Abstract The processes h c → γP (P = η′, η, π 0) are studied with a sample of (27.12 ± 0.14) × 108 ψ(3686) events collected by the BESIII detector at the BEPCII collider. The decay h c → γη is observed for the first time with the significance of 9.0 σ, and the branching fraction is determined to be (3.77 ± 0.55 ± 0.13 ± 0.26) × 10 −4, while B B \mathcal{B} (h c → γη′) is measured to be (1.40 ± 0.11 ± 0.04 ± 0.10) × 10 −3, where the first uncertainties are statistical, the second systematic, and the third from the branching fraction of ψ(3686) → π 0 h c . The combination of these results allows for a precise determination of R h c = B h c → γη B h c → γ η ′ , Rhc=B(hcπ0γη)B(hcπ0γη), {R}_{h_c}=\frac{\mathcal{B}\left({h}_c\to {\pi}^0\gamma \eta \right)}{\mathcal{B}\left({h}_c\to {\pi}^0\gamma {\eta}^{\prime}\right)}, which is calculated to be (27.0 ± 4.4 ± 1.0)%. The results are valuable for gaining a deeper understanding of η − η′ mixing, and its manifestation within quantum chromodynamics. No significant signal is found for the decay h c → γπ 0, and an upper limit is placed on its branching fraction of B B \mathcal{B} (h c → γπ 0) < 5.0 × 10 −5, at the 90% confidence level

    Cobalt-Catalyzed Oxidase C-H/N-H Alkyne Annulation:Mechanistic Insights and Access to Anticancer Agents

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    Cp*-free cobalt-catalyzed alkyne annulations by C-H/N-H functionalizations were accomplished with molecular O2 as the sole oxidant. The user-friendly oxidase strategy proved viable with various internal and terminal alkynes through kinetically relevant C-H cobaltation, providing among others step-economical access to the anticancer topoisomerase-I inhibitor 21,22-dimethoxyrosettacin. DFT calculations suggest that electronic effects control the regioselectivity of the alkyne insertion step.</p

    Hydrogen sensors based on Pt-AlGaN/GaN back-to-back Schottky diode

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    In this paper, platinum (Pt) with a thickness of 45 nm was sputtered on the surface of AlGaN/GaN heterostructure to form the Schottky contact and the back-to-back Schottky diodes were characterized for H-2 sensing at room temperature. Both the forward and reverse current of the devices increased with exposure to H-2 gas, which was attributed to Schottky barrier height reduction caused by hydrogen absorption in the catalytic metals. A shift of 0.7 V at 297 K was obtained at a fixed forward current of 0.1 mA after switching from N-2 to 40% H-2 in N-2. The sensor's responses under different concentrations from 2500 ppm H-2 to 40% H-2 in N-2 at 297 K were investigated. Time response of the sensor at a fixed bias of 1 V was given. Finally, the decrease of the Schottky barrier height and the sensitivity of the sensor were calculated. (C) 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

    Search for new hadronic decays of h c and observation of h c → p p ¯ η ppη p\overline{p}\eta

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    Abstract A search for the hadronic decays of the h c meson to the final states p p ¯ pp p\overline{p} π + π − π 0, p p ¯ η ppη p\overline{p}\eta , and p p ¯ pp p\overline{p} π 0 via the process ψ(3686) → π 0 h c is performed using (4.48 ± 0.03) × 108 ψ(3686) events collected with the BESIII detector. The decay channel h c → p p ¯ η ppη p\overline{p}\eta is observed for the first time with a significance greater than 5σ and a branching fraction of (6.41 ± 1.74 ± 0.53 ± 1.00) × 10 −4, where the uncertainties are statistical, systematic, and that from the branching fraction of ψ(3686) → π 0 h c . Strong evidence for the decay h c → p p ¯ pp p\overline{p} π + π − π 0 is found with a significance of 4.9σ and a branching fraction of (3.84 ± 0.83 ± 0.69 ± 0.58) × 10 −3. The significances include systematic uncertainties. No clear signal of the decay h c → p p ¯ pp p\overline{p} π 0 is found, and an upper limit of 6.59 × 10 −4 on its branching fraction is set at the 90% confidence level
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