108,543 research outputs found
Corrigendum to “General reduced vehicle model for simulating truck-bridge pier collisions” [Dev. Built. Environ. 16 (2023) 100233] (Developments in the Built Environment (2023) 16, (S2666165923001151), (10.1016/j.dibe.2023.100233))
No full textThe authors regret there were two errors in the authors' affiliation in the published article. First, the affiliation of the first author (Daogang Ou) should only be the School of Civil Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China. Second, the corresponding author (Lin Chen) should have two affiliations; the first one should be: School of Civil Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China; and the second one should be: Key Laboratory of Building Safety and Energy Efficiency of Ministry of Education, Hunan University, Changsha, 410082, China. The authors would like to apologise for any inconvenience caused
INNOVATIVE PILLAR[6]ARENE-BASED STATIONARY PHASES FOR HIGH-RESOLUTION GAS CHROMATOGRAPHIC ANALYSES
No full textIn this work, the synthesis, fabrication, and characterization of new stationary phases based on pillar[6]arene derivative modified by long alkyl chains (P6A-C10) for high-resolution gas chromatographic (GC) analyses are reported. Pillar[n]arenes are a new class of macrocyclic hosts that can accommodate specific guests due to their highly symmetrical and rigid pillar architectures with π-electron rich cavities. Quantum chemistry calculations have been performed, showing a difference in non-covalent interactions with the P6A-C10 pillar framework, which leads to specific selectivity for aromatic compounds. The GC columns prepared with these innovative stationary phases exhibited a medium polarity, and good reproducibility for run-to-run, day-to-day, and column-to-column analyses [1], demonstrating great potential as new stationary phases in separation science. Furthermore, peculiar advantages are achieved if compared with the commercial HP-5, HP-35, DB-17, and PEG-20M columns, showing unmatched resolving capabilities toward chloroaniline, bromoaniline, iodoaniline, toluidine, and xylene isomers [2].
References:
1. Sun, T., Chen, R., Huang, Q., Ba, M., Cai, Z., Hu, S., Liu, X., Nardiello, D., & Quinto, M., ACS Appl. Mater. Interfaces 14 (2022) 56132−56142.
2. Sun, T., Chen, R., Huang, Q., Ba, M., Cai, Z., Chen, H., Qi, Y., Chen, H., Liu, X., Nardiello, D., & Quinto, M., Anal. Chim. Acta 1251 (2023) 340979
ISOMER SEPARATIONS BY INNOVATIVE GAS CHROMATOGRAPHY STATIONARY PHASES
No full textThe chromatographic separation of aromatic amines and xylenes isomers represents a big issue in chemical and petroleum industries, owing to their high similarity in terms of molecular sizes, polarity, and boiling points: as a result, commercial columns very often do not allow their complete peak separation. For this reason, several typologies of materials with different structures and properties have been developed and proposed as gas chromatography stationary phases in recent years. Macrocycles and ionic liquid-based chain-typed copolymers have emerged, due to their special chromatographic selectivity and separation mechanisms, resulting from their three-dimensional structures and outstanding thermal stability. Very recently, innovative stationary phases based on functionalized calixarene-polyethylene glycol (C4A-mPEG) [1], and amphiphilic triblock copolymer bonded with benzimidazolium ionic liquid (TCP-Bim) [2] were designed, characterized, and used for GC separations of aromatic isomers. The separation features of the C4A-mPEG stationary phase, resulting from multiple molecular recognition processes with analytes, including π-π, H-bonding, dipole-dipole, and van der Waals interactions, allowed to obtain high-resolution performances for a wide range of compounds and their isomers, especially benzaldehydes, phenols, and anilines. Moreover, compared with 4-tertbutyl calix[4]arene (C4A) and polyethylene glycol (PEG) stationary phases, a higher resolving capability was also observed for the separation of toluidine and xylidine isomers. The separation capabilities of the TCP-Bim columns are attributable to different analyte-stationary phase interaction mechanisms, arising from the particular TCP-Bim structure that combines ionic liquid and copolymer peculiarities, showing stronger retention towards aromatic compounds. The high-resolution capabilities of the TCP-Bim column were also tested with different aliphatic cis-/trans-isomers; the excellent separation performances for analytes with very similar properties demonstrated the good potential of these innovative materials as new classes of stationary phases for high-resolution GC separations.
References:
1. Chen, R., Cai, Z., Li, W., Huang, Q., Nardiello, D., Quinto, M., Liu, X., Hu, S., & Sun, T., Chem. Biodiversity 19 (2022) e202200829.
2. Huang, Q., Cai, Z., Chen, R., Zhang, W., Nardiello, D., Quinto, M., Liu, X., Hu, S., & Sun, T., Microchemical Journal 183 (2022) 108084
Ptisana ambulans Murdock & C. W. Chen
No full textPtisana ambulans Murdock & C.W. Chen: Solomon Islands, New Georgia, (629), Voucher: C.-W. Chen & T.-C. Hsu SITW00629 (TAIF, TNM, BSIP), GenBank: MW051627, MW051612.Published as part of Shepherd, Lara D., Murdock, Andrew G., Amice, Rémy & Perrie, Leon R., 2023, A synopsis of Ptisana Murdock ferns (Marattiaceae) in New Caledonia based on sequence data and morphology with the recognition of a new vulnerable species, P. soluta (Compton) Murdock & Perrie, comb. nov., stat. nov., pp. 41-59 in Adansonia (3) (3) 45 (3) on page 57, DOI: 10.5252/adansonia2023v45a3, http://zenodo.org/record/766506
T.-W. Chen
No full textQuality of Service (QoS) support for multimedia applications has been widely discussed in the context of high speed wired networks. As interest increases in wireless ATM networks that extend the connection to a wireless endpoint, the issue of QoS over a wireless link has to be addressed. In this paper, we focus on the provision of QoS at the application level in a wireless environment. Our work includes the design of an application programming interface (API) that allows applications to specify and renegotiate the QoS level during a call; as well as the implementation of such API in a wireless ATM testbed: the SWAN system [1]. Experiments are performed to verify the efficiency of this scheme, and the results reveal quality control for multimedia applications despite changing network conditions. 1 Introduction This work is motivated by the rising popularity of wireless data networking and the desire for mobile, multimedia communications. Wireless technology has recently begun to take ..
Orthogonal least squares methods and their application to non-linear system identification
No full textIdentification algorithms based on the well-known linear least squares methods ofgaussian elimination, Cholesky decomposition, classical Gram-Schmidt, modifiedGram-Schmidt, Householder transformation, Givens method, and singular valuedecomposition are reviewed. The classical Gram-Schmidt, modified Gram-Schmidt,and Householder transformation algorithms are then extended to combinestructure determination, or which terms to include in the model, and parameterestimation in a very simple and efficient manner for a class of multivariablediscrete-time non-linear stochastic systems which are linear in the parameters
Supplemental material for Combination immunosuppressant therapy and lupus nephritis outcome: a hospital-based studyY.M.C. and W.T.H. contributed equally to this work.
No full textSupplemental Material for Combination immunosuppressant therapy and lupus nephritis outcome: a hospital-based study Y.M.C. and W.T.H. contributed equally to this work. by Y M Chen, W T Hung, Y W Liao, C Y Hsu, T Y Hsieh, H H Chen, C W Hsieh, C T Lin, K L Lai, K T Tang, C W Tseng, W N Huang and Y H Chen in Lupus</p
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