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New perfluorodioxol, its production and homo-polymer and copolymer obtained therefrom
No full textprovide a novel perfluorodioxole which is suitable for producing a homopolymer and a copolymer both having excellent mechanical properties and a good thermal stability.
CONSTITUTION: A perfluorodioxole of formula I (wherein RF is 1-5C perfluoroalkyl; and X1 and X2 are each F or CF3) (e.g. 2,2,4-trifluoro-5- trifluoromethoxy-1,3-dioxole of formula II) is provided, which is obtd. e.g. by reacting a dioxole of formula III with a fluorooxy compd. of the formula: RFOF and reacting the resultant dioxolane of formula IV with a metal in a dipolar aprotic solvent to dehalogenate the dioxolane of formula IV or by reacting a compd. of formula V with a bisflurooxy compd. of formula VI at -140 to -20°C and dehalogenating the resultant dioxolane of formula IV in the same way as above. The perfluorodioxole of formula I may be homopolymerized or copolymerized with an olefinically unsatd. comonomer
“Recent developments in the chemistry of fluoroxy compounds"
No full text10th European Symposium on Fluorine Chemistry, Padova, Italy (1992)
Recent development in the chemistry of fluoroxy compounds J. Fluorine Chem. (1992) 58, 143.
No full text
“Perfluoroalchil-ipofluoriti e il loro recente ruolo nella chimica organica industriale”
No full textXXVI Convegno Nazionale della Divisione di Chimica Organica.Messina (1999)
A new type of a-N-amidoalkylation of heteroaromatic bases. Mechanism of the oxidation of the N-acylaminoethanolsby peroxydisulfate
No full text“New Aspect in the synthesis and reactivity of some fluoromonomers”
No full textInvited speech at the SERMACS ’96: Innovation in the Southeast, Greenville, S.C., USA (1996)
“New route to 2,2-difluoro-1,3-dioxoles”
No full text11th Winter Conference, St.Petersburg, USA (1993)
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