3,776 research outputs found
Development of a microfluidic based analytical system for copper monitoring in environmental water samples
No full textA microfluidic-based system has been developed for copper (II) monitoring in water samples with sensitive and selective detection, based on the measurement of light emitted from the copper (II) catalysed oxidation of 1,10-phenanthroline by hydrogen peroxide. Work initially focussed on the development of a flow injection analysis (FIA) system with micellar enhanced chemiluminescence (CL) detection. Sufficient selectivity was achieved by removing interfering metal ions using an on-line itaconic acid modified microcolumn, allowing copper (II) to be easily determined at concentrations as low as 1 jig L_1 from high concentrations of calcium (II) and magnesium (II).
The FIA-CL system was further developed and scaled-down to create a microfluidicbased system. A number of different microflow devices, of various designs and dimensions, were manufactured from polymethylmethacrylate (PMMA). A range of in-house micro-fabrication techniques were investigated for the fabrication of the microfluidic devices including hot embossing, laser ablation and direct micromilling. A complete miniaturised flow system was developed incorporating miniaturised peristaltic pumps, a microfluidic plastic manifold and a compact photomultiplier tube for CL detection. Experimental conditions including reagent concentrations and flow rates were optimised and the system was found to produce linear results for copper (II) over the concentration range 0 to 150 jxg L‘\.
Selectivity of the microfluidic-based CL system was further enhanced by incorporating an on-line separation step into the microflow manifold. A number of different solid phases were compared and contrasted for the on-line separation of copper (II) from complex sample matrices. These included incorporating a stationary phase e.g. monolithic and chelating resin micro-columns into the plastic microflow device and the use of on-line modified Convective-Interaction Media® (CIM®) disk monolithic columns. Finally the optimised system was successfully used for trace copper (II) determinations in a standard reference freshwater sample (SRM 1640) and in real water samples
The 2D/3D dynamics of wall-bounded low-Rm magnetohydrodynamic (MHD) turbulence
No full textWith this experimental study, we give evidence that the dynamics of low-Rm MHD turbulence depends on the diffusion length l_z, which corresponds to the distance over which the Lorentz force is able to diffuse momentum before it is balanced by inertia
K-feldspar sand-grain provenance in the Triassic, west of Shetland : distinguishing first-cycle and recycled sediment sources?
No full textSandstone provenance studies can help constrain palaeogeographic reconstructions and ancient drainage system scales and pathways. However, these insights can be obscured by difficulties in geochemically distinguishing or adequately characterising potential sourcelands, or by failure to identify sedimentary recycling. Triassic basins west of Shetland accumulated ~2.5 km of sand-rich sediment. The Middle-Upper Triassic Foula Formation represents fluvial, aeolian and sabkha facies deposited in the northern interior of the Pangean supercontinent. Published U-Pb zircon geochronology and heavy mineral analysis suggest that these sandstones were derived from East Greenland. They contain significant fresh K-feldspar which is likely to be first-cycle and derived directly from its source. Pb isotopic analyses of individual K-feldspar sand-grains show a single, unradiogenic Pb population, consistent with the provenance indicated by U-Pb zircon geochronology. Archaean and Palaeo-Mesoproterozoic rocks – the Nagssugtoqidian Mobile Belt, the Lewisian Complex or equivalents - are the likely source, with terranes south of the Moine Thrust (Grampian, Caledonian and Variscan) ruled out by both the Pb and U-Pb data. However, it is not possible to distinguish between rift flank sources to the east and west, as both areas have similar crustal affinity and/or share the same tectonic history. It is possible that the sediment was derived from the West Shetland Platform and not from Greenland. The comparison of provenance signals from robust and less stable mineral phases provides a means of recognising sedimentary recycling. Robust zircon populations and less stable feldspar in Foula Formation sandstones concur in indicating the same source, suggesting that they are likely to be first-cycle. The Triassic sand supply can be contrasted with that in Upper Carboniferous (Namurian) basins in the north of England where a significant zircon population has no corresponding K-feldspar component. This zircon population is likely to have been recycled from Lower Palaeozoic greywackes from the Southern Uplands Belt or its along strike extension.Science Foundation Irelan
Triangular Constellations in Flows
No full textParticles advected on the surface of a fluid can exhibit fractal clustering. The local structure of a fractal set is described by its dimension , which is the exponent of a power-law relating the mass in a ball to its radius : . It is desirable to characterise the {\em shapes} of constellations of points sampling a fractal measure, as well as their masses. The simplest example is the distribution of shapes of triangles formed by triplets of points, which we investigate for fractals generated by chaotic dynamical systems. The most significant parameter describing the triangle shape is the ratio of its area to the radius of gyration squared. We show that the probability density of has a phase transition: is independent of and approximately uniform below a critical flow compressibility , which we estimate. For the distribution appears to be described by two power laws: when , and when
Exact two-dimensionalization of low-magnetic-Reynolds-number flows subject to a strong magnetic field
No full textWe investigate the behavior of flows, including turbulent flows, driven by a horizontal body-force and subject to a vertical magnetic field, with the following question in mind: for very strong applied magnetic field, is the flow mostly two-dimensional, with remaining weak three-dimensional fluctuations, or does it become exactly 2D, with no dependence along the vertical? We restrict attention to low-magnetic-Reynolds number (Rm) flow. Because liquid metals have low magnetic Prandtl number, such low- flows can have a kinetic Reynolds number as large as one million and therefore be strongly turbulent. We first focus on the quasi-static approximation, i.e. the asymptotic limit of vanishing magnetic Reynolds number Rm << 1: we prove that the flow becomes exactly 2D asymptotically in time, regardless of the initial condition and provided the interaction parameter N is larger than a threshold value. We call this property absolute two-dimensionalization: the attractor of the system is necessarily a (possibly turbulent) 2D flow. We then consider the full-magnetohydrodynamic equations and we prove that, for low enough Rm and large enough N, the flow becomes exactly two-dimensional in the long-time limit provided the initial vertically-dependent perturbations are infinitesimal. We call this phenomenon linear two-dimensionalization: the (possibly turbulent) 2D flow is an attractor of the dynamics, but it is not necessarily the only attractor of the system. Some 3D attractors may also exist and be attained for strong enough initial 3D perturbations. These results shed some light on the existence of a dissipative anomaly for magnetohydrodynamic flows subject to a strong external magnetic field
The Decay of Wall Bounded MHD Turbulence at Low RM
No full textWe have developed a new spectral method to simulate flows with very fine boundary layers present. We apply it to calculate the evolution of freely decaying MHD turbulence between isolating walls. By comparison them with results obtained in fully periodic domain we quantify the influence of the channel walls on the character of freely decaying MHD turbulence
A basis of a certain module for the hyperalgebra and some applications
No full textIn the hyperalgebra of the -th Frobenius kernel of the algebraic group , we construct a basis of the
-module generated by a certain element which was given by the
author before. As its applications, we also prove some results on the
-modules and the algebra .Comment: 30 page
Borromini tuscolano
No full textLa pubblicazione propone, in versione ampliata e aggiornata, la chiave di lettura già avanzata dall’autore alcuni anni or sono in relazione all’intervento seicentesco voluto dalla famiglia Falconieri sulla più antica delle Ville Tuscolane, la Rufina, ritenendone valida la consolidata attribuzione al Borromini.
Nel volume viene data un’ampia dimostrazione dell’efficacia dell’interazione “documenti storici-rilievo architettonico”, nella ricostruzione delle fasi evolutive di una fabbrica e di come questo momento d’analisi, ove insufficientemente approfondito, possa indurre a considerazioni erronee.
Infatti, l’ipotesi diffusa in vari contributi sull’argomento riguardo alla forma dell’originario Casino della Rufina – e in particolare alla posizione della loggia verso Roma – è suffragata soltanto da incisioni d’epoca e non è mai stata scientificamente comprovata dal riscontro di un rilievo, né dal confronto attento con la pianta del nucleo originario della fabbrica conservata nelle Carte Strozzi presso l’Archivio di Stato di Firenze, ignorata o considerata – con una certa superficialità – come inattendibile.
L’ipotesi qui sostenuta valuta la “logica” dell’addizione alla Villa Rufina basandosi su considerazioni relative sia ai vari documenti iconografici sia all’attendibilità di ciascuno; il tutto è inoltre riferito al completo rilevamento dell’opera nel suo stato attuale.
Discutendo ipotesi diverse (anche attributive) emerse nel frattempo e sviluppando le considerazioni precedentemente avanzate grazie anche a un nuovo apparato iconografico che vede sfruttate le potenzialità della modellazione 3D applicate ai criteri del rilievo filologico, il lavoro tende a ribadire l’efficacia di tale metodo d’indagine, basato sul rilievo delle attuali condizioni dell’opera in associazione all’imprescindibile analisi storico-documentale.
Attraverso il medesimo impianto scientifico procedurale è inoltre sviluppata la ricostruzione filologica del fronte settentrionale, basata anche su documentazione fotografica d’epoca parzialmente inedita. Si intende così offrire un iniziale – seppur parziale – contributo alla rilettura dell’ultima fase (quella novecentesca) che ha contrassegnato la fabbrica, vedendola già alterata ai primi del XX secolo, quindi compromessa dagli eventi bellici e infine trasformata dalle operazioni di restauro/ripristino del complesso, che hanno riproposto solo parzialmente e in modo generico la precedente morfologia del manufatto.This publication proposes, in an expanded and updated version, the key that the Author had already advanced in an earlier essay which was published ten years ago, concerning the 17th century intervention on the Villa Rufina: the first one of the Ville Tuscolane (summer residences for the papal circle that rose, in the late Renaissance, on the hills at the south of Rome). The Authors assumes also to be valid the well-established attribution of this work to Francesco Borromini.
In this volume a wide demonstration is offered of the efficacy, for the aim of a reliable reconstruction of the evolutionary phases of a certain building, of the interaction between the historical documents and the architectural survey, showing also how this time of analysis can lead to incorrect or misleading considerations, when it is not carried out enough deeply.
In the second phase (the expansion of the 17th century) which characterized all the Ville Tuscolane, the Rufina, at the time owned by the Falconieri (family), was the subject of an extensive renewal. With this intervention the first bulding that had initiated the “modern rediscovery” of building activity in these places (being, in fact, the originator of the Complex) was considerably transformed with regard to its material structure, appearance and relationship with the environment. For the devising of the general plan, it is commonly ascribed to Francesco Borromini, on the basis more of archive documents than of its style.
If the decoration of the Villa has been extensively and reliably studied, the same cannot be said about the transformations that the old building underwent, especially with regard to the lost loggia towards Rome. The hypothesis that has gradually taken root, about the location of this lodge, in the various papers published on the subject, is in fact supported only by some engravings of the time (in which the Villa is depicted in a pseudo-perspectival view and only as an element amongst the many others of the Complex). It has never been scientifically proved by the check of a survey, or by a careful comparison with the plan of the original nucleus of the original factory map stored in the “Carte Strozzi” at the State Archives of Florence, that has been ignored or considered – with some superficiality – as unreliable.
The hypothesis the Author suggested since the previous essay, evaluates the “logic” of the addition Borromini made to the Villa Rufina detaching itself from these assumptions and basing itself on some specific considerations concerning the iconographic documents that have been published over the years in various contributions, evaluating the reliability of each of them. These considerations were also related to a comprehensive survey of the work in its current state, as the so far published surveys are partial or were carried out on the structure as extensively damaged by the war.
In the volume are also discussed several different hypotheses that emerged in the meantime, also on the allocation of the project, as the attribution to Borromini – which in the past had seen ups and downs, from the header of the engraving by Alessandro Specchi to the evidences provided by Paolo Portoghesi and by Angela Negro, taken from the Falconieri-Carpegna archive – has recently been the subject of a new attempt of denial.
Developing the considerations already advanced before, and using a new display of subsidiary iconography that sees the exploitation of the potential of 3d modeling when applied to the criteria of the philological surveying, this study aims at a confirmation of the effectiveness of this method of investigation, which is based on a survey of the work in its positive state in conjunction with an unavoidable historical-documentary analysis.
On the basis of this same scientific procedural system, taking as well in account many historical photographic documents, so far unpublished, is also developed a philological reconstruction of the northern front, that is proposed in the last chapter. The aim is to provide a first – although partial – contribution to the re-reading of the last phase (the 20th century), which marked the building, that had already been altered in the early years of the 20th century, then compromised by the war and finally transformed by the restoration and rehabilitation of the complex, which reconstructed the pre-existing morphology only in a partial and general way
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