25,115 research outputs found

    Monocationic μ-diborolyl triple-decker complexes [CpCo(μ-1,3-C 3B2Me5)M(ring)]+: Synthesis, structures, and electrochemistry

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    Cationic triple-decker complexes with a bridging diborolyl ligand, [CpCo(μ-1,3-C3B2Me5)M(ring)]+ (M(ring) = CoCp (2a), CoCp* (2b), RhCp (3a), RhCp* (3b), IrCp (4a), IrCp* (4b), Ru(C6H6) (5a), Ru(p-MeC 6H4Pri) (5b), Ru(C6Me6) (5c), Ru(η6-cycloheptatriene) (6)), were synthesized by reaction of CpCo(μ-1,3-C3B2Me5)Tl with [M(ring)Hal2]2. The structures of 2aBPh4, 2bPF6, 4aPF6, 5aOTf, and 5cPF6 were determined by X-ray diffraction. The electron-transfer ability of the complexes has been ascertained by electrochemical and spectroelectrochemical techniques. In general, they are able to shuttle reversibly in the sequence 2+/+/0/-, plausibly affording completely delocalized mixed-valence derivatives. DFT calculations revealed structural changes accompanying redox processes and satisfactorily predicted the potentials for the first reduction and first oxidation. © 2013 American Chemical Society

    Wave turbulence of a rotating array of quantized vortices in the T → 0 temperature limit

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    The dynamics of quantized vortices in the zero temperature limit T0T \rightarrow 0 is currently of great interest, particularly in the case of the Fermi superfluid 3^3He-B. Here we study wave turbulence, generated by the librating motion of a rotating cylindrical container filled with 3^3He-B, in the limit of vanishing viscous forces at temperatures T0.2TcT \leq 0.2 T_{c}. The polarization of the quantized vortices with respect to the axis of rotation is measured using non-invasive NMR techniques. We observe a decrease of the polarization when the librating motion is started, and a two-stage relaxation process when the modulation of the rotation velocity is stopped. The first relaxation process is associated with the dissipation of large-scale flow stored in inertial waves and the solid body rotation of the vortex array. From the decay of these energy reservoirs we determine the rate of energy dissipation of large-scale flow. The later second process is related to the relaxation of Kelvin waves on individual vortices. This process is monitored by the recovery of the polarization. The existence of a Kelvin wave cascade at the lowest temperatures is currently a central open question. We supply some evidence for the cascade

    Design and Analysis of a Distributed TRIC concept Seamless Smart Morphing Wing

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    This thesis embarked upon establishing and validating a design process to build and control a distributed TRIC concept seamless smart morphing wing to achieve simultaneous load alleviation, flutter suppression and drag minimization capabilities. A novel aeroelastic simulation tool was built to carry out composite wing skin optimization, with prototype testing carried out to design a flexible connection between modules. The work output was a fully built morphing wing which was successfully tested in the TU Delft Open Jet Facility. Control of the wing was partially made feasible through the development of a surrogate model of the system which was also validated with DIC testing.https://www.youtube.com/watch?v=SdagIiYRWyA&t=1s Smart-X Alpha DemonstratorAerospace Engineerin

    Pelevin’s Trinity in the novel “t”: author – protagonist – reader

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    The article attempts to interpret Pelevin's artistic strategy in the novel "T" by exploring its subject organization and addressing the key problems of the author, the protagonist, and the reader as they are seen by the researcher. The article analyzes the peculiarities of constructing the narrative reality in the novel "T", and goes on to discuss Pelevin's philosophic models of the development of the humankind, and the emergence of his new anthropology

    Fig. 1. Heterocotyle chinensis Timofeeva, 1983 in Heterocotyle chinensis (Monogenea: Monocotylidae) from the Whip Stingray Dasyatis akajei in the Seto Inland Sea, Japan

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    Fig. 1. Heterocotyle chinensis Timofeeva, 1983. NMST-Pl 6164. A, whole mount (ventral view); B, hamulus; C, hooklet; D, male copulatory organ. Scale bars: A, 200 µm; B–D, 10 µm. Abbreviations: alg, anterolateral gland; amg, anteromedian gland; d, duct; dh, dorsal haptoral accessory structure; ej, ejaculatory bulb; ey, eyespots; h, hamulus; ho, hooklet; in, intestine; m, mouth; mag, male accessory gland; mco, male copulatory organ; mg, Mehlis' gland; o, oötype; od, oviduct; ov, ovary; ph, pharynx; pg, posterior gland; phg, pharyngeal glands; r, sinuous ridge; sr, seminal receptacle; sv, seminal vesicle; t, testis; tv, transverse vitelline duct; u, uterus; vi, vitellaria; v, vagina; vp, vaginal pore; vd, vas deferens.Published as part of Nitta, Masato & Nagasawa, Kazuya, 2015, Heterocotyle chinensis (Monogenea: Monocotylidae) from the Whip Stingray Dasyatis akajei in the Seto Inland Sea, Japan, pp. 89-93 in Species Diversity 20 on page 90, DOI: 10.12782/sd.20.1.089, http://zenodo.org/record/573752

    Heterogeneous and tissue-specific regulation of effector T cell responses by IFN-gamma during Plasmodium berghei ANKA infection.

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    IFN-γ and T cells are both required for the development of experimental cerebral malaria during Plasmodium berghei ANKA infection. Surprisingly, however, the role of IFN-γ in shaping the effector CD4(+) and CD8(+) T cell response during this infection has not been examined in detail. To address this, we have compared the effector T cell responses in wild-type and IFN-γ(-/-) mice during P. berghei ANKA infection. The expansion of splenic CD4(+) and CD8(+) T cells during P. berghei ANKA infection was unaffected by the absence of IFN-γ, but the contraction phase of the T cell response was significantly attenuated. Splenic T cell activation and effector function were essentially normal in IFN-γ(-/-) mice; however, the migration to, and accumulation of, effector CD4(+) and CD8(+) T cells in the lung, liver, and brain was altered in IFN-γ(-/-) mice. Interestingly, activation and accumulation of T cells in various nonlymphoid organs was differently affected by lack of IFN-γ, suggesting that IFN-γ influences T cell effector function to varying levels in different anatomical locations. Importantly, control of splenic T cell numbers during P. berghei ANKA infection depended on active IFN-γ-dependent environmental signals--leading to T cell apoptosis--rather than upon intrinsic alterations in T cell programming. To our knowledge, this is the first study to fully investigate the role of IFN-γ in modulating T cell function during P. berghei ANKA infection and reveals that IFN-γ is required for efficient contraction of the pool of activated T cells

    Measuring industry-science links through inventor-author relations: A profiling method

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    In this pilot study we examine the performance of text-based profiling in recovering a set of validated inventor-author links. In a first step we match patents and publications solely based on their similarity in content. Next, we compare inventor and author names on the highest ranked matches for the occurrence of name matches. Finally, we compare these candidate matches with the names listed in a validated set of inventor-author names. Our text-based profile methodology performs significantly better than a random matching of patents and publications, suggesting that text-based profiling is a valuable complementary tool to the name searches used in previous studies.innovation; industry-science links; text-based profiling;

    Valuation of J&T BANK, a.s.

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    The diploma thesis deals with the valuation of J&T BANKA, a.s. The aim of the thesis is to estimate its market price. The thesis is divided into two parts - theoretical and practical. In the theoretical part, the author describes the banking sector, its regulation and risks affecting banks. The practical part is devoted to financial and strategic analysis, preparation of a financial plan and the actual valuation based on two income methods.Diplomová práce se zabývá oceněním J&T BANKY, a.s. Cílem práce je odhadnout její tržní cenu. Práce je rozdělena do dvou částí – teoretická a praktická. V rámci teoretické části autor popisuje bankovní sektor, jeho regulaci a rizika působící na banky. Praktická část se věnuje finanční a strategické analýze, sestavení finančního plánu a samotnému ocenění na základě dvou výnosových metod

    Trip account

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    Trip account - AMs, 15 pp. “I am attempting to give you some account of a recent vacation trip which we were privileged to enjoy - Rose, Mother and I…” As the account of the trip to view the eclipse is unsigned, we can’t say for sure but as the author states “Rose, Mother and I” one could logically assume that the author is a sibling of T. Rose Curtis

    Retail marketing in T-Mobile during the time of digitalization

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    Diplomová práce se zabývá retail marketingem ve společnosti T-Mobile. V teoretické části autorka nejprve věnovala pozornost retail marketingu jakožto součásti marketingu. Následně jsou vysvětleny pojmy jako je marketingový mix, SWOT analýza, zákaznická cesta, marketingové a komerční komunikace s důrazem na nové technologie a digitální média využívaná v místech prodeje. V praktické části je úvodní kapitola věnována představení společnosti T-Mobile Česká republika (TMCZ) a následující kapitoly se zabývají aplikací retail marketingu v prodejnách TMCZ. Na základě získaných teoretických poznatků je na zkoumanou společnost aplikována SWOT analýza a analýza marketingového mixu. Dále jsou provedeny dva výzkumy, jeden kvantitativní, formou dotazníkového šetření a druhý kvalitativní, pomocí oční kamery. Cílem této diplomové práce je zjistit, jaký mají vliv digitální média využívaná v prodejnách TMCZ na konečné spotřebitele a ověřit optimální rozmístění hlavních komunikačních "touch pointů" na prodejnách. Z vlastního šetření autorky plynou nová doporučení pro oblast retail marketingových aktivit ve společnosti T-Mobile, a to především v oblasti použití digitálních versus tištěných médií na prodejnách a zoptimalizování zákaznické cesty.The diploma thesis deals with a topic of retail marketing which is practically applied to a T-Mobile company. Firstly, in the theoretical part, retail marketing is defined as a part of marketing. Further on, the concepts such as marketing mix, SWOT analysis, customer journey, marketing and commercial communications, new technologies and digital media are explained. In the practical part, the introductory chapter deals with a subscription of the T-Mobile Czech Republic (TMCZ) company. In the subsequent chapters are analyzed retail marketing activities applied in TMCZ stores with a focus on the new technologies used in in-store marketing. On the basis of the acquired theoretical knowledge SWOT analysis and marketing mix analysis are performed. Further on, research is carried out by means of a questionnaire survey and qualitative research using eye tracking camera. The aim of the diploma theses is to investigate the impact of the new media used in TMCZ stores on the customers by means of own field research. Finally, on the basis of the evaluation of the research results, author will propose recommendations for the future retail marketing activities and customer journey optimization in T-Mobile stores
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