57 research outputs found

    Trioctylphosphine as Both Solvent and Stabilizer to Synthesize CdS Nanorods

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    Abstract High quality CdS nanorods are synthesized reproducibly with cadmium acetate and sulfur as precursors in trioctylphosphine solution. The morphology, crystalline form and phase composition of CdS nanorods are characterized by transmission electron microscopy (TEM), high-resolution TEM and X-ray diffraction (XRD). CdS nanorods obtained are uniform with an aspect ratio of about 5:1 and in a wurtzite structure. The influence of reaction conditions on the growth of CdS nanorods demonstrates that low precursor concentration and high reaction temperature (260 &#176;C) are favorable for the formation of uniform CdS nanorods with 85.3% of product yield.</p

    Pho-view of auxin: Reversible protein phosphorylation in auxin biosynthesis, transport and signaling

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    The phytohormone auxin plays a central role in shaping plant growth and development. With decades of genetic and biochemical studies, numerous core molecular components and their networks, underlying auxin biosynthesis, transport, and signaling, have been identified. Notably, protein phosphorylation, catalyzed by kinases and oppositely hydrolyzed by phosphatases, has been emerging to be a crucial type of post-translational modification, regulating physiological and developmental auxin output at all levels. In this review, we comprehensively discuss earlier and recent advances in our understanding of genetics, biochemistry, and cell biology of the kinases and phosphatases participating in auxin action. We provide insights into the mechanisms by which reversible protein phosphorylation defines developmental auxin responses, discuss current challenges, and provide our perspectives on future directions involving the integration of the control of protein phosphorylation into the molecular auxin network

    The ABI3-ERF1 module mediates ABA-auxin crosstalk to regulate lateral root emergence

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    Summary: Abscisic acid (ABA) is involved in lateral root (LR) development, but how ABA signaling interacts with auxin signaling to regulate LR formation is not well understood. Here, we report that ABA-responsive ERF1 mediates the crosstalk between ABA and auxin signaling to regulate Arabidopsis LR emergence. ABI3 is a negative factor in LR emergence and transcriptionally activates ERF1 by binding to its promoter, and reciprocally, ERF1 activates ABI3, which forms a regulatory loop that enables rapid signal amplification. Notably, ABI3 physically interacts with ERF1, reducing the cis element-binding activities of both ERF1 and ABI3 and thus attenuating the expression of ERF1-/ABI3-regulated genes involved in LR emergence and ABA signaling, such as PIN1, AUX1, ARF7, and ABI5, which may provide a molecular rheostat to avoid overamplification of auxin and ABA signaling. Taken together, our findings identify the role of the ABI3-ERF1 module in mediating crosstalk between ABA and auxin signaling in LR emergence

    One-Pot Synthesis of Hollow PbSe Single-Crystalline Nanoboxes via Gas Bubble Assisted Ostwald Ripening

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    We report a simple one-pot route to fabricate PbSe hollow single-crystalline nanoboxes with the presence of trioctylphosphine as the structure-directing agent and stabilizer. Various controlling parameters were examined, such as trioctylphosphine amounts, reaction temperature, reaction time, and lead(II) precursors. On the basis of the experimental results, the gas bubbles assisted Ostwald ripening process was proposed to explain the formation of hollow PbSe nanoboxes. The morphology and composition of the products were characterized by X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, and transmission electron microscopy
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