1,721,080 research outputs found
Longitudinally Two-Photon Pumped Leaky Waveguide Dye Film Laser
No full textLongitudinally two-photon pumped (TPP) and frequency-upconverted cavity lasing is achieved in a planar leaky waveguide configuration which utilizes a dye-doped polymer film coating on the surface of an optical glass prism. The TPP lasing dye is 4-dimethylamino-N-methylstilbazolium tosylate (DAST) that has been extensively studied as a second order nonlinear optical material. The spectral, temporal, and spatial structures as well as the output-input characteristics of the TPP cavity lasing were measured using a ~170-μm-thick film with a ~2.4-mm pump depth. The leaky waveguide lasing was featured by a nearly single transverse-mode and five axial-modes structure. In our preliminary study, the net conversion
efficiency from the absorbed 1064-nm pump pulse energy to the output ~607-nm upconverted cavity lasing energy was found to be ~0.65%. However, this efficiency can be considerably increased by further optimizing the system parameters
Excited state absorption of fullerenes measured by the photoacoustic calorimetry technique
No full textPhotoacoustic calorimetry (PAC) is used to determine the excited state absorption cross sections in a molecular system showing reverse saturable absorption behavior. PAC experiments on fullerene and fulleropyrrolidine in toluene solutions are performed at 532 nm and 690 nm, with a ns laser source. The PAC signal amplitude displays a superlinear increase when the energy of the applied laser source is increased. This behavior is ascribed to a process of enhanced absorption due to molecules populating the excited electronic states. The PAC signal observed for these chromophores is simulated numerically. The simulations rely on a description of the absorbing molecule as a six-level system, whose molecular parameters (i.e. absorption cross sections and lifetimes) are the ones for a reverse saturable absorber. The time-dependent population in the different energy levels is described through a rate equation system. This kind of model has been widely used by us to reproduce other experimental data such as nonlinear transmittance and Z-scan data. The PAC signal amplitude is the sum of the different contributions to non-radiative relaxation which arise from molecules populating different energy levels. The absorption cross sections for the singlet and triplet excited states of fullerene and fulleropyrrolidine are derived from the simulated PAC signal amplitudes. The values obtained are in good agreement with literature data measured with different techniques
Sensitive detection of Ochratoxin A in food and drinks using metal-enhanced fluorescence
No full textRaman Investigation on Silicon Nitride Chips after Soldering onto Copper Substrates
Full text linkThe unique electrical properties of silicon nitride have increased the applications in microelectronics, especially in the manufacture of integrated circuits. Silicon nitride is mainly used as a passivation barrier against water and sodium ion diffusion and as an electrical insulator between polysilicon layers in capacitors. The interface with different materials, like semiconductors and metals, through soldering may induce residual strains in the final assembly. Therefore, the dentification and quantification of strain becomes strategically important in optimizing processes to enhance the performance, duration, and reliability of devices. This work analyzes the thermomechanical local strain of semiconductor materials used to realize optoelectronic components. The strain induced in the β-Si3N4 chips by the soldering process performed with AuSn pre-formed on copper substrates is investigated by Raman spectroscopy in a temperature range of −50 to 180 °C. The variation in the position of the E1g Raman peak allows the calculation of the local stress present in the active layer, from which the strain induced during the assembly process can be determined. The main reason for the strain is attributed to the differences in thermal expansion coefficients among the various materials involved, particularly between the chip, the interconnection material, and the substrate. Micro-Raman spectroscopy allows for the assessment of how different materials and assembly processes impact the strain, enabling more informed decisions to optimize the overall device structure
Organic functionalization and optical properties of carbon onions
No full textHere we report, for the first time, a method for chemically
functionalizing onions from arc discharge soots. The new methodology not only allows the isolation of giant fullerenes, but especially renders them soluble in organic solvents, such that their solution properties can be studied for the first time
Two-Photon Pumped Frequency-Upconvertion blue Lasing in Coumarine Dye Solution
No full textTwo-photon-pumped (TPP) frequency-upconverted blue lasing of Coumarin 500 dye solution has been experimentally investigated. The shortest lasing wavelength was measured to be ~479 nm from a Coumarin 500 solution in chloroform pumped with ~800-nm laser pulses of ~5-ns duration. The spectral, temporal, and spatial structures as well as the output-input characteristics of TPP cavity lasing were measured with a 1-cm-long Coumarin 500 solution-filled quartz cuvette. The cavity lasing spectral structure and the numbers of longitudinal modes were easily controlled simply by attachment of an optical plate to the output window of the dye-solution cuvette. The net conversion efficiency from the absorbed 800-nm pump pulse energy to the blue-upconverted cavity lasing energy was ~4.8%
New sol-gel materials for high energy applications in nonlinear optics
No full textOrganic-inorganic hybrid materials, composed of inorganic oxide structures and interpenetrated cross-linked organic polymers, are promising candidates for electro/optical applications, combining the most important glasslike and
polymerlike properties. This is particularly true when large laser power density is used: these materials show high laser
damage resistance compared with that of polymeric systems.
A deep study of effects and causes of laser damage has never been done, especially for hybrid materials. The
mechanisms of optical damage depend on different factors like laser experimental parameters, such as pulse duration,
beam size and wavelength, or the microstructural characteristics and defects of the material.
Hybrid materials possessing desired shapes and optical and mechanical properties are well synthesized by the sol-gel
technique. The use of Glycidoxypropyltrimethoxysilane (GPTMS) allows preparing heterogeneous and resistant
materials, with good optical properties.
Different sol-gel matrices have been prepared in order to study their laser damage resistance. The possibility of varying
the catalysts and precursors or the synthesis protocol allows obtaining materials with similar chemical composition and
different microscopical properties. By this way, it is possible to study the laser damage threshold of these samples and to
find the way to enhance and optimize the laser damage resistance, useful in non-linear optical devices
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