54 research outputs found

    New Mn Electrochemistry for Rechargeable Aqueous Batteries: Promising Directions Based on Preliminary Results

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    Aqueous batteries with metal anodes exhibit robust anodic capacities, but their energy densities are low because of the limited potential stabilities of aqueous electrolyte solutions. Current metal options, such as Zn and Al, pose a dilemma: Zn lacks a sufficiently low redox potential, whereas Al tends to be strongly oxidized in aqueous environments. Our investigation introduces a novel rechargeable aqueous battery system based on Mn as the anode. We examine the effects of anions, electrolyte concentration, and diverse cathode chemistries. Notably, the ClO4-based electrolyte solution exhibits improved deposition and dissolution efficiencies. Although stainless steel (SS 316 L) and Ni are stable current collectors for cathodes, they display limitations as anodes. However, using Ti as the anode resulted in increased Mn deposition and dissolution efficiencies. Moreover, we evaluate this system using various cathode materials, including Mn-intercalation-based inorganic (Ag0.33V2O5) and organic (perylenetetracarboxylic dianhydride) cathodes and an anion-intercalation-chemistry (coronene)-based cathode. These configurations yield markedly higher output potentials compared to those of Zn metal batteries, highlighting the potential for an augmented energy density when using an Mn anode. This study outlines a systematic approach for use in optimizing metal anodes in Mn metal batteries, unlocking novel prospects for Mn-based batteries with diverse cathode chemistries. © 2024 The Author(s). Energy & Environmental Materials published by John Wiley & Sons Australia, Ltd on behalf of Zhengzhou University.TRUEsciescopu

    Expert Opinion and Reform in Anglo-American, Continental, and Israeli Adjudication

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    The factual framework of modem litigation has become increasingly technical and complex; this development poses new challenges for traditional fact-finders. More and more, expert witnesses are being used to assist judges and juries in the factfinding process. This Article examines the role of the expert witness in the common-law and civil-law judicial systems, emphasizing the manner in which the divergent systems have responded to the need for reform in this area. The author then examines the role of the expert in the hybrid Israeli judicial system, which is rooted in both the civil-law and common-law traditions. Finally, the author demonstrates the relationship between prevailing attitudes toward the nature of adjudication and the response to pressure for the reform of the adjudicative process

    Expert Opinion and Reform in Anglo-American, Continental, and Israeli Adjudication

    No full text
    The factual framework of modem litigation has become increasingly technical and complex; this development poses new challenges for traditional fact-finders. More and more, expert witnesses are being used to assist judges and juries in the factfinding process. This Article examines the role of the expert witness in the common-law and civil-law judicial systems, emphasizing the manner in which the divergent systems have responded to the need for reform in this area. The author then examines the role of the expert in the hybrid Israeli judicial system, which is rooted in both the civil-law and common-law traditions. Finally, the author demonstrates the relationship between prevailing attitudes toward the nature of adjudication and the response to pressure for the reform of the adjudicative process

    Laser exfoliated 2D MXene for supercapacitor applications

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    MXenes-based compounds, particularly Ti3C2Tx, have been studied intensively as electrodes for supercapacitors due to their layered structure and high conductivity, enabling facile ion diffusion and charge transfer. However, tight restacking of the 2D layers in these materials limits their practical, accessible surface area, thereby impeding their capacity and rate capability performance. To mitigate this phenomenon, we present a new approach using a processing method based on laser beam irradiation to modify Ti3C2Tx films. We found that the laser treatment induces chemical and morphological changes, ultimately optimizing the stacking arrangement of the MXene electrodes and consequently enhancing their capacity in both neutral and acidic electrolytes. Furthermore, the laser-modified MXene electrodes demonstrate excellent rate capabilities, showing 84 % retention at extreme rates of 0.5 V compared to only 33 % of the original Ti3C2Tx electrodes. Finally, we discuss the chemical and physical changes induced by the laser treatments and their influence on the electrochemical behavior of the lasered MXene. The principles of laser exfoliation discovered in this study can be implemented in broader 2D materials for various applications

    π-Electron-Assisted Charge Storage in Fused-Ring Aromatic Carbonyl Electrodes for Aqueous Manganese-Ion Batteries

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    Rechargeable manganese batteries hold promise for large-scale energy storage due to the abundance and eco-friendly nature of manganese. A key challenge is developing cathode materials capable of reversibly inserting Mn ions with a high specific capacity. Here, we demonstrate that perylene-3,4,9,10-tetracarboxylic dianhydride electrodes efficiently and reversibly insert Mn2+ ions in 3 M MnCl2 aqueous electrolyte solutions. Leveraging the carbonyl groups and the π-electron configuration, such compounds can serve as robust redox centers, facilitating reversible interactions with divalent ions such as Mn2+. Through comprehensive studies involving electrochemistry, elemental analyses, spectroscopy, and structural analysis, we explored these systems and found them as promising anode materials for Mn batteries. Demonstrating excellent Mn storage capabilities, such molecules could attain a reversible capacity of approximately >185 mAh g-1 at a current density of 100 mA g-1, maintaining an average voltage of approximately 0.8 V vs Mn/Mn2+, while exhibiting notable capacity retention. © 2024 American Chemical Society.FALSEsciescopu
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