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    Reaction of ortho-azidohetaren carbaldehydes with bis(trimethylsilyl)sulfide: a novel route to fused isothiazoles

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    o-Azidohetarenecarbaldehydes react with bis(trimethylsiyl) sulfide and hydrochloric acid to give fused isothiazoles in yields strongly dependent upon the nature of the heteroaromatic ring through intramolecular cyclization reaction of presumable intermediate o-azidocarbothialdehydes

    Novel synthesis of stable furan and thiophene o-aminothioaldehydes through reaction of o-azidoaldehydes with hexamethyldisilathiane

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    new synthesis of monomeric o-amino thioaldehydes of thiophene, benzo[b]thiophene, furan and benzo[b]furan by reacting the corresponding o-azido aldehydes with hexamethyldisilathiane in neat acetonitrile and/or in methanol in the presence of hydrochloric acid at room temperature is reported
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