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    Multiscale Soil Salinity Assessment at the Southern Margin of the Venice Lagoon, Italy

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    Saltwater intrusion affects many coastlands around the world contaminating fresh-groundwater and decreasing soil quality. In order to manage saline soils one should understand the spatiotemporal dynamics of salinity in the soil profile and its spatial variability at field scale. In the last decades, soil and pore-water salinity have been assessed using geophysical techniques, most commonly with the use of apparent electrical conductivity (ECa) measurements. At point-scale, pore-water salinity can be estimated once its relationship with ECa, soil properties, and water content is understood. Moreover, most sensors for water content estimation normally provide biased readings in saline conditions and in soil with high clay and organic carbon contents. At field-scale proximal-sensing can be used to characterize large portions of land from a relatively small number of soil samples. Sometimes, characterizing salinity is however not sufficient to understand crop yield spatial variability, which can be also influenced by other soil properties. Understanding the influence of salinity and other soil properties on crop productivity can be useful in the identification of areas that can be managed site-specifically. The general aim of this dissertation is to evaluate some sensor-based methodologies for monitoring and characterizing salinity and other related soil properties both at point- and field-scale. In particular, at point-scale the dissertation will deal with the issues regarding the use of capacitive-resistive technology for water content and pore-water salinity estimation. At field-scale some methodologies will be proposed in order to characterize the spatial variability of salinity and other soil properties influencing maize (Zea mais L.) yield using soil proximal-sensing. All the material presented in this manuscript regard the soils of an area affected by saltwater intrusion located at the southern edge of the Venice Lagoon (Italy). The dissertation is structured in five chapters. The first one includes a review on commonly used methodologies for point- and field-scale salinity assessment. An overview on the environmental issues concerning the coastland at the southern margin of the Venice Lagoon is also presented. The second chapter deals with the calibration of a low-cost capacitance-resistance probe for simultaneous monitoring of soil water content and salinity. In the third chapter an ECa-directed soil sampling scheme optimization procedure is proposed. The forth chapter analyzes maize yield as a function of soil chemical and physical properties and investigates on the use of soil-proximal sensing correlated to soil spatial variability for site-specific management units. The final chapter presents the general conclusions of the work

    Simultaneous Monitoring of Soil Water Content and Salinity with a Low-Cost Capacitance-Resistance Probe

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    Capacitance and resistivity sensors can be used to continuously monitor soil volumetric water content (θ) and pore-water electrical conductivity (ECp) with non-destructive methods. However, dielectric readings of capacitance sensors operating at low frequencies are normally biased by high soil electrical conductivity. A procedure to calibrate capacitance-resistance probes in saline conditions was implemented in contrasting soils. A low-cost capacitance-resistance probe (ECH2O-5TE, 70 MHz, Decagon Devices, Pullman, WA, USA) was used in five soils at four water contents (i.e., from dry conditions to saturation) and four salinity levels of the wetting solution (0, 5, 10, and 15 dS·m−1). θ was accurately predicted as a function of the dielectric constant, apparent electrical conductivity (ECa), texture and organic carbon content, even in high salinity conditions. Four models to estimate pore-water electrical conductivity were tested and a set of empirical predicting functions were identified to estimate the model parameters based on easily available soil properties (e.g., texture, soil organic matter). The four models were reformulated to estimate ECp as a function of ECa, dielectric readings, and soil characteristics, improving their performances with respect to the original model formulation. Low-cost capacitance-resistance probes, if properly calibrated, can be effectively used to monitor water and solute dynamics in saline soils

    Identification of the Origins of Vadose-Zone Salinity on an Agricultural Site in the Venice Coastland by Ionic Molar Ratio Analysis

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    Saltwater contamination seriously affects water quality and land productivity of reclaimed farmlands along the Venice Lagoon, Italy. To characterize the hydrogeochemical dynamics involved in this phenomenon, a three-year study was carried out in an experimental field located at the southern margin of the Venice Lagoon. Soil matric potential, quality of soil pore water and groundwater, and soil physical and chemical properties were monitored at five monitoring stations. Relationships between Cl−, Na+, Mg2+, Ca2+, K+, SO42−, Br− ionic concentrations, and electrical conductivity of the water samples with the soil characteristics (e.g., texture, exchangeable cations) were investigated. Soil water flux direction was calculated and related to ion concentrations. Moreover, specific molar ratios (Mg/Ca, Na/Cl, Cl/Br, and SO4/Cl) were calculated to identify the main drivers affecting salinity in the field. The study confirmed that the experimental site was strongly affected by soil and water salinity, and two major contamination dynamics were identified. The first one was mainly driven by seawater intrusion from the near lagoon and salty watercourses, while the second was derived by the interactions between the peaty soil and salts that were originally in place, since the area was only reclaimed a few decades ago. The latter highlighted the potentiality of the experimental field to become an acidic sulfate environment. Ionic ratios were implemented and proved to be an important tool for the identification of salinity origin
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