66 research outputs found

    Influence of chemical structure on the mesomorphic behaviour of 3,5-disubstituted 1,2,4-oxadiazoles

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    The correlation between chemical structure and mesomorphic properties is one of the most important problems in liquid crystals science. 3,5-Disubstituted 1,2,4-oxadiazoles are very convenient model-compounds for studying the dependence of the LC properties on the molecular design. The transition temperatures and dielectric properties of 1,2,4-oxadiazoles depend significantly both on the position of the substituents with respect to the heterocycle and on their donor or acceptor features

    Alignment transition driven by adsorption in a nematic liquid crystal forming H-bonds

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    Restricted Access.We have found that some nematic liquid crystals whose molecules from H-bonds, namely trans-4-alkylcyclohexanecarboxylic acids, undergo a new type of alignment transition on silicon-monoxide-coated glass plates exposed to dry air. We argue that it is caused by the adsorption of the acid monomers and discuss the result on the basis of Fowler's theory
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