1,471 research outputs found
Wetting: Theory and Experiment
No full textComitato organizzatore: Amy Novick-Cohen, Alexander Nepomnyashchy, Leonid Pismen.
Comitato Scientifico: M. Ben Amar, S. Davis, L. Giacomelli, G. Gruen, J. King, D. Mukamel, A. Nepomnyashchy, A. Novick-Cohen, L. Pismen, Y. Pomeau, D. Quere.
The goal of the conference is to exchange information and discussion among numerous people interested in this field and coming from various disciplines, with an emphasis on the analytical and the asymptotic, the theoretical as well as the experimental
S. M. Novick, Honorable Justice. The Life of Oliver Wendell Holmes
No full textS. M. Novick, Honorable Justice. The Life of Oliver Wendell Holmes. In: Revue internationale de droit comparé. Vol. 42 N°1, Janvier-mars 1990. pp. 421-423
S. M. Novick, Honorable Justice. The Life of Oliver Wendell Holmes
No full textS. M. Novick, Honorable Justice. The Life of Oliver Wendell Holmes. In: Revue internationale de droit comparé. Vol. 42 N°1, Janvier-mars 1990. pp. 421-423
A Microwave Study Of Three Bromine-containing Molecules: Cbr<sub>2</sub>f<sub>2</sub>, Agbr, And H<sub>2</sub>-agbr
No full textIn preparation for our FTMW study of the complex between hydrogen and silver bromide, H-AgBr, we have investigated the microwave spectra of our source of bromine, dibromodifluoromethane, CBrF. Previous sources of bromine to produce AgBr proved either too damaging to the instrumentation in the long term (Br), or did not produce enough AgBr to be useful (CHBr). In addition, silver bromide, originally studied by Hoeft, Lovas, Tiemann, and Torring in 1971,\footnote{J. Hoeft, F. J. Lovas, E. Tiemann, T. Torring, Z. Naturforsch. 25a, 35 (1970).} and remeasured by Evans and Gerry in 2000,\footnote{C. J. Evans, M. C. L. Gerry, J. Chem. Phys. 112, 1321 (2000).} was remeasured once more. We plan to produce H-AgBr, using laser ablation of a silver rod within a supersonic expansion of an argon carrier gas containing H and CBrF. This is part of our ongoing study of hydrogen complexed with metal halides which include H-CuF,\footnote{D. J. Frohman, G. S. Grubbs II, Z. Yu, S. E. Novick, Inorg. Chem. 52, 816 (2013).} H-AgCl,\footnote{G. S. Grubbs II, D. A. Obenchain, H. M. Pickett, S. E. Novick, J. Chem. Phys. 141, 114306 (2014).} and H-AuCl.\footnote{D. A. Obenchain, G. S. Grubbs II, H. M. Pickett, S. E. Novick, J. Chem. Phys. 146, 204302 (2017).} These molecules are “models” of the molecular hydrogen storage in the cavities of metal organic frameworks (MOFs).Made available in DSpace on 2021-09-24T21:08:58Z (GMT). No. of bitstreams: 2
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Previous issue date: 2021-06-2
Fitzpatrick S., Le stalinisme au quotidien. La Russie soviétique dans les années 30 - Novick P., L'Holocauste dans la vie américaine
No full textCourty Guillaume. Fitzpatrick S., Le stalinisme au quotidien. La Russie soviétique dans les années 30 - Novick P., L'Holocauste dans la vie américaine. In: Politix, vol. 16, n°63, Troisième trimestre 2003. Fréquentations militantes, sous la direction de Jean-Philippe Heurtin. pp. 202-208
A microwave study of three bromine-containing molecules: cbr2f2, agbr, and h2 agbr
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Previous issue date: 24In preparation for our FTMW study of the complex between hydrogen and silver bromide, H AgBr, we have investigated the microwave spectra of our source of bromine, dibromodifluoromethane, CBrF. Previous sources of bromine to produce AgBr proved either too damaging to the instrumentation in the long term (Br), or did not produce enough AgBr to be useful (CHBr). In addition, silver bromide, originally studied by Hoeft, Lovas, Tiemann, and Torring in 1971,\footnote{J. Hoeft, F. J. Lovas, E. Tiemann, T. Torring, Z. Naturforsch. 25a, 35 (1970).} and remeasured by Evans and Gerry in 2000,\footnote{C. J. Evans, M. C. L. Gerry, J. Chem. Phys. 112, 1321 (2000).} was remeasured once more. We plan to produce H AgBr, using laser ablation of a silver rod within a supersonic expansion of an argon carrier gas containing H and CBrF. This is part of our ongoing study of hydrogen complexed with metal halides which include H CuF,\footnote{D. J. Frohman, G. S. Grubbs II, Z. Yu, S. E. Novick, Inorg. Chem. 52, 816 (2013).} H AgCl,\footnote{G. S. Grubbs II, D. A. Obenchain, H. M. Pickett, S. E. Novick, J. Chem. Phys. 141, 114306 (2014).} and H AuCl.\footnote{D. A. Obenchain, G. S. Grubbs II, H. M. Pickett, S. E. Novick, J. Chem. Phys. 146, 204302 (2017).} These molecules are “models” of the molecular hydrogen storage in the cavities of metal organic frameworks (MOFs)
The Pure Rotational Spectrum of a Claisen Rearrangement Precursor Allyl Phenyl Ether using CP-FTMW Spectroscopy
No full textThe pure rotational spectrum of a Claisen rearrangement precursor, Allyl Phenyl Ether (APE), has been measured on a chirped pulse Fourier transform microwave (CP-FTMW) spectrometer in the 8-14 GHz region. Rotational and centrifugal distortion constants for multiple conformations have been determined and are reported for the first time. This is the first study of a phenyl-containing ether where multiple conformers were experimentally observed all within their ground vibrational states. Quantum chemical calculations have been performed to isolate low energy geometries of APE and are implemented to aid in spectral assignment. Other structural parameters such as planar moments and inertial defects for the Allyl Phenyl Ether conformers are presented and compared to similar molecules
The Covalent Interaction between Dihydrogen and Gold: a Rotational Spectroscopic Study of H₂-AuCl
No full textThe pure rotational transitions of H2-AuCl have been measured using a pulsed-jet cavity Fourier transform microwave spectrometer equipped with a laser ablation source. The structure was found to be T-shaped, with the H-H bond interacting with the gold atom. Both 35Cl and 37Cl isotopologues have been measured for both ortho and para states of H2. Rotational constants, quartic centrifugal distortion constants, and nuclear quadrupole coupling constants for gold and chlorine have been determined. The use of the nuclear spin-nuclear spin interaction terms Daa, Dbb, and Dcc for H2 were required to fit the ortho state of hydrogen, as well as a nuclear-spin rotation constant Caa. The values of the nuclear quadrupole coupling constant of gold are Xaa=-817.9929(35) MHz, Xbb=504.0(27) MHz, and Xcc=314.0(27). This is large compared to the eQq of AuCl, 9.63 312(13) MHz, which indicates a strong, covalent interaction between gold and dihydrogen
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