1,721,075 research outputs found
Recent and paleokarst systems and their relation to ore mineralization in the Iberg-reef-complex, Harz Mountains
No full textIn the SW Harz Mountains (F.R.G.) the dome-shaped Devonian Iberg-Winterberg reef limestone emerges from the surrounding Carboniferous graywackes. The small limestone outcrop (km2) consists of two atoll-like structures, the Iberg in the SE and the Winterberg in the NW. The original reef shape is suppressed by boundary faults, separating the limestone from the clastic rocks. Its total extension may have amounted to 12.5 km2, with a thickness of 600 m (FRANKE, 1973). More than 80 cavities are known within the complex descending a few to 50 m belwo the surface. Most of them are closely associated with iron-manganese ore bodies, which gave rise to intensive mining activity during the last centuries. The natural caves served as shafts for bost descending into the mines and hauling the iron ores in the eralier periods of mining. In the middle of the 19th centruy a gallery (Eisensteinstollen) was driven into the IBerg, but already in 1887 the last mine was abondoned. In 1986 the gallery and the system of natural caves and mines was made accessible again exceeding a total length of 5 km (Fig. 1,2)
Calcification of cyanobacterial filaments: Girvanella and the origin of lower Paleozoic lime mud: Comment and reply - Comment
No full textAlkalinity
No full textThe term “Alkalinity ,” commonly denoted by TA (also AT, ALK, and others) and then called titration alkalinity or total alkalinity, refers to a very important chemical concept in aquatic chemistry. Total alkalinity is one of the few measurable quantities in natural waters that allows, together with other properties, to calculate concentrations of single species of the carbonate system such as CO2, HCO3 −, CO3 2−, H+, and OH− (Wolf-Gladrow et al., 2007), and further on, the saturation state of the waters with respect to certain carbonate minerals. Therefore, alkalinity represents a hydrogeochemical key parameter for the understanding of carbonate precipitation, either biologically mediated or not, and its variation through the geological history
Calcification in cyanobacterial biofilms of alkaline salt lakes
No full textGeomicrobiological analysis of calcifying biofilms of three alkaline salt lakes characterized by moderate to high carbonate alkalinity indicates that microbial carbonate rock formation is not directly linked to cyanobacterial carbon fixation. The present review summarizes results from two published case studies that have been carried out at Pyramid Lake, USA, and Lake Nuoertu, PR China. New observations and data are presented for a current project on Satonda Crater Lake, Indonesia, that revise previous conclusions concerning the relationship between cyanobacteria and biofilm calcification. Extracellular polymeric substances (EPS) in the investigated lakes are mostly produced by cyanobacteria; their properties are discussed as key factors in biofilm calcification. In particular, EPS are capable of binding divalent cations (e.g. Ca2+) from the liquid phase by their carboxylate and sulphate groups. Therefore, despite a high supersaturation of the lake water with respect to calcium carbonate minerals, precipitation does not take place immediately. A delayed onset of precipitation can be achieved by a continuous Ca2+ supply that exceeds the Ca2+-binding capacity of the EPS, and/or an exoenzymatic degradation (decarboxylation, cleavage) of mucous substances that reduces the binding capacity and causes secondary Ca2+ release. The resulting microcrystalline precipitates are randomly distributed within the EPS, usually away from any of the living cyanobacteria. This suggests that the effect of photosynthetic CO2 fixation in increasing supersaturation is of secondary importance at high alkalinities. In contrast to biofilm-covered surfaces, calcium carbonate minerals nucleate and grow rapidly at surfaces poor in EPS when the critical supersaturation level for non-enzymatically controlled carbonate precipitation is reached. Examples of such surfaces poor in EPS are dead, lysed green algal cells and thin, discontinuous biofilms in voids of microbial reef rocks. Calcium carbonate crystals directly linked to cyanobacterial cells or filaments have been observed only exceptionally, e.g. on Calothrix
Photosynthesis-induced biofilm calcification and calcium concentrations in phanerozoic oceans
No full textPhotosynthetic carbon assimilation is commonly invoked as the cause of calcium carbonate precipitation in cyanobacterial biofilms that results in the formation of calcareous stromatolites. However, biofilm calcification patterns in recent lakes and simulation of photosynthetically induced rise in calcium carbonate supersaturation demonstrate that this mechanism applies only in settings Low in dissolved inorganic carbon and high in calcium. Taking into account paleo-partial pressure curves for carbon dioxide, we show that Phanerozoic oceans sustaining calcified cyanobacteria must have had considerably higher calcium concentrations than oceans of today. In turn, the enigmatic lack of calcified cyanobacteria in stromatolite-bearing Precambrian sequences can now be explained as a result of high dissolved inorganic carbon concentrations
Investigations on stromatolitic carbonates from Western Australian Lakes Research report CALM Licence No. SF002571
No full textCalcification in cyanobacterial biofilms of alkaline salt lakes
No full textGeomicrobiological analysis of calcifying biofilms of three alkaline salt lakes characterized by moderate to high carbonate alkalinity indicates that microbial carbonate rock formation is not directly linked to cyanobacterial carbon fixation. The present review summarizes results from two published case studies that have been carried out at Pyramid Lake, USA, and Lake Nuoertu, PR China. New observations and data are presented for a current project on Satonda Crater Lake, Indonesia, that revise previous conclusions concerning the relationship between cyanobacteria and biofilm calcification. Extracellular polymeric substances (EPS) in the investigated lakes are mostly produced by cyanobacteria; their properties are discussed as key factors in biofilm calcification. In particular, EPS are capable of binding divalent cations (e.g. Ca²⁺) from the liquid phase by their carboxylate and sulphate groups. Therefore, despite a high supersaturation of the lake water with respect to calcium carbonate minerals, precipitation does not take place immediately. A delayed onset of precipitation can be achieved by a continuous Ca²⁺ supply that exceeds the Ca²⁺-binding capacity of the EPS, and/or an exoenzymatic degradation (decarboxylation, cleavage) of mucous substances that reduces the binding capacity and causes secondary Ca²⁺ release. The resulting microcrystalline precipitates are randomly distributed within the EPS, usually away from any of the living cyanobacteria. This suggests that the effect of photosynthetic CO2 fixation in increasing supersaturation is of secondary importance at high alkalinities. In contrast to biofilm-covered surfaces, calcium carbonate minerals nucleate and grow rapidly at surfaces poor in EPS when the critical supersaturation level for non-enzymatically controlled carbonate precipitation is reached. Examples of such surfaces poor in EPS are dead, lysed green algal cells and thin, discontinuous biofilms in voids of microbial reef rocks. Calcium carbonate crystals directly linked to cyanobacterial cells or filaments have been observed only exceptionally, e.g. on Calothrix
Biostratigraphy and sedimentary sequences of the Toarcian Hainberg section (Northwestern Harz foreland, Northern Germany)
No full textA temporary outcrop in southern Lower Saxony permitted the sedimentological, geochemical and palaeontological investigation of a 40.8 m thick Toarcian section, from the top of the Amaltheenton Formation, through the Posidonienschiefer and Jurensismergel Formations, to lower parts of the Opalinuston Formation. Bed by bed collected ammonites and belemnites, bivalve associations, as well as data from neighbouring sections indicate a largely complete sequence of ammonite zones and subzones for the Lower Toarcian. A prominent stratigraphic gap at the Posidonienschiefer/Jurensismergel Formation boundary probably comprises the Semipolitum Subzone as well as the Variabilis and Thouarsense Zones. Above a condensed Dispansum Zone follows the higher Upper Toarcian with a presumably largely complete sequence of zones and subzones, although direct evidence for this is only sporadic. However, a thin condensed bed with stromatolite crusts is recognisable at the boundary Pseudoradiosa to Mactra/Aalensis Subzone. The Toarcian/Aalenian boundary can only be drawn on basis of belemnite finds at another thin condensed bed. Only a few metres above, the Opalinum Zone is evident by ammonite findings. Based on discontinuities, lithofacies, biofacies and correlations with neighbouring sections, a subdivision into alloformations, which largely correspond to formations, is applied. Based on that, a sequence stratigraphic interpretation with respect to third order transgression-regression cycles (T-R sequences) can be inferred: Above the regressive upper parts alloformation 1 (Amaltheenton Formation) with a maximum regression surface (mrs) near its top, the T-R sequence of the alloformation 2 (Posidonienschiefer Formation) is developed, with a maximum flooding surface (mfs) at the transition Falciferum/Commune Subzone and the regressive phase within the later Bifrons Zone. For the Commune Subzone, belemnite alignment indicates a seawater bottom current from SSE. The following maximum regression surface (mrs) lies near the Bifrons/Variabilis Zone boundary. The next sequence is not preserved at the studied location, but is preserved further East as well as further West, represented by the transgressive Dörnten Member (Variabilis and Thouarsense Zone). However, the regressive phase (Fallaciosum Subzone) is also missing there, indicated by a prominent sequence boundary with erosional relief at the base of the Dispansum Zone. The following alloformation 3 (Jurensismergel Formation and lowermost parts Opalinuston Formation) represents another T-R sequence with a maximum transgressive surface (base Mactra/Aalensis subzone) and a slightly thicker regressive Aalensis Subzone. The following maximum regression surface represents the boundary to alloformation 4 (major parts of Opalinuston Formation), followed again by a short transgressive phase (Pseudolotharingicum Subzone), condensation horizon and a longer regressive phase (Opalinum Zone). These sequence stratigraphic interpretations are largely consistent with previous investigations in Northern and Southern Germany. Minor deviations in the timely position of maximum flooding and regression surfaces likely reflect effects of a higher subsidence at variable sedimentation rate in the North German Basin. With respect to the, at the site of investigation, incompletely exposed Opalinuston Formation, further studies on complete drill core sections are required
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