1,721,068 research outputs found
Mechanisms of the aerobic oxidation catalyzed by N-hydroxyderivatives. Enthalpic, polar and solvent effects. Molecole-induced homolysis and synthetic involvements
No full textMechanisms of the aerobic oxidations catalyzed by N-hydroxyderivatives. Enthalpic, polar and solvent effects, "molecule-induced homolysis" and synthetic involvments
No full text
Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide
No full textThis review gives a general overview of the reactions
catalyzed by N-hydroxyphthalimide and related compounds.
It focuses on processes ranging from commercial production of
chemicals, such as adipic and terephthalic acid, to fine
chemicals such as those discussed in the sections on C-N
and C-C bond formation.
The synthetic and reaction mechanisms aspects are critically rewieved, as well
a great consideration is given to the thermodynamic and kinetic issues
concerning the nitroxyl radicals involved in the catalytic procesess
HYDROPEROXIDES AS PSEUDOHALIDES - OXIDATION, OXIDATIVE ALKYLATION, ACYLATION AND ARYLATION OF ACRYLONITRILE
No full textFunzionalizzazione selettiva di idrocarburi con acido nitrico in condizioni aerobiche, catalizzata da NHPI e iodio in condizioni blande
No full textFree-radical mechanisms in the oxidation and halogenation of alkanes, alkenes and alkylbenzenes by t-BuOOH under Gif-Barton catalysis
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