1,721,077 research outputs found

    Esperienze in Europa: il caso belga

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    Il testo affronta il problema dell'adeguamento e delle progettazione delle stazioni e delle aree ferroviarie come occasioni di riqualificazione urban

    Polymer-bound chiral (Salen)Mn(III) complex as heterogeneous catalyst in rapid and clean enantioselective epoxidation of unfunctionalized olefins

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    The application of a new polystyrene-divinylbenzene system containing an optically active (salen)Mn(III) complex in asymmetric epoxidation of unfunctionalised olefins is reported. This system showed a remarkably high reaction speed in the conditions described. Reaction outcomes drastically varied, in terms of enantioselectivity and cis-trans isomerization extent, upon the terminal oxidant employed (mCPBANMO and MMPP). Reuse of the catalyst was extremely efficient for several cycles. Interesting values of ee were obtained for styrene (15%) and cis-β-methylstyrene (41%)

    In Defence of the Catalytic Asymmetric cis Dihydroxylation of Olefins Utilizing Insoluble Polymeric Ligands

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    In Defense of the Catalytic Asymmetric Cis Dihydroxylation of Olefins Utilizing Insoluble Polymeric Ligand

    STUDIO DI UN CASO DI ORTICARIA SOLARE DA LUCE VISIBILE

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    A case of solar urticaria by visible light is reported. Among the other light sources employed to elicite isomorphic cutaneous responses, the authors emphasize the use of an unfocused argon laser beam for fototest studies
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