1,098 research outputs found

    Novel Mercury Phosphanylamides

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    The definitive version may be found at www.wiley.comMarcus L. Cole, Glen B. Deacon, Peter C. Junk, Kristina Konstas and Peter W. Roesk

    Synthesis and structural characterisation of some novel lithium and sodium N,N-di(para-tolyl)formamidinate complexes

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    © Royal Society of Chemistry 2002Marcus L. Cole, Peter C. Junk and Lance M. Loui

    Direct syntheses and structural novelty of lanthanoid aryloxides with flexible radial arms

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    The definitive version may be found at www.wiley.comMarcus L. Cole, Glen B. Deacon, Peter C. Junk, Kathryn M. Proctor, Janet L. Scott and Christopher R. Straus

    Reappraising the formation of Jaffe's Base: studies of the treatment of imidazolidine-2-thione with mild oxidising agents

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    Yupa Thanyasirikul, Chaveng Pakawatchai, Marcus L. Cole, Peter C. Junk, Brian W. Skelton and Allan H. Whit

    Structural studies of N,N'-di(ortho-fluorophenyl)formamidine group 1 metallation

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    The definitive version may be found at www.wiley.comMarcus L. Cole, David J. Evans, Peter C. Junk, and Matthew K. Smit

    Synthesis and structural characterisation of lithium and sodium 2,6-dibenzylphenolate complexes

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    © Royal Society of Chemistry 2006Marcus L. Cole, Peter C. Junk, Kathryn M. Proctor, Janet L. Scott and Christopher R. Straus

    Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes

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    Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these disubstituted complexes to redistribute forming trisubstituted ones, which is a common behaviour in lanthanoid chemistry. Also, compared to their corresponding lanthanoid carboxylates, all these products are discrete molecular entities forming an extensive hydrogen-bonded and/or pi stacking network rather than hybrid polymeric frameworks. (C) 2007 Elsevier Ltd. All rights reserved

    Steric engineering of C-F activation with lanthanoid formamidinates

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    Reaction of lanthanum with Hg(C6F5)2 and bulky N,N-bis(2,6-diisopropylphenyl)formamidine (HDippForm) in tetrahydrofuran gives [LaF{DippForm}2(THF)] with a rare terminal Ln–F bond, and a high yield of a novel functionalised formamidine, DippForm((CH2)4OC6F4H-o).Marcus L. Cole, Glen B. Deacon, Peter C. Junk and Kristina Konsta
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