6,152 research outputs found

    EFFECTIVE-MEDIUM THEORY FOR GRANULAR HIGH-TC SUPERCONDUCTORS ELECTROMAGNETIC PROPERTIES IN THE MICROWAVE REGION

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    The authors extend to finite frequencies their recently developed effective-medium theory (EMT) for granular high-Tc superconductors (HTS). Here they present results for the electromagnetic properties in the microwave region, which is of potential significance for early commercial applications of HTS materials. Most of their discussions centre on generalisations of classical Mie scattering theory to spherical superconductor grains. However, there are important corrections to previous works on EMT at finite frequencies by Stroud and Pan (1978) and also Mahan (1988), which they discuss. Some illustrative numerical results are presented, deferring lengthy numerical computations and comparisons with experiments, to be published elsewhere

    Motor racing, tobacco company sponsorship, barcodes and alibi marketing

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    Background Sponsorship of Formula One (F1) motor racing, which has been used as an indirect medium of tobacco advertising for several decades, was prohibited by the 2005 European Union Tobacco Advertising Directive. Most F1 tobacco sponsorship of motor racing in the EU has since ceased, with the exception of the Scuderia Ferrari team, which continues to be funded by Philip Morris. In 2007, the Marlboro logo on Ferrari cars and other race regalia was replaced by an evolving ‘barcode’ design, which Ferrari later claimed was part of the livery of the car, and not a Marlboro advertisement. Objective: To determine whether the ‘barcode’ graphics used by Ferrari represent ‘alibi’ Marlboro advertising. Methods Academic and grey literature, and online tobacco industry document archives, were searched using terms relevant to tobacco marketing and motorsport. Results Tobacco sponsorship of F1 motor racing began in 1968, and Philip Morris has sponsored F1 teams since 1972. Phillip Morris first used a ‘barcode’ design, comprising red vertical parallel lines below the word Marlboro on the British Racing Motors F1 car in 1972. Vertical or horizontal ‘barcode’ designs have been used in this way, latterly without the word Marlboro, ever since. The modern ‘barcode’ logos occupied the same position on cars and drivers' clothing as conventional Marlboro logos in the past. The shared use of red colour by Marlboro and Ferrari is also recognised by Philip Morris as a means of promoting brand association between Marlboro and Ferrari. Conclusion The Ferrari ‘barcode’ designs are alibi Marlboro logos and hence constitute advertising prohibited by the 2005 EU Tobacco Advertising Directive

    Mechanisms for accumulation and migration of technetium-99 in saltmarsh sediments

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    This thesis describes the development of analytical methods for both the bulk determination of 99Tc, and determination of 99Tc in sequential extracts from sediments. These methods have been used to collect data, which, along with trace and major element data have been used to interpret the mechanisms for 99Tc input, migration and accumulation in saltmarshes. The inventory of 99Tc stored in the Thornflatt Saltmarsh, Esk Estuary has also been determined. The routine determination of 99Tc in bulk samples uses 99mTc as a yield monitor. Samples are ignited stepwise to 550°C and the 99Tc is extracted using 8M nitric acid. Many contaminants are precipitated with Fe(OH)3 and the Tc in the supernant is pre-concentrated and further purified using anion-exchange chromatography. Final separation of Tc from Ru is achieved by extraction of Tc into 5% TnOA in xylene from 2M sulphuric acid. The yield is determined by γ-spectrometric analysis of 99mTc. Determination of 99Tc is made by liquid scintillation counting. Typical recoveries are in the order of 70-95% and the method has a detection limit of 1.7 Bq/kg for a sample size of 10g. Determination of Tc in sequential extracts uses operationally defined procedures to extract: exchangeable Tc, reducible Tc and oxidisable Tc. An initial water wash is used to extract any occluded Tc and a final leach in 8 M nitric acid is used to dissolve any residual Tc. The isolation of 99Tc uses TEVA resin for Extracts 1-4 and the decontamination procedure developed for bulk analysis for Extract 5. 99mTc was used as a yield monitor, and determination of 99Tc is by liquid scintillation counting. Limits of detection were dependent on the amount of 99mTc tracer used but were found to be as low as 2.4 Bq/kg for a sample size of 2g. A study was made of the mechanisms responsible for the accumulation and migration of Tc in estuarine sediments using sediments collected from saltmarshes at Thornflatt, Carlaverock and the Ribble Estuary. 99Tc was present at determinable activities in all the sediment cores taken from these sites. Good correlations between Tc and CaO as well as CO3 concentrations and poor correlation between Tc and radionuclides adsorbed to inorganic detritus infer a direct input of 99Tc to marsh sediments. Determination of 99Tc in biota living on the marsh also showed that this was not a significant pathway for input of Tc to the sediments. Sequential extraction data imply sorption to an organic fraction of the sediment. Stable element and sequential extraction data indicates that Tc is readily oxidised and remobilised before reprecipitation where redox conditions are favourable. Data indicate a reduction potential between those of the MnIV to MnII reaction and the FeIII to FeII reaction is necessary for re-accumulation to occur, as suggested by published thermodynamic data. Data collected from reducing sediments imply that similar mechanisms are responsible for the accumulation of Mn (e.g. reduction by sulphate reducing bacteria) and the accumulation of Tc. The inventory of 99Tc held within the Thornflatt saltmarsh is proportionally less than that of 137Cs or 241Am when compared to discharges from Sellafield. However a higher proportion of 99Tc is transferred from Seliafield and incorporated into saltmarsh sediments than is suggested by previously published standard distribution coefficient data. Saltmarsh sediments are therefore a more important sink of 99Tc than extrapolations made from inventories of other radionuclides would suggest

    Service-oriented models for audiovisual content storage

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    What are the important topics to understand if involved with storage services to hold digital audiovisual content? This report takes a look at how content is created and moves into and out of storage; the storage service value networks and architectures found now and expected in the future; what sort of data transfer is expected to and from an audiovisual archive; what transfer protocols to use; and a summary of security and interface issues

    T0-Berekening: Status Quo van UNIBEST-TC

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    Dit rapport gaat in op de ontwikkelingen bij het UNIBETS-TC model. Met dit model wordt het cross-shore en longshore sediment transport berekend. Om inzicht te krijgen in de verbeteringen in het model wordt er in dit rapport een T0-berekening (een berekening op tijdstip T=0) gemaakt. Dit maakt het mogelijk de ontwikkelingen te evalueren door het te vergelijken met een dergelijke exercitie op het moment T1. Met de berekening wordt er antwoord gegeven op de vragen of het UNIBEST-TC model één heel jaar de ontwikkeling van het kustprofiel kan doorrekenen en in hoeverre het model de werkelijkheid beschrijft. Geconcludeerd wordt dat het (nieuwe) UNIBEST-TC model het dwarstransport in de goede orde van grootte bepaald, maar dat het model geen rekening houdt met het ontstaan van banken. Verder onderzoek is nodig. Het model houdt verder goed rekening met de interactie tussen langs- en dwarstransport en biedt daarnaast een goede mogelijkheid om het lot van een zandsuppletie te bestuderen

    Feasibility study on manganese nodules recovery in the Clarion-Clipperton Zone

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    The sea occupies three quarters of the area on the earth and provides various kinds of resources to mankind in the form of minerals, food, medicines and even energy. “Seabed exploitation” specifically deals with recovery of the resources that are found on the seabed, in the form of solids, liquids and gasses (methane hydrates, oil and natural gas). The resources are abundant; nevertheless the recovery process from the seabed, poses various challenges to mankind. This study starts with a review on three types of resources: polymetallic manganese nodules, polymetallic manganese crusts and massive sulphides deposits. Each of them are rich in minerals, such as manganese, cobalt, nickel, copper and some rare earth elements. They are found at many locations in the deep seas and are potentially a big source of minerals. No commercial seabed mining activity has been accomplished to date due to the great complexities in recovery. This book describes the various challenges associated with a potential underwater mineral recovery operation, reviews and analyses the existing recovery techniques, and provides an innovative engineering system. It further identifies the associated risks and a suitable business model.Chapter 1 presents a brief background about the past and present industrial trends of seabed mining. A description of the sea, seabed and the three types of seabed mineral resources are also included. A section on motivations for deep sea mining follows which also compares the latter with terrestrial mining.Chapter 2 deals with the decision making process, including a market analysis, for selecting manganese nodules as the resource of interest. This is followed by a case study specific to the location of interest: West COMRA in the Clarion-Clipperton Zone. Specific site location is determined in order to estimate commercial risk, environmental impact assessment and logistic challenge.Chapter 3 lists the existing techniques for nodule recovery operation. The study identifies the main components of a nodules recovery system, and organizes them into: collector, propulsion and vertical transport systems.Chapter 4 discusses various challenges posed by manganese nodules recovery, in terms of the engineering and environment. The geo-political and legal-social issues have also been considered. This chapter plays an important role in defining the proposed engineering system, as addressing the identified challenges will better shape the proposed solution.Chapter 5 proposes an engineering system, by considering the key components in greater details. An innovative component, the black box is introduced, which is intended to be an environmentally-friendly solution for manganese nodules recovery. Other auxiliary components, such as the mother ship and metallurgical processing, are briefly included. A brief power supply analysis is also provided.Chapter 6 assesses the associated risks, which are divided into sections namely commercial viability, logistic challenges, environmental impact assessment and safety assessment. The feasibility of the proposed solution is also dealt with.Chapter 7 provides a business model for the proposed engineering system. Potential customers are identified, value proposition is determined, costumer relation is also suggested. Public awareness is then discussed and finally a SWOT analysis is presented. This business model serves as an important bridge to reach both industry and research institutes.Finally, Chapter 8 provides some conclusions and recommendation for future work
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