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The Stereochemistry of the Simmons-Smith Reaction on Some 3- and 4-Substituted Cyclohexenes
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Selective amination reactions of α-nitro aryl and heteroaryl enoates
No full textHighly functionalized tetrasubstituted alkenes were obtained by an unexpected amination reaction promoted by ethyl nosyloxycarbamate on various α-nitro aryl and heteroaryl enoates. A nitrene is likely the aminating species responsible for the observed insertion reaction leading to (E)-β-amino α-nitro enoates as the major products, regardless of the substrate configuration. The compounds, bearing two nitrogenous functional groups in different oxidation states, can be regarded as interesting synthons. In contrast, aziridination was observed for α-nitro alkyl enoates or β-nitro allylic alcohols. © 2013 American Chemical Society
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