1,224 research outputs found
Michel Balmont : Le Tuilage. 1994
No full textTamain Guy. Michel Balmont : Le Tuilage. 1994. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 594
Michel Balmont : Le Tuilage. 1994
No full textTamain Guy. Michel Balmont : Le Tuilage. 1994. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 594
Nicolas de Bonneville : I : Le Secret des Templiers du 14e siècle. 1993. II : Les Jésuites chassés de la Maçonnerie et leur poignard brisé par les Maçons, 1993
No full textTamain Guy. Nicolas de Bonneville : I : Le Secret des Templiers du 14e siècle. 1993. II : Les Jésuites chassés de la Maçonnerie et leur poignard brisé par les Maçons, 1993. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 583
Le Frère de La Tierce : Histoire des Francs-Maçons, 1745. 1994
No full textTamain Guy. Le Frère de La Tierce : Histoire des Francs-Maçons, 1745. 1994. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 561
Le Régulateur du Maçon, ou les trois premiers grades et les quatre Ordres supérieurs (1801), d'après le manuscrit de 1783. 1993
No full textTamain Guy. Le Régulateur du Maçon, ou les trois premiers grades et les quatre Ordres supérieurs (1801), d'après le manuscrit de 1783. 1993. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 583
Pierre Chevallier : Les Ducs sous l'Acacia ou les premiers pas de la Franc-Maçonnerie française, 1725-1743. Nouvelles recherches sur les Francs-Maçons parisiens et lorrains, 1709-1785. Les idées religieuses de Davy de La Fautrière. Coll. « Classiques de la Franc-Maçonnerie ». 1994
No full textTamain Guy. Pierre Chevallier : Les Ducs sous l'Acacia ou les premiers pas de la Franc-Maçonnerie française, 1725-1743. Nouvelles recherches sur les Francs-Maçons parisiens et lorrains, 1709-1785. Les idées religieuses de Davy de La Fautrière. Coll. « Classiques de la Franc-Maçonnerie ». 1994. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 592
A.L.C. Destutt de Tracy et l'Idéologie. Textes et documents édités et annotés par Henry Deneys et Anne Deneys-Tunney. Corpus, n° 26/27, 2e semestre 1994
No full textTamain Guy. A.L.C. Destutt de Tracy et l'Idéologie. Textes et documents édités et annotés par Henry Deneys et Anne Deneys-Tunney. Corpus, n° 26/27, 2e semestre 1994. In: Dix-huitième Siècle, n°27, 1995. L'Antiquité. p. 629
Perrhenate and pertechnetate complexation by an azacryptand in nitric acid medium
No full textTechnetium is present as the pertechnetate anion in spent nuclear fuel solutions, and its extraction by several extractant systems is a major problem for the liquid-liquid extraction processes used to separate uranium and plutonium. To prevent technetium extraction into the organic phase, a complexing agent may be added to the aqueous nitric acid phase to selectively bind the pertechnetate anion. In the present study, liquid-liquid extraction experiments reveal that technetium distribution ratios are considerably lowered with addition of an azacryptand, which is a good receptor for pertechnetate anion recognition. This ligand is able to overcome the Hofmeister bias and selectively bind techetium in nitric acid solution. Coordination studies using infrared and Raman spectoscopies and DFT calculations show the formation of an inclusion complex with hydrogen bonds stabilizing the oxo-anion within the cavity. For the first time, the cage molecules are studied for an extraction process
Synthesis and Characterization of Polynuclear Actinide(IV) Species
No full textInternational audienceThe actinide chemistry is largely influenced by the formation of polynuclear species that have attracted valuable interest over the last decades. These species have been proven to play a potential role in the management of waste, fuel reprocessing and even in biological media. The polynuclear species of tetravalent actinides (i.e., actinides clusters) discussed here materialize as molecules containing multiple metal centers connected by oxo and/or hydroxo groups. This forms the core of the cluster, often described by its nuclearity, N, which represent the number of actinides in it. These entities are formed through condensation reactions (referred to as olation and oxolation reactions) in the presence of water and are surface-stabilized by organic or inorganic ligands.[1] In the solid state, various polynuclear species of actinides(IV) have been identified from XRD crystal structures, with various nuclearities ranging from 2 to 38. However, the hexamer consisting of 6 plutonium atoms (Pu6) is frequently observed.[1] This nuclearity has been studied and stabilized several times in the form of the [Pu6O4(OH)4]12+ core. Takao et al. investigated the formation of hexanuclear clusters of neptunium, uranium, and thorium in solution, in the presence of carboxylate ligands.[2] Our group have also studied the formation of plutonium hexameric clusters under various conditions. The results revealed similarities in UV-Vis spectra associated with this nuclearity. [1] [3, 4] However, studies in aqueous solutions are still inadequate, and it remains difficult to identify these polynuclear species in solution.Additionally, recent studies suggest that these species could play a role in the formation mechanism of PuO2 colloidal nanoparticles.[5] Indeed, some hexanuclear Pu(IV) clusters have been identified as reactive intermediates in this process. Colloid formation is an irreversible process that may pose challenges in the context of used nuclear fuel reprocessing. Understanding the formation of polynuclear actinide species is thus crucial for comprehending and mastering the formation of colloids in solution.The first objective of this study is to develop reliable spectroscopic databases, in order to help the identification of polynuclear species in solution. This work begins with the synthesis of plutonium(IV) single crystals characterized by X-ray diffraction (SCXRD), which specific spectra are collected with UV-visible and vibrational spectroscopies (IR and Raman). This approach will simplify the identification of these species in solution, enhance the understanding of the mechanisms involved in the formation of polynuclear species, as well as their evolution towards the formation of colloids. Preliminary results will be presented in the poster.[1]Knope, K. E.; Soderholm, L. Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products. Chem. Rev., 2013, 113 (2), 944–994. https://doi.org/10.1021/cr300212f.[2]Takao, K.; Takao, S.; Scheinost, A. C.; Bernhard, G.; Hennig, C. Formation of Soluble Hexanuclear Neptunium(IV) Nanoclusters in Aqueous Solution: Growth Termination of Actinide(IV) Hydrous Oxides by Carboxylates. Inorg. Chem., 2012, 51 (3), 1336–1344. https://doi.org/10.1021/ic201482n.[3]Tamain, C.; Dumas, T.; Guillaumont, D.; Hennig, C.; Guilbaud, P. First Evidence of a Water-Soluble Plutonium(IV) Hexanuclear Cluster. Eur. J. Inorg. Chem., 2016, 2016 (22), 3536–3540. https://doi.org/10.1002/ejic.201600656.[4]Chupin, G.; Tamain, C.; Dumas, T.; Solari, P. L.; Moisy, P.; Guillaumont, D. Characterization of a Hexanuclear Plutonium(IV) Nanostructure in an Acetate Solution via Visible–Near Infrared Absorption Spectroscopy, Extended X-Ray Absorption Fine Structure Spectroscopy, and Density Functional Theory. Inorg. Chem., 2022, 61 (12), 4806–4817. https://doi.org/10.1021/acs.inorgchem.1c02876.[5]Cot-Auriol, M.; Virot, M.; Dumas, T.; Diat, O.; Menut, D.; Moisy, P.; Nikitenko, S. I. First Observation of [Pu6(OH)4O4]12+ Cluster during the Hydrolytic Formation of PuO2 Nanoparticles Using H/D Kinetic Isotope Effect. Chem. Commun., 2022, 58 (94), 13147–13150. https://doi.org/10.1039/D2CC04990B
Synthesis and Characterization of Polynuclear Actinide(IV) Species
No full textInternational audienceThe actinide chemistry is largely influenced by the formation of polynuclear species that have attracted valuable interest over the last decades. These species have been proven to play a potential role in the management of waste, fuel reprocessing and even in biological media. The polynuclear species of tetravalent actinides (i.e., actinides clusters) discussed here materialize as molecules containing multiple metal centers connected by oxo and/or hydroxo groups. This forms the core of the cluster, often described by its nuclearity, N, which represent the number of actinides in it. These entities are formed through condensation reactions (referred to as olation and oxolation reactions) in the presence of water and are surface-stabilized by organic or inorganic ligands.[1] In the solid state, various polynuclear species of actinides(IV) have been identified from XRD crystal structures, with various nuclearities ranging from 2 to 38. However, the hexamer consisting of 6 plutonium atoms (Pu6) is frequently observed.[1] This nuclearity has been studied and stabilized several times in the form of the [Pu6O4(OH)4]12+ core. Takao et al. investigated the formation of hexanuclear clusters of neptunium, uranium, and thorium in solution, in the presence of carboxylate ligands.[2] Our group have also studied the formation of plutonium hexameric clusters under various conditions. The results revealed similarities in UV-Vis spectra associated with this nuclearity. [1] [3, 4] However, studies in aqueous solutions are still inadequate, and it remains difficult to identify these polynuclear species in solution.Additionally, recent studies suggest that these species could play a role in the formation mechanism of PuO2 colloidal nanoparticles.[5] Indeed, some hexanuclear Pu(IV) clusters have been identified as reactive intermediates in this process. Colloid formation is an irreversible process that may pose challenges in the context of used nuclear fuel reprocessing. Understanding the formation of polynuclear actinide species is thus crucial for comprehending and mastering the formation of colloids in solution.The first objective of this study is to develop reliable spectroscopic databases, in order to help the identification of polynuclear species in solution. This work begins with the synthesis of plutonium(IV) single crystals characterized by X-ray diffraction (SCXRD), which specific spectra are collected with UV-visible and vibrational spectroscopies (IR and Raman). This approach will simplify the identification of these species in solution, enhance the understanding of the mechanisms involved in the formation of polynuclear species, as well as their evolution towards the formation of colloids. Preliminary results will be presented in the poster.[1]Knope, K. E.; Soderholm, L. Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products. Chem. Rev., 2013, 113 (2), 944–994. https://doi.org/10.1021/cr300212f.[2]Takao, K.; Takao, S.; Scheinost, A. C.; Bernhard, G.; Hennig, C. Formation of Soluble Hexanuclear Neptunium(IV) Nanoclusters in Aqueous Solution: Growth Termination of Actinide(IV) Hydrous Oxides by Carboxylates. Inorg. Chem., 2012, 51 (3), 1336–1344. https://doi.org/10.1021/ic201482n.[3]Tamain, C.; Dumas, T.; Guillaumont, D.; Hennig, C.; Guilbaud, P. First Evidence of a Water-Soluble Plutonium(IV) Hexanuclear Cluster. Eur. J. Inorg. Chem., 2016, 2016 (22), 3536–3540. https://doi.org/10.1002/ejic.201600656.[4]Chupin, G.; Tamain, C.; Dumas, T.; Solari, P. L.; Moisy, P.; Guillaumont, D. Characterization of a Hexanuclear Plutonium(IV) Nanostructure in an Acetate Solution via Visible–Near Infrared Absorption Spectroscopy, Extended X-Ray Absorption Fine Structure Spectroscopy, and Density Functional Theory. Inorg. Chem., 2022, 61 (12), 4806–4817. https://doi.org/10.1021/acs.inorgchem.1c02876.[5]Cot-Auriol, M.; Virot, M.; Dumas, T.; Diat, O.; Menut, D.; Moisy, P.; Nikitenko, S. I. First Observation of [Pu6(OH)4O4]12+ Cluster during the Hydrolytic Formation of PuO2 Nanoparticles Using H/D Kinetic Isotope Effect. Chem. Commun., 2022, 58 (94), 13147–13150. https://doi.org/10.1039/D2CC04990B
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