2 research outputs found
Glass/Au Composite Membranes with Gold Nanoparticles Synthesized inside Pores for Selective Ion Transport
No full textNanocomposite membranes have been actively developed in the last decade. The involvement of nanostructures can improve the permeability, selectivity, and anti-fouling properties of a membrane for improved filtration processes. In this work, we propose a novel type of ion-selective Glass/Au composite membrane based on porous glass (PG), which combines the advantages of porous media and promising selective properties. The latter are achieved by depositing gold nanoparticles into the membrane pores by the laser-induced liquid phase chemical deposition technique. Inside the pores, gold nanoparticles with an average diameter 25 nm were formed, which was confirmed by optical and microscopic studies. To study the transport and selective properties of the PG/Au composite membrane, the potentiometric method was applied. The uniform potential model was used to determine the surface charge from the experimental data. It was found that the formation of gold nanoparticles inside membrane pores leads to an increase in the surface charge from −2.75 mC/m2 to −5.42 mC/m2. The methods proposed in this work allow the creation of a whole family of composite materials based on porous glasses. In this case, conceptually, the synthesis of these materials will differ only in the selection of initial precursors
Low-Frequency Magnetic Scanning Device and Algorithm for Determining the Magnetic and Non-Magnetic Fractions of Moving Metallurgical Raw Materials
No full textThe development of an algorithm to automate the process of measuring the magnetic properties of macroscopic objects in motion is an important problem in various industries, especially in ferrous metallurgy and at factories where ferrous scrap is a strategic raw material. The parameter that requires work control is the hidden mass fraction of a non-magnetic substance that is present in the ferromagnetic raw material. The solution to this problem has no prototypes. In our work, a simple measuring device and a mathematical algorithm for calculating the mass fraction of the non-magnetic fraction in a strongly magnetic matrix were developed. The device is an inductance coil, in which the angle of the electromagnet losses is related to the mass of the magnetic material moving the coil. The magnitude of the instantaneous values of the lost angle integral was compared with the result of weighing the object on scales. This allowed us to calculate the proportion of the magnetic and non-magnetic fractions. The use of this prototype is herein illustrated. The experimental results of the determination of the magnetic-fractional composition depending on the mass of scrap metal and its bulk and the magnetic characteristics are presented
