10,861 research outputs found

    Lun Yuesefu de wai tao.

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    論約瑟夫的外套 -- 論美之誕生 -- 思想和創作 -- 文藝之政治性, 藝術性及其他 -- 論文藝創作上的主觀和客觀 -- 讀了《文藝工作底發展及其努力方向》以後 -- 論詩歌工作者的自我改造.前言 ---p.i論約瑟夫的外套 ---p.1論美之誕生 ---p.25思想和創作 ---p.57文藝之政治性,藝術性及其他 ---p.85論文藝創作上的主觀和客觀 ---p.99讀了"文藝工作底發展及其努力方向"以後 ---p.119論詩歌工作者的自我改造 ---p.141黃藥眠著.Huang Yaomian zhu.Lun Yuesefu de wai tao -- Lun mei zhi dan sheng -- Si xiang he chuang zuo -- Wen yi zhi zheng zhi xing, yi shu xing ji qi ta -- Lun wen yi chuang zuo shang de zhu guan he ke guan -- Du le "Wen yi gong zuo di fa zhan ji qi nu li fang xiang" yi hou -- Lun shi ge gong zuo zhe de zi wo gai zao

    Novel routes to bidentate cyclopentadienyl-alkoxy complexes of titanium

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    Reaction of C5R14 (SiMe3)CHR2CH2CR3CR4OR5 with titanium tetrachloride gives bidentate (&eta;5, &sigma;-C5R14CHR2CH2CR3R4O) TiCl2 through elimination of ClSiMe3 and RCl (R = SiMe3, CH2Ph and CMe3). A potentially tridentate system (R1, R2, R3 = H, R4 = -(CH2)2OMe) was synthesised in optically pure form. X-ray structure determination, and NMR studies confirmed that the pendant ether did not co-ordinate to the metal and the complex gave no enantioinduction in hydride transfer reactions. Efficient routes to tetramethylcyclopentadienyl substituted ligands (R1 = Me) were developed through the addition of 2-magnesio-2-butene to γ-lactones followed by protection of the so formed pendant primary hydroxyl group and acid catalysed cyclisation. Indenyl and fluorenyl ligands carrying 3-hydroxypropyl substituents were synthesised, but did not form stable titanium complexes. The bidentate cyclopentadienyl-alkoxy titanium complexes were active catalysts for a variety of transformations.</p

    Man, Au Wai

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    Studies on the mechanism of citrate synthase using site directed mutagenesis

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    SIGLEAvailable from British Library Document Supply Centre- DSC:DX181470 / BLDSC - British Library Document Supply CentreGBUnited Kingdo
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