82,651 research outputs found

    Gnomidolon pulchrum Martins 1960

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    Gnomidolon pulchrum Martins, 1960 (Fig. 2) Gnomidolon pulchrum Martins, 1960: 7; Monné, 2005: 313 (cat.). Martins (2006) called attention to the variation in color of G. pulchrum. The typical form, with the apical half of the elytra reddish, occurs in the south-central part of Paraguay (San Pedro, Cordillera) and in northern Argentina. The form with the apical half of the elytra black is recorded for Brazil (Mato Grosso), but also occurs in northern Paraguay (Concepción). The typical form has been illustrated in color by Martins (1967: 210, est. 7, fig. 2; 2006: 169, fig. 183). A female from Bolivia before us agrees with the form that shows the apical half of the elytra black, but the extremities of the elytra have a narrow transverse white stripe (Fig. 2). Structurally, the specimen agrees morphologically with the other forms cited. Specimens examined. BOLIVIA, Santa Cruz: Albanez (40 km S S(santa)C(cruz), “Laspetas”, fêmea, 6.XII. 2011, J. L. Aramayo col. (ACMS).Published as part of Martins, Ubirajara R. & Galileo, Maria Helena M., 2013, New species and records of Cerambycinae and Lamiinae (Coleoptera: Cerambycidae) from the Neotropical Region, pp. 571-580 in Zootaxa 3683 (5) on pages 572-573, DOI: 10.11646/zootaxa.3683.5.5, http://zenodo.org/record/21812

    Flora Zambesiaca. Mozambique, Malawi, Zambia, Zimbabwe, Botswana. Volume 12, part 2.

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    List of families included in volume 12, part 2. Alismataceae / E.S. Martins & L. Catarino. Limnocharitaceae / E.S. Martins. Hydrocharitaceae / J.J. Symoens. Najadaceae / J.J. Symoens & L. Triest. Aponogetonaceae / E.S. Martins. Juncaginaceae / E.S. Martins. Potomogetonaceae / J.J. Symoens. Zosteraceae / S.O. Bandeira. Zannichelliaceae / M.C. Duarte. Cymodoceaceae / M.C. Duarte. Dioscoridaceae / P. Wilkin. Burmanniaceae / M. Cheek. Pandanaceae / H.J. Beentje. Velloziaceae / A.C. Gonçalves. Colchicaceae / I. la Croix. Liliaceae sensu stricto / P. Wilkin. Smilacaceae / M.A. Diniz

    Compsibidion trichocerum Martins 1962

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    218. Compsibidion trichocerum (Martins, 1962) Octoplon trichocerum Martins, 1962 e: 128, figs. 6, 10 Holotype male: Brazil, Rio de Janeiro: Parque Nacional do Itatiaia, I. 1958, R. Barth.Published as part of Monné, Miguel A. & Monné, Marcela L., 2016, Checklist of Cerambycidae (Coleoptera) primary types of the Museu Nacional, Rio de Janeiro, Brazil, with a brief history of the collection, pp. 1-90 in Zootaxa 4110 (1) on page 21, DOI: 10.11646/zootaxa.4110.1.1, http://zenodo.org/record/25531

    Quiacaua abacta Martins 1981

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    9. Quiacaua abacta (Martins, 1981) (Fig. 26) Eburia abacta Martins, 1981 a: 206. Quiacaua abacta; Martins, 1997: 71. Distribution. Brazil (Espírito Santo, Rio de Janeiro). Specimen examined. BRAZIL, Rio de Janeiro: Itatiaia (Parque Nacional do Itatiaia), 750 m, 1 female, 18– 21.X. 2012, J.P. Botero, V. Machado, A. Carelli, M. Cupello & R. Souza col.Published as part of Botero, Marcela L. Monné Miguel A. Monné Juan P. & Carelli, Allan, 2016, Two new species and new records of Cerambycidae (Insecta, Coleoptera) from Itatiaia National Park, Rio de Janeiro, Brazil, pp. 339-356 in Zootaxa 4137 (3) on pages 346-347, DOI: 10.11646/zootaxa.4137.3.3, http://zenodo.org/record/25666

    Taiophlebia ferreirai Martins-Neto & Gallego & Brauckmann & Cruz 2007, comb. n.

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    Taiophlebia ferreirai (Pinto, 1994), comb. n. Archaemegaptilus ferreirai Pinto, 1994: 107–108, fig. 1 (holotype BA-PB-638, studied). Remarks: A. ferreirai from the Upper Carboniferous (Piedra Shotle Formation, Chubut) of Argentina, was originally attributed to the palaeodictyopterans but clearly exhibits characters typical for Taiophlebia, and can be therefore transferred to the latter genus.Published as part of Martins-Neto, R. G., Gallego, O. F., Brauckmann, C. & Cruz, J. L., 2007, A review of the South American Palaeozoic entomofauna Part I: the Ischnoneuroidea and Cacurgoidea, with description of new taxa, pp. 87-101 in African Invertebrates 48 (1) on page 98, DOI: 10.5281/zenodo.766762

    Catalytic activity of Copper(I) and Copper(II) 3,5-dinitro- or 3,5-bis(trifluoromethyl)-pyrazolate derivatives

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    Catalytic activity of Copper(I) and Copper(II) 3,5-dinitro- or 3,5-bis(trifluoromethyl)-pyrazolate derivatives. Rossana Galassi,a Oumarou Camille Simon,a* Claudia Graiff,b M. Fátima C. Guedes da Silva,c Nuno M. R. Martins,c Luísa M. D. R. S. Martins,c,d Armando J. L. Pombeiroc a School of Science and Technology, Via S. Agostino 1, 62032 Camerino (MC), Italy, *[email protected] b Dipartimento di Chimica, Parco Area delle Scienze 17/A, Parma, Italy c Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade de Lisboa, Portugal. d Chemical Engineering Departament, Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de Lisboa, Portugal. The reaction of [μ-N,N-Cu-(3,5(CF3)2pz]3 (1) with halide sources led to the formation of Cu(II) hexanuclear derivatives such as [(Cu((CF3)2pz)6(OH)6) X][Bu4N] (2a)(Cl-), (2b) (Br-), (2c) (I-), (2d) (NO2-).[1] If the reaction occurs in the same conditions but without halides, a highly hydrated hexanuclear metallocycle [(Cu((CF3)2pz)6(OH)6) (H2O)n], (3), was isolated, ruling out the template action of the anions. By replacing the CF3 groups with NO2 groups in the pyrazole, neither the trinuclear nor the hexanuclear copper derivatives were obtained, and the dinuclear [Cu-(3,5-(NO2)2pz)(PPh3)]2 compound, (4), was the only Cu(I) derivative isolated in good yield. Even though CF3 and NO2 are both withdrawing groups, a pronounced different chemical behavior was already revealed in the case of similar pyrazolate silver(I) derivatives.[2] All compounds were characterized by elemental analysis, NMR, IR spectroscopy and ESI-MS spectrometry. In the case of compound 4 its crystal structure has been determined by X Ray diffraction analysis, evidencing its dinuclear nature, build up by two bridging ligands which coordinate two copper atoms through nitrogen donors, forming a six member ring with boat conformation. Compounds (3) and (4) act as catalysts towards the microwave (MW) assisted peroxidative oxidation of cyclohexane to cyclohexanol and cyclohexanone under mild conditions, which is of industrial significance for the synthesis of Nylon-6,6. High yield (up to 51% of oxygenated products) is obtained after 2h of MW irradiation, using a maximum of 0.2% molar ratio of 3 (the best catalyst) relatively to the substrate in the presence of TEMPO. The efficiency of the catalytic systems as well as the influence of various parameters, such as the reaction time, amount of catalyst, temperature and presence of different additives, are discussed. The work was partially supported by the Fundação para a Ciência e a Tecnologia (project UID/QUI/00100/2013) [ ] Galassi, R.; Burini, A.; Ahmed, A. M. Eur. J. Inorg. Chem. 2012, 3257. [2] Galassi, R.; Ricci, S., Burini, A., Macchioni A., Rocchiggiani, L., Marmottini, F., Tekarli, S. M., Nesterov, V. N. Omary M. A. Inorg. Chem., 2013, 52, 14124

    Schooling and education.

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    Schooling and education by Giles R. Wright with Howard L. Green and Lee R. Parks. Number 4 in the New Jersey Ethnic Life Series. Published by New Jersey Historical Commission

    Oncideres glebulenta Martins 1981

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    39. Oncideres glebulenta Martins, 1981 Oncideres glebulenta Martins, 1981 b: 231. Distribution. Brazil (Goiás, São Paulo), Argentina (Misiones). Specimen examined. BRAZIL, Rio de Janeiro: Itatiaia (Parque Nacional do Itatiaia), 750 m, 1 male, 11– 13.XI. 2011, J.P. Botero, V. Machado, A. Carelli, M. Cupello, M. Simões & R. Souza col.Published as part of Botero, Marcela L. Monné Miguel A. Monné Juan P. & Carelli, Allan, 2016, Two new species and new records of Cerambycidae (Insecta, Coleoptera) from Itatiaia National Park, Rio de Janeiro, Brazil, pp. 339-356 in Zootaxa 4137 (3) on page 354, DOI: 10.11646/zootaxa.4137.3.3, http://zenodo.org/record/25666

    Eburia charmata Martins 1981

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    6. Eburia charmata Martins, 1981 (Fig. 24) Eburia charmata Martins, 1981 a: 207. Distribution. Brazil (Espírito Santo). New record for Rio de Janeiro State and for PNI. Specimen examined. BRAZIL, Rio de Janeiro: Itatiaia (Parque Nacional do Itatiaia), 750 m, 1 female, 29.X. 2011, R. Cavichioli col.Published as part of Botero, Marcela L. Monné Miguel A. Monné Juan P. & Carelli, Allan, 2016, Two new species and new records of Cerambycidae (Insecta, Coleoptera) from Itatiaia National Park, Rio de Janeiro, Brazil, pp. 339-356 in Zootaxa 4137 (3) on page 346, DOI: 10.11646/zootaxa.4137.3.3, http://zenodo.org/record/25666

    Costemilophus aurantius Galileo & Martins, 2005, sp. nov.

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    Costemilophus aurantius sp. nov. (Fig. 7) Etimologia. Latim, aurantius = laranja, alusivo à faixa pronotal. Tegumento preto em todo corpo, menos no protórax que apresenta faixa alaranjada, larga, com lados convergentes para a base e faixa longitudinal, alaranjada, nas partes laterais do protórax e mais estreita na base. Cabeça e partes pretas do pronoto revestidas por pilosidade preta. Élitros com aspecto mais brilhante; pontuação no dorso organizada em fileiras longitudinais entre as costas. Dimensões em mm, holótipo macho. Comprimento total, 9,0; comprimento do protórax, 1,5; maior largura do protórax, 1,7; comprimento do élitro, 6,9; largura umeral, 2,3. Material-tipo. Holótipo macho, COSTA RICA, Puntarenas: El Guarco (San Isidro, Estación Esperanza, 2700 m), 24.I.2001, R. González col., L N 550117 185285 # 61546 (INBio).Published as part of Galileo, Maria Helena M. & Martins, Ubirajara R., 2005, Contribuição aos Hemilophini Da Costa Rica (Coleoptera, Cerambycidae, Lamiinae), pp. 103-109 in Papéis Avulsos de Zoologia 45 (10) on page 107, DOI: 10.1590/S0031-10492005001000001, http://zenodo.org/record/490080
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