1,721,007 research outputs found
Oxone: a Convenient Reagent for the Oxidation of Acetals
No full textSymmetrical cyclic and acyclic acetals by oxidation with Oxone(R) gave the corresponding esters in good yield. Treatment of tetrahydropyranyl derivatives of alcohols with the same reagent resulted in oxidative regeneration of the alcohols
Absolute configuration of furanogermacrenones from Commiphora erythraea by computational analysis of ECD and ORD spectra
No full textThe Synthesis of Solvent-Free Glycidic Esters from Diazoesters and Carbonyl Compounds Catalysed by Lanthanide Triflates
No full textThe results of the reaction between ethyl diazoacetate and carbonyl compounds catalysed by lanthanide triflates are described, Aldehydes, and alpha-unsubstituted and alpha-monosubstituted cyclohexanones react to give the selective formation of alpha,beta-epoxy esters (glycidic esters), whereas other ketones are unreactive
Oxone-KI Induced Lactonization and Etherification of Unsaturated Acids and Alcohols: a Formal Synthesis of Mintlactone
No full textAbsolute configuration of furanogermacrenones from Commiphora erythraea resin by computational analysis of ORD curves and ECD spectra
No full text
Ytterbium Triflate Promoted Tandem One-pot Oxidation-Cannizzaro Reaction of Aryl Methyl Ketones
No full textYtterbium triflate was shown to be an effective catalyst in promoting the synthesis of either isopropyl esters or free r-hydroxy-arylacetic acids
from substituted aromatic glyoxals and aryl methyl ketones, respectively. The reaction to provide acids starting from differently substituted
ketones was carried out by an environmentally friendly method using an aqueous medium as a solvent and giving the adducts in 78-99%
yield without any further purification after the usual workup
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