6,968 research outputs found
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene
No full textPT: J; CR: BONNEAU R, 1989, J AM CHEM SOC, V111, P5973 BONNEAU R, 1989, J PHYS CHEM-US, V93, P4802 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 LIU MT, UNPUB LIU MTH, 1985, J CHEM SOC CHEM COMM, P982 LIU MTH, 1990, J AM CHEM SOC, V112, P3915 PLATZ MS, 1989, J AM CHEM SOC, V111, P6874 WARNER PM, 1984, TETRAHEDRON LETT, P4211; NR: 8; TC: 5; J9: J CHEM SOC CHEM COMMUN; PG: 3; GA: EL425Source type: Electronic(1
Reaction of benzylchlorocarbene with hydrogen chloride
No full textPT: J; CR: BROWN HC, 1942, J AM CHEM SOC, V64, P2223 BUSSEY RJ, 1969, J ORG CHEM, P1323 CLOSS GL, 1962, J AM CHEM SOC, V84, P4350 COCIVERA M, 1963, J AM CHEM SOC, V85, P1702 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 KIRMSE W, 1971, CARBENE CHEM LIU MTH, 1981, J CHEM SOC P2, P53 LIU MTH, 1982, CHEM SOC REV, V11, P127 LIU MTH, 1984, J CHEM SOC CHEM COMM, P1062 LIU MTH, 1984, TETRAHEDRON, V40, P887 MOSS RA, 1973, CARBENES, V1 MOSS RA, 1975, CARBENES, V2; NR: 12; TC: 5; J9: J ORG CHEM; PG: 3; GA: APQ51Source type: Electronic(1
Benzylchlorocarbene: a new ambiphile
No full textPT: J; CR: GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 LIU MTH, 1985, J CHEM SOC CHEM COMM, P982 LIU MTH, 1985, TETRAHEDRON LETT, V26, P3071 LIU MTH, 1987, CHEM DIAZIRINES, CH5 LIU MTH, 1987, J ORG CHEM, V52, P4223 MOSS RA, 1985, REACTIVE INTERMEDIAT, V3 MOSS RA, 1986, J AM CHEM SOC, V108, P7028 MOSS RA, 1987, TETRAHEDRON LETT, V28, P4779 SOUNDARARAJAN N, 1988, J AM CHEM SOC, V110, P7143 TURRO NJ, 1987, J AM CHEM SOC, V109, P4973; NR: 10; TC: 7; J9: J CHEM SOC CHEM COMMUN; PG: 3; GA: T0046Source type: Electronic(1
Termolecular trapping of benzylchlorocarbene by methanol
No full textPT: J; CR: GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 GRILLER D, 1982, J AM CHEM SOC, V104, P5549 KIRMSE W, 1971, CARBENE CHEM LIU MTH, UNPUB LIU MTH, 1982, CHEM SOC REV, V11, P127 MOSS RA, 1973, CARBENES, V1 MOSS RA, 1975, CARBENES, V2 TOMIOKA H, 1984, J AM CHEM SOC, V106, P454 TURRO NJ, 1982, J AM CHEM SOC, V104, P1754; NR: 9; TC: 14; J9: J CHEM SOC CHEM COMMUN; PG: 3; GA: TF969Source type: Electronic(1
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanol
No full textPT: J; CR: GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 GRILLER D, 1982, J AM CHEM SOC, V104, P5549 LIU MTH, 1984, J CHEM SOC CHEM COMM, P1062 LIU MTH, 1985, J CHEM SOC CHEM COMM, P982 LIU MTH, 1985, J ORG CHEM, V50, P3218 LIU MTH, 1985, TETRAHEDRON LETT, V26, P3071 LIU MTH, 1986, J CHEM SOC PERK T 2, P1233 LIU MTH, 1986, J PHYS CHEM-US, V90, P75 LIU MTH, 1987, CHEM DIAZIRINES, V1, CH5 TOMIOKA H, 1984, J AM CHEM SOC, V106, P454 TOMIOKA H, 1986, J CHEM SOC CHEM COMM, P1364; NR: 11; TC: 5; J9: J CHEM SOC PERKIN TRANS 2; PG: 3; GA: L7207Source type: Electronic(1
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirine
No full textPT: J; CR: BONNEAU R, 1989, J AM CHEM SOC, V111, P5973 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 JONES M, 1973, CARBENES, V1 JONES M, 1975, CARBENES, V2 JONES WM, 1980, REARRANGEMENTS GROUN, V1 KIRMSE W, 1971, CARBENE CHEM LAVILLA JA, 1989, J AM CHEM SOC, V111, P6877 LIU MTH, IN PRESS J PHOTOCHEM LIU MTH, IN PRESS J PHYS ORG LIU MTH, 1987, CHEM DIAZIRINES LIU MTH, 1989, J AM CHEM SOC, V111, P6873 LIU MTH, 1990, J AM CHEM SOC, V112, P3915 LIU MTH, 1990, J CHEM SOC CHEM COMM, P1650 MORGAN S, 1991, J AM CHEM SOC, V113, P2782 MOSS RA, 1990, J AM CHEM SOC, V112, P5642 REGITZ M, 1989, METHODEN ORGANISCH E, V19 SCHAEFER HF, 1979, ACCOUNTS CHEM RES, V12, P288; NR: 17; TC: 4; J9: J ORG CHEM; PG: 3; GA: HN858Source type: Electronic(1
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis
No full textPT: J; CR: BURFIELD DR, 1981, J ORG CHEM, V46, P629 GOULD IR, 1985, ETRAHEDRON, V41, P1987 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 HOUK KN, 1984, J AM CHEM SOC, V106, P4291 HOUK KN, 1984, J AM CHEM SOC, V106, P4293 LIAU MTH, 1987, CHEM DIAZIRINES LIU MTH, UNPUB J AM CHEM SOC LIU MTH, 1984, TETRAHEDRON, V40, P887 LIU MTH, 1989, J CHEM SOC CHEM COMM, V12 MAERCKER A, 1982, CHEM BER, V115, P540 MOSS RA, 1986, J AM CHEM SOC, V108, P7028; NR: 11; TC: 5; J9: LASER CHEM; PG: 9; GA: ED999Source type: Electronic(1
Spectroscopy and dynamics of para-nitrophenylchlorocarbene
No full textPT: J; CR: BARCUS RL, 1986, J AM CHEM SOC, V108, P3928 BENASSON R, 1971, T FARADAY SOC, V67, P1904 GOULD IR, 1985, TETRAHEDRON, V41, P1587 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 GRILLER D, 1984, J AM CHEM SOC, V106, P2227 JACKSON JE, 1988, J AM CHEM SOC, V110, P5595 LIU MTH, 1972, CAN J CHEM, V50, P3009 LIU MTH, 1987, CHEM DIAZIRINES, CH5 MOSS RA, 1983, TETRAHEDRON LETT, V24, P685 MOSS RA, 1986, J AM CHEM SOC, V108, P7028 SOUNDARARAJAN N, 1988, J AM CHEM SOC, V110, P7143; NR: 11; TC: 12; J9: J CHEM SOC CHEM COMMUN; PG: 3; GA: U4526Source type: Electronic(1
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene
No full textThe first determination of a 1,2-phenyl shift in alpha,alpha-dimethylbenzylchlorocarbene was achieved by nanosecond laser flash photolysis, tau = 50 ns.PT: J; CR: BONNEAU R, 1989, J AM CHEM SOC, V111, P5973 EVANSECK JD, 1990, J PHYS CHEM-US, V94, P5518 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 JACKSON JE, IN PRESS ADV CARBENE JONES M, 1973, CARBENES, V1, P267 LIU MTH, 1992, J AM CHEM SOC, V114, P3604 LIU MTH, 1992, J PHOTOCH PHOTOBIO A, V63, P115 LIU MTH, 1992, J PHYS ORG CHEM, V5, P285 MOSS RA, IN PRESS ADV CARBENE MOSS RA, 1990, J AM CHEM SOC, V112, P5642 MOSS RA, 1992, J AM CHEM SOC, V114, P959 SARGEANT PB, 1964, TETRAHEDRON LETT, P3957 SUGIYAMA MH, 1992, J AM CHEM SOC, V114, P996; NR: 13; TC: 6; J9: J PHYS ORG CHEM; PG: 3; GA: MQ787Source type: Electronic(1
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene
No full textPT: J; CR: BODOR N, 1972, J AM CHEM SOC, V94, P9103 BURNETT SM, 1983, CHEM PHYS LETT, V100, P124 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 JONES WM, 1980, REARRANGEMENTS GROUN, V1, P95 KIRMSE W, 1967, CHEM BER, V100, P1491 KIRMSE W, 1971, CARBENE CHEM KYBA EP, 1977, J AM CHEM SOC, V99, P8330 LIU MTH, 1982, CHEM SOC REV, V11, P127 LIU MTH, 1983, TETRAHEDRON LETT, V24, P5713 LIU MTH, 1984, TETRAHEDRON, V40, P887 MOSS RA, 1973, CARBENES, V1 MOSS RA, 1975, CARBENES, V2 POPLE JA, 1983, J AM CHEM SOC, V105, P6389 SCHAEFER HF, 1979, ACCOUNTS CHEM RES, V12, P288 SU DTT, 1978, J AM CHEM SOC, V100, P1972 TOMIOKA H, 1984, J AM CHEM SOC, V106, P454 TURRO NJ, 1982, J AM CHEM SOC, V104, P1754 WARNER PM, 1984, TETRAHEDRON LETT, V25, P4211; NR: 18; TC: 34; J9: J CHEM SOC CHEM COMMUN; PG: 3; GA: AMG08Source type: Electronic(1
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