114,570 research outputs found
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine: Carbene, diazo and rearrangement in excited state
No full textC-60 acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the photolysis of 3-chloro-3-isopropyldiazirine and 3-chloro-3-chloromethyldiazirine. The carbene adds to C-60 to form methanofullerene, whereas the diazo compound adds to C-60 to form fulleroid. The olefin product arises as a result of the rearrangement in the excited state.PT: J; CR: AKASAKA T, 1999, J ORG CHEM, V64, P566 AKASAKA T, 1999, ORG LETT, V1, P1509 AKASAKA T, 2000, J AM CHEM SOC, V122, P7134 ARENAS JF, 2002, J AM CHEM SOC, V124, P1728 BECKE AD, 1988, PHYS REV A, V38, P3098 BECKE AD, 1993, J CHEM PHYS, V98, P5648 BONNEAU R, 1996, J AM CHEM SOC, V118, P3829 BONNEAU R, 1996, J AM CHEM SOC, V118, P7229 BRINKER U, 1994, ADV CARBENE CHEM, V1 BRINKER U, 1998, ADV CARBENE CHEM, V2 FRISCH MJ, 1998, GAUSSIAN 98 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 HIRSCH A, 1993, CHEM BER, V126, P1061 JACKSON JE, 1988, J AM CHEM SOC, V110, P595 LAVILLA JA, 1989, J AM CHEM SOC, V111, P6877 LAVILLA JA, 1989, J AM CHEM SOC, V111, P712 LEE C, 1988, PHYS REV B, V37, P785 LIU MTH, 1987, CHEM DIAZIRINES, V1 LIU MTH, 1987, CHEM DIAZIRINES, V2 LIU MTH, 1996, J AM CHEM SOC, V118, P8098 MARTIN N, 1998, CHEM REV, V98, P2527 MODARELLI DA, 1992, J AM CHEM SOC, V114, P7034 PIETRO WJ, 1982, J AM CHEM SOC, V104, P5039 PLATZ MS, 1994, RES CHEM INTERMEDIAT, V20, P175 SCHICK G, 1998, TETRAHEDRON, V54, P4283 WHITE WR, 1992, J ORG CHEM, V57, P2841; NR: 26; TC: 8; J9: J AM CHEM SOC; PG: 4; GA: 582NTSource type: Electronic(1
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridine
No full text3-Substituted indolizines have been obtained in a one-step procedure from the reaction of chlorocarbenes with 2-vinylpyridine.PT: J; CR: BERGNIELSEN K, 1977, ACTA CHEM SCAND B, V21, P224 BONNEAU R, 1989, J CHEM SOC P1, P1547 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 JACKSON JE, 1988, J AM CHEM SOC, V110, P5595 LAWS AP, 1987, J CHEM SOC PERK T 2, P591 LIU MTH, 1984, TETRAHEDRON, V40, P887 LIU MTH, 1992, J AM CHEM SOC, V114, P3604 MODARELLI DA, 1991, J AM CHEM SOC, V113, P8985 OHSAWA A, 1979, CHEM LETT, P241 REGEN SL, 1982, J ORG CHEM, V47, P1587 SWINBOURNE FJ, 1978, ADV HETEROCYCL CHEM, V23, P103 UCHIDA T, 1976, SYNTHESIS-STUTTGART, P209; NR: 12; TC: 12; J9: J CHEM SOC CHEM COMMUN; PG: 2; GA: MY782Source type: Electronic(1
Retraction of articles by T. Liu et al.
No full textA series of 29 papers by Liu et al. are retracted
Effect of substituents on the thermal decomposition of diazirines: Experimental and computational studies
No full textThe thermal decomposition of phenylehlorodiazirine (1), phenyl-n-butyldiazirine (2), and 2-adamantane-2,3'-[3H] diazirine (3) has been studied in solution in the presence Of C-60. The C-60 probe technique indicates that in the decomposition diazirine 1 yielded exclusively phenylchlorocarbene, diazirine 2 yielded mainly a diazo intermediate, and diazirine 3 yielded a mixture of carbene and diazo compound. In the case of diazirine 2, 13% of (E)-1-phenyl-1-pentene resulted from the direct thermal rearrangement of diazirine without the participation of a carbene. As well, the thermal decomposition of these diazirines has been studied theoretically with ab initio and density functional methods. The experimental results are broadly in agreement with the theoretical predictions. The calculations further indicate that the rebound reaction between carbene and molecular nitrogen leading to the formation of a diazo intermediate is an important reaction in the gas-phase decomposition of diazirine.PT: J; CR: AKASAKA T, 2000, J AM CHEM SOC, V122, P7134 AMRICH MJ, 1964, J AM CHEM SOC, V86, P292 BECKE AD, 1988, PHYS REV A, V38, P3098 BECKE AD, 1993, J CHEM PHYS, V98, P5648 BONNEAU R, 1998, ADV CARBENE CHEM, V2, P1 BONNEAU R, 1998, J PHOTOCH PHOTOBIO A, V116, P9 CELEBI S, 1993, J AM CHEM SOC, V115, P8613 DIEDERICH F, 1994, CHEM SOC REV, P243 DIEDERICH F, 1994, NATURE, V369, P199 FIGUERA JM, 1976, AN QUIM, V72, P737 FIGUERA JM, 1978, J CHEM SOC F1, V74, P809 FREY HM, 1962, P CHEM SOC, P79 FREY HM, 1963, J CHEM SOC, P3514 FREY HM, 1964, J CHEM SOC, P4700 FREY HM, 1965, J CHEM SOC, P1700 FREY HM, 1965, J CHEM SOC, P3101 FREY HM, 1966, ADV PHOTOCHEM, V4, P225 FRISCH MJ, 2001, GAUSSIAN 98 REVISION GONZALEZ R, 1995, J ORG CHEM, V60, P2618 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 HEHRE WJ, 1972, J CHEM PHYS, V56, P2257 HIRAO K, 1992, CHEM PHYS LETT, V190, P374 HIRAO K, 1992, CHEM PHYS LETT, V196, P397 HIRAO K, 1992, INT J QUANTUM CHEM S, V26, P517 HIRAO K, 1993, CHEM PHYS LETT, V201, P59 HIRSCH A, 1993, ANGEW CHEM INT EDIT, V32, P1138 HIRSCH A, 1994, CHEM FULLERENES HIRSCH A, 1999, FULLERENES RELATED S ISAEV SD, 1973, ZH ORG KHIM+, V9, P724 JENNINGS BM, 1976, J AM CHEM SOC, V98, P6416 LAUFER AH, 1971, J AM CHEM SOC, V93, P4137 LEE C, 1988, PHYS REV B, V37, P785 LIU M, 1987, CHEM DIAZIRINES LIU MTH, 1972, CAN J CHEM, V50, P3009 LIU MTH, 1972, J PHYS CHEM-US, V76, P797 LIU MTH, 1977, CAN J CHEM, V55, P3596 LIU MTH, 1982, CHEM SOC REV, V11, P127 MERRER DC, 2001, ADV CARBENE CHEM, V3, P53 MODARELLI DA, 1992, J AM CHEM SOC, V114, P7034 MOORE CB, 1964, J CHEM PHYS, V41, P3504 NAKANO H, 1993, J CHEM PHYS, V99, P7983 NAKANO H, 1995, MR2D VER 2 PAULSEN SR, 1960, ANGEW CHEM, V72, P781 PLATZ MS, 1998, ADV CARBENE CHEM, V2, P133 PLATZ MS, 2002, CARBENE CHEM, P27 PLATZ MS, 2002, CARBENE CHEM, P44 ROOS BO, 1987, ADV CHEM PHYS, V69, P399 SCHMIDT MW, 1993, J COMPUT CHEM, V14, P1347 SCHMITZ E, 1961, TETRAHEDRON LETT, P612 SHILOV AE, 1968, TETRAHEDRON LETT, P4177 SMITH AB, 1993, J AM CHEM SOC, V115, P5829 STEVENS IDR, 1990, J CHEM SOC P2, P661 SUZUKI T, 1991, SCIENCE, V254, P1186 SUZUKI T, 1992, J AM CHEM SOC, V114, P7301 TAYLOR R, 1993, NATURE, V363, P685 TAYLOR R, 1996, CHEM FULLERENS WAKAHARA T, 2002, J AM CHEM SOC, V124, P9465; NR: 57; TC: 5; J9: J ORG CHEM; PG: 8; GA: 721XFSource type: Electronic(1
Photolysis of diazirines in the presence of C-60: A chemical probe for carbene
No full textPT: J; CR: AKASAKA T, 1999, J ORG CHEM, V64, P566 AKASAKA T, 1999, ORG LETT, V1, P1509 AN YZ, 1994, J ORG CHEM, V59, P2927 ANDERSON HL, 1994, ANGEW CHEM INT EDIT, V33, P1366 BINKLEY JS, 1980, J AM CHEM SOC, V102, P939 BONNEAU R, 1996, J AM CHEM SOC, V118, P7229 DIEDERICH F, 1994, CHEM SOC REV, P243 DIEDERICH F, 1994, NATURE, V369, P199 FRISCH MJ, 1988, PHYS REV A, V38, P3098 GANZER GA, 1986, J AM CHEM SOC, V108, P1517 GONZALEZ R, 1995, J ORG CHEM, V60, P2618 GRILLER D, 1982, J AM CHEM SOC, V104, P5549 GRILLER D, 1983, J ORG CHEM, V48, P1359 HIRSCH A, 1993, ANGEW CHEM INT EDIT, V32, P1138 HIRSCH A, 1993, CHEM BER, V126, P1061 HIRSCH A, 1994, CHEM FULLERENES HIRSCH A, 1999, FULLERENES RELATED S ISAACS L, 1993, HELV CHIM ACTA, V76, P2454 JANSSEN RAJ, 1995, J AM CHEM SOC, V117, P544 KOMATSU K, 1993, CHEM LETT, P2163 LEE C, 1988, PHYS REV B, V37, P785 LIU MTH, 1987, CHEM DIAZIRINES, V1 MARTIN N, 1998, CHEM REV, V98, P2527 SMITH AB, 1993, J AM CHEM SOC, V115, P5829 STEVENS IDR, 1990, J CHEM SOC P2, P661 SUZUKI T, 1991, SCIENCE, V254, P1186 SUZUKI T, 1992, J AM CHEM SOC, V114, P7301 SUZUKI T, 1994, J AM CHEM SOC, V116, P1359 TAYLOR R, 1993, NATURE, V363, P685 TAYLOR R, 1995, CHEM FULLERENES TOKUYAMA H, 1993, TETRAHEDRON LETT, V34, P7429 TSUDA M, 1993, TETRAHEDRON LETT, V34, P6911 TURRO NJ, 1980, J AM CHEM SOC, V102, P7576 TURRO NJ, 1982, J AM CHEM SOC, V104, P1754 VASELLA A, 1992, ANGEW CHEM INT EDIT, V31, P1388; NR: 35; TC: 8; J9: J AM CHEM SOC; PG: 2; GA: 340FPSource type: Electronic(1
The thermolysis and photolysis of diazirines
No full textPT: J; CR: AMRICH MJ, 1964, J AM CHEM SOC, V86, P292 ARCHER WH, 1976, J CHEM SOC F1, V72, P1448 BAYLEY H, 1978, BIOCHEMISTRY-US, V17, P2420 BIGOT B, 1978, J AM CHEM SOC, V100, P6575 BOTTOMLEY GA, 1964, AUST J CHEM, V17, P406 BRADLEY GF, 1977, J CHEM SOC P2, P1214 BRASLAVSKY S, 1977, CHEM REV, V77, P473 BRIDGE MR, 1969, J CHEM SOC A, P91 BRUNNER J, 1980, J BIOL CHEM, V255, P3313 BURKHOLDER CD, 1980, J AM CHEM SOC, V102, P2841 CADMAN P, 1974, J SA CHEM I, V27, P149 CHANG KT, 1979, J AM CHEM SOC, V101, P5082 CHAPMAN OL, 1976, J AM CHEM SOC, V98, P7844 CRISTY SS, 1970, INT J MASS SPECTROM, V5, P319 ENGEL PS, 1980, CHEM REV, V80, P99 ENGELBRECHT WJ, 1975, J S AFR CHEM I, V28, P144 ENGELBRECHT WJ, 1975, J S AFR CHEM I, V28, P148 ENGELBRECHT WJ, 1975, J S AFR CHEM I, V28, P158 ERNI B, 1980, J AM CHEM SOC, V102, P3888 FIGUERA JM, 1978, J CHEM SOC F1, P809 FRANICH RA, 1972, J CHEM SOC P1, P2034 FREY HM, 1962, J AM CHEM SOC, V84, P2647 FREY HM, 1962, J CHEM SOC, P3865 FREY HM, 1962, P CHEM SOC, P79 FREY HM, 1964, J CHEM SOC, P4700 FREY HM, 1965, J CHEM SOC, P1700 FREY HM, 1965, J CHEM SOC, P3101 FREY HM, 1966, ADV PHOTOCHEM, V4, P225 FREY HM, 1966, J CHEM SOC A, P968 FREY HM, 1970, J CHEM SOC A, P1916 FREY HM, 1977, J CHEM SOC F1, P2010 GRAHAM WH, 1965, J AM CHEM SOC, V87, P4396 GRILLER D, UNPUB JENNINGS BM, 1976, J AM CHEM SOC, V98, P6416 JONES M, 1973, CARBENE, V1 JONES WE, 1976, J PHOTOCHEM, V5, P311 KIRMSE W, 1971, CARBENE CHEM LELEU MJ, 1978, CAHIERS NOTES DOCUME, V93, P569 LIU MTH, UNPUB LIU MTH, 1972, CAN J CHEM, V50, P3009 LIU MTH, 1972, INT J CHEM KINET, V4, P229 LIU MTH, 1972, J PHYS CHEM-US, V76, P797 LIU MTH, 1973, CAN J CHEM, V51, P2393 LIU MTH, 1974, CAN J CHEM, V52, P246 LIU MTH, 1974, CHEM ENG NEWS 0909, P3 LIU MTH, 1974, J CHEM SOC P2, P937 LIU MTH, 1977, CAN J CHEM, V55, P3596 LIU MTH, 1977, J ORG CHEM, V42, P3450 LIU MTH, 1977, TETRAHEDRON LETT, P3139 LIU MTH, 1979, CAN J CHEM, V57, P1299 LIU MTH, 1980, J PHYS CHEM-US, V84, P3184 LIU MTH, 1981, J CHEM SOC P2, P53 LOWE G, 1971, J CHEM SOC CHEM COMM, P1135 MAEDA Y, 1979, J AM CHEM SOC, V101, P837 MANSOOR AM, 1966, TETRAHEDRON LETT, P1733 MEIER H, 1977, ANGEW CHEM INT EDIT, V16, P835 MILLIGAN DE, 1964, J CHEM PHYS, V41, P1199 MITSCH RA, 1964, J HETEROCYCLIC CHEM, V1, P59 MITSCH RA, 1965, J AM CHEM SOC, V87, P758 MITSCH RA, 1966, J HETEROCYCLIC CHEM, V3, P245 MIYASHI T, 1978, J CHEM SOC CHEM COMM, P442 MOFFAT JB, 1978, CHEM DIAZONIUM DIA 1 MOORE CB, 1964, J CHEM PHYS, V41, P3504 MOSS RA, 1967, TETRAHEDRON LETT, P4905 MOSS RA, 1970, J AM CHEM SOC, V92, P6951 MOSS RA, 1978, J AM CHEM SOC, V100, P6788 MOSS RA, 1978, J CHEM SOC CHEM COMM, P775 MOSS RA, 1978, TETRAHEDRON LETT, P1935 MOSS RA, 1979, TETRAHEDRON LETT, P1277 NEUVARAND EW, 1967, J PHYS CHEM-US, V71, P1229 OVERBERGER CG, 1963, TETRAHEDRON LETT, P1405 PAULSEN SR, 1960, ANGEW CHEM, V72, P781 PIERCE L, 1962, J AM CHEM SOC, V84, P2651 SCHMITZ E, 1961, ANGEW CHEM, V73, P115 SCHMITZ E, 1961, TETRAHEDRON LETT, P612 SCHMITZ E, 1962, CHEM BER, V95, P2714 SCHMITZ E, 1967, CHEM BER, V100, P2093 SCHMITZ E, 1967, DREIRINGE ZWEI HETER SCHMITZ E, 1971, 23RD INT C PUR ALL C, V2, P283 SCHMITZ E, 1979, ADV HETEROCYCL CHEM, V24, P63 SMITH NP, 1978, TETRAHEDRON LETT, P1931 SMITH NP, 1979, J CHEM SOC P2, P213 SMITH RAG, 1975, J CHEM SOC P2, P686 SU TT, 1978, J AM CHEM SOC, V100, P1872 VOIGT E, 1975, ANGEW CHEM INT EDIT, V14, P103 VOIGT E, 1975, CHEM BER, V108, P3326; NR: 86; TC: 58; J9: CHEM SOC REV; PG: 14; GA: PJ228Source type: Electronic(1
Inverse determinations of thickness and elastic properties of a bonding layer using laser-generated surface waves
No full text- …
