4,999 research outputs found

    DS_10.1177_0022034519880824 – Supplemental material for Periodontal Pathogens Modulate Lipid Flux via Fatty Acid Binding Protein 4

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    Supplemental material, DS_10.1177_0022034519880824 for Periodontal Pathogens Modulate Lipid Flux via Fatty Acid Binding Protein 4 by D.J. Kim, J.H. Rho, B.H. Woo, J.Y. Joo, J.Y. Lee, J.M. Song, J.H. Lee and H.R. Park in Journal of Dental Research</p

    A Role of Side-Chain Regiochemistry of Thienylene–Vinylene–Thienylene (TVT) in the Transistor Performance of Isomeric Polymers

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    The pi-extended (E)-2-(2-(thiophen-2-ye-vinyl)thiophene (TVT)-based polymers are an interesting class of semiconducting polymers because of their excellent mobilities and unique film microstructures. Despite these properties, the effect of the side-chain regiochemistry of TVT skeletons on the intrinsic properties of these polymers remains unclear. To investigate this, in this study, hexyl-substituted TVT subunits with a "tail in (TI)" or "tail out (TO)" regiosymmetrical arrangement were first introduced into diketo-pyrrolopyrrole (DPP) -based copolymer main chains to afford "isomeric" polymers PI and PO, respectively. By combining optical spectroscopy, atomic force microscopy (AFM), and grazing incidence X-ray diffraction (GIXD) data, we quantitatively characterized the aggregation, crystallization, and backbone orientation of both polymer films, which were then correlated to the charge carrier mobilities. The PI film exhibited a bimodal packing motif comprising a mixture of edge-on and face-on orientations, which was beneficial for three-dimensional (3D) charge transport and resulted in a hole mobility 2-fold larger than that in the PO film (mu(h) = 1.69 cm(2) V-1 s(-1)). This comparative study substantiates the important role of the regiochemistry of TVT in developing high-performance semiconducting polymers.11125sciescopu
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