2,758 research outputs found
Preparation and Characterization of Large Unilamellar Vesicles Mixed with Trimethylchitosan (TMC): The Effect of Polyelectrolyte Concentration
No full textBackground: The effect of different concentrations of the absorption enhancer trimethylchitosan (TMC) to the physicochemical properties of large unilamellar vesicles (LUV) comprised of L-a-Phospahtidylcholine (PC) were investigated in the current study. Methods: The degree of quartenization (DQ) of trimethylchitosan was assessed with nuclear magnetic resonance (H NMR). The vesicles were characterized by means of dynamic light scattering (DLS), ζ-potential, differential scanning calorimetry (DSC) and contact angle goniometry (CAG) measurements. Results: The data showed that the surface charge of the PC liposomes was significantly altered as a function of the TMC concentration, giving evidence of presence of the polyelectrolyte to the liposome’s membrane. Varying the concentration of TMC affected the phase transition temperature (T) of the lipid, verifying the miscibility of the polyelectrolyte with the lipid bilayer. The association of the polymer with the liposomes was related to the amount of the polyelectrolyte present, reflecting changes to the wettability of the dispersion as measured by CAG. Conclusions: The results demonstrated that presence of TMC significantly modified the physical properties of liposomes. Such systems might have a potential use for mucosal delivery (e.g. nasal route of administration)
Self-assembled structures of alkanethiols on gold-coated cantilever tips and substrates for atomic force microscopy : molecular organisation and conditions for reproducible deposition
No full textMeasurements of surface-liquid interactions (contact-angle goniometry) and tip-surface adhesion forces (atomic force microscopy) combined with infrared spectroscopic studies have been used to investigate surface-preparation and solution-deposition conditions for the reproducible formation of self-assembled molecular structures on gold-coated tips and substrates for atomic force microscopy. Preliminary data show that surface-saturated self-assembled monolayers form reproducibly on prolonged (> 20 h) exposure of gold-coated glass substrates to ethanolic solutions of omega-functionalised alkanethiols in the concentration range 80-160 mmol dm(-3). The data also show that exposure for 16 h to alkanethiol concentrations in the range 160-240 mmol dm(-3) promote bilayer formation whereas concentrations of 240-320 mmol dm(-3) result in the deposition of multilayers, the average orientation of which is parallel to that of the first molecular layer; the use of parent 1-undecanethiol solutions at concentrations of 1-80 mmol dm(-3) results in incomplete monolayer coverage. (C) 2009 Elsevier B.V. All rights reserved
Design metrics for evaluating the propulsive efficiency of future ships
No full textThere is an increasing need for the ship design process to take account of environmental issues such as the emission of greenhouse gases and the likely extension of a carbon dioxide charging mechanism to international shipping. These issues, together with the need for economic viability, provide further incentives to improve the efficiency of propulsion of ships. The main components of powering are firstly reviewed. Individual components and other power saving devices are identified which should contribute to improvements in the overall efficiency of propulsion. Suitable design metrics and procedures, taking into account economic and environmental factors, are recommended for the design of future ships
Brief note: some observations on oscillating tangential forces and wear in general plane contacts
No full textFor general plane contact of elastically similar materials, including cases where there are multiple regions of contact, general properties of the partial slip solution for conditions of constant normal force and monotonically increasing shearing force have been found recently by the first author. An extension is given here to cover the unloading and cyclic loading cases. Further, it is shown that, if the tangential load varies between two fixed limits, the region of stick does not change, even if relative microslip causes wear, changing continuously the profile of the indenter. The contact area will change, but wear will not enter the original region of adhesion. The theoretical limit to which wear will eventually, asymptotically proceed is established, viz. almost complete contact over what is the initial stick zone, although it may, in practice, take a long time to reach this state
The description of Kabarda by D.A. Milutin in the context of the cauсasus version of russian orien-talism foundation
No full textThe paper pertains to the analysis of a manuscript authored by D.A. Milutin in the first half of the 19th century, regarding the region of Kabarda. This manuscript, hitherto unpublished in academic circles, has been the subject of our examination. Our endeavor was to uncover the utilization of orientalist clichés by the manuscript's author, in order to depict both the geographical delineations of this ethno-political entity and the ethnography, livelihood, societal structure, and customary legal norms of its inhabitants. A remarkable parallel can be observed between certain aspects of the manuscript and the ideas propounded by E. Said in his discourse on European Orientalism. The researcher drew a comparison between the political framework and traditions of the Kabardian people and those prevalent in Europe. Moreover, the researcher romanticized the region's historical past, employing the conceptof "reverse human progress," along with other typical methodologies embraced by Orientalist thinkers of that era. Concomitantly, D.A. Milutin provided detailed descriptions of the political, social, and everyday existence in Kabarda, thereby endowing the manuscript with an intrinsic value as an original historical and cultural resource for contemporary scholars. It is concluded that, similar to numerous analogous texts produced by Orientalist scholars, the significance of D.A. Milutin's man-uscript lies not in its political arguments concerning the military and economic dominion of the Russian Empire over the Caucasian peoples, or the imperative to extend colonial governance to these ethnic territorie
Elements of Ethnotaxonomy in Dhule and Nandurbar Districts (Maharashtra)
No full textDhule and Nandurbar districts of Maharashtra are mainly inhabited by tribals and rural folks. The author’s ethnobotanical and floristic forays in these districts brought out certain elements of ethnotaxonomy like ethnotaxonomic markers, classifications, principles of nomenclature and exomorphic features. The facts gathered indicated that the people in the area are fairly flooded with reckonable elements of ethnotaxonomy. And 22 ethnotaxonomic markers are identified. These are evaluated and discussed pertinently in this paper.-----------------------------------------------------------------------------------------------------Post Graduate Department of Botany, S.S.V.P.S’s L.K. P.R.Ghogrey Science College, Dhule-424005 (Maharashtra), India*Corresponding author, Email: [email protected] Cite This Article As: D.A. Patil. 2010. Elements of Ethnotaxonomy in Dhule and Nandurbar Districts (Maharashtra). J. Ecobiotechnol. 2(3): 18-25
Aanteekeningen omtrent de gevolgen van zware stormvloeden, tusschen 1500 en 1825 voorgekomen, voor de dijken en polders langs het Zuidwestelijk deel der Zuiderzee: samengesteld door den ingenieur van den Rijkswaterstaat D.A. van Heyst
No full textOverzicht van stormvloeden (1500 - 1825) die tot overstromingen langs de Zuiderzee geleid hebben. Aanleiding was de overstroming van 1916, en men wilde weten of deze stormvloed inderdaad uniek was
The dynamical influences of a hard transition zone on post-glacial uplifts and rotational signatures
No full textRecent investigations from laboratory and Monte-Carlo inversion of geophysical signatures have suggested that the transition zone of the mantle between 400 and 670 km depth may be stiffer than the lower and the upper mantle. By means of a five-layer viscoelastic spherical Earth model, we have calculated the displacement fields associated with post-glacial rebound, the induced polar motions, the temporal variations of the coefficients of the geopotential up to degree eight and the stress fields induced by deglaciation in the lithosphere and the upper mantle. Temporal variations of stress fields in the lithosphere reveal a non-monotonic behaviour due to the viscosity stratification. The results demonstrate the importance of the coming LAGEOS II geodetic satellite mission on constraining the rheological nature of the transition zone in the mantle. -from Author
Author Correction: Coupling electrochemical CO<sub>2</sub> conversion with CO<sub>2</sub> capture (Nature Catalysis, (2021), 4, 11, (952-958), 10.1038/s41929-021-00699-7)
No full textIn the version of this article, there were errors in Fig. 2a and d. In Fig. 2a, we have changed Cu2+ to Cu(0) in the revised version. While the two references cited in our paper used Cu2+ in their schematics,1,2 we believe that Cu(0) is the correct representation for the electrochemically mediated amine regeneration (EMAR)3. To be clear, the Cu metal anode is oxidized into cupric ions. The cupric ions then bind to the carbamate and displace the CO2 and form a copper–amine complex. The copper–amine complex is then reduced at the cathode where Cu metal is plated out. In Fig. 2d, we have changed the polarity of the cathode and anode in the revised version. A proton is released at the anode, while a hydroxide is released at the cathode. We have also simplified the quinone/hydroquinone chemistry in the revised version to be consistent with proton and hydroxide stoichiometry. The original and revised Fig. 2 images are shown below. The changes have been made to the html and PDF versions of the article.Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. Author correction to DOI 10.1038/s41929-021-00699-7ChemE/Transport Phenomen
Cotton mill processes and calculations. An elementary text book for the use of textile schools and for home study ...
No full text2d ed.--rev. and enl. By D.A. Tompkins.viii, 394 p
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