1,721,093 research outputs found
Valutazione delle prestazioni e della durabilità di innovativi strati diffusori di gas per celle a combustibile PEM
Full text link
New formulations and processes for ceramic layers deposition on complex geometry substrates
No full text
Development and characterization of novel PBI/SGO composites as possible proton exchange membranes filling the “conductivity gap”
Full text linkThe research for non-fluorinated polymeric electrolytes able to operate at temperatures of 80–120 °C, the so-called “conductivity gap”, is becoming central. Within this frame, the present work discusses the investigation of innovative self-assembling polybenzimidazole/sulfonated graphene oxide (PBI/SGO) composite membranes. A set of five samples, characterized by never-explored PBI-to-SGO mass ratios between 3:1 and 1:3, is studied through surface and cross-sectional SEM, XRD, ATR-FTIR spectroscopy, and TGA. The experimental outcomes reveal the reciprocal compatibility between PBI and SGO, whose main features appear to be evenly distributed within the composites. Water immersion tests demonstrate the excellent interplay between the membranes and the aqueous environment. EIS experiments, performed with the in-plane and through-plane configurations, disclose the improvement of the proton transfer ability (σ) in both directions. At 120 °C, PBI/SGO 1:2 achieves the highest in-plane σ of 0.113 S cm−1, while PBI/SGO 1:3 shows the best through-plane σ of 0.025 S cm−1. The preference toward planar proton migration is confirmed by the computation of the anisotropy factor, which is attenuated to ≈0.5 with the aid of temperature. Based on these findings, the composites with large SGO content seem to possess great potential as alternative non-fluorinated proton exchange membranes
Development and durability assessment of innovative Gas Diffusion Media for PEM fuel cells
No full textNovel Superhydrophobic Gas Diffusion Media for PEM Fuel Cells: Evaluation of Performance and Durability
No full text
- …
